The given molecules CS and S 2 is very unstable compared to other two given molecules namely CO and O 2 hence using the phi bond forming ability of O and S the reason for their stability should be explained. Concept Introduction : Hybridization: The mixing of atomic orbitals gives the equal number of molecular orbitals. Lewis structures : Diagrams that tell the bonding between atoms in a molecule and the lone pairs of electrons in the molecule. Add dots for anions and remove dots for cations. The total number of dots indicates the valence electron of an atom. VSEPR : Valence shell electron pair repulsion theory is method to predict the geometry of the molecule from the number of electron pairs surrounding the central atom. Idea is that repulsion between electron pairs occurs and increases the separation between the terminal groups or atoms. To Explain: The stability of CS and S 2 molecules using phi bond forming ability of O and S .
The given molecules CS and S 2 is very unstable compared to other two given molecules namely CO and O 2 hence using the phi bond forming ability of O and S the reason for their stability should be explained. Concept Introduction : Hybridization: The mixing of atomic orbitals gives the equal number of molecular orbitals. Lewis structures : Diagrams that tell the bonding between atoms in a molecule and the lone pairs of electrons in the molecule. Add dots for anions and remove dots for cations. The total number of dots indicates the valence electron of an atom. VSEPR : Valence shell electron pair repulsion theory is method to predict the geometry of the molecule from the number of electron pairs surrounding the central atom. Idea is that repulsion between electron pairs occurs and increases the separation between the terminal groups or atoms. To Explain: The stability of CS and S 2 molecules using phi bond forming ability of O and S .
Solution Summary: The author explains the stability of CS and S_ 2 molecules using phi bond forming ability.
The given molecules
CS and S2 is very unstable compared to other two given molecules namely
CO and O2 hence using the phi bond forming ability of
O and S the reason for their stability should be explained.
Concept Introduction:
Hybridization: The mixing of atomic orbitals gives the equal number of molecular orbitals.
Lewis structures: Diagrams that tell the bonding between atoms in a molecule and the lone pairs of electrons in the molecule.
Add dots for anions and remove dots for cations. The total number of dots indicates the valence electron of an atom.
VSEPR: Valence shell electron pair repulsion theory is method to predict the geometry of the molecule from the number of electron pairs surrounding the central atom. Idea is that repulsion between electron pairs occurs and increases the separation between the terminal groups or atoms.
To Explain: The stability of
CS and S2 molecules using phi bond forming ability of
O and S.
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 9 Solutions
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