The electron dot structure for Phosgene

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Answer 1

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9.151MP

(a)

Interpretation Introduction

To Determine:

The electron dot structure for Phosgene

(b)

Interpretation Introduction

To Determine:

Using the table of bond dissociation energies and the value of Δ∘Hf=716.7kJ/mol for C(g) , estimate Δ∘Hf for COCl2 at 25 ∘C.Compare the answer to the actual Δ∘Hf given and explain why your calculation is only an estimate.

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Answer 2

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9.151MP

(a)

Interpretation Introduction

To Determine:

The electron dot structure for Phosgene

(b)

Interpretation Introduction

To Determine:

Using the table of bond dissociation energies and the value of Δ∘Hf=716.7kJ/mol for C(g) , estimate Δ∘Hf for COCl2 at 25 ∘C.Compare the answer to the actual Δ∘Hf given and explain why your calculation is only an estimate.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9.151MP

(a)

Interpretation Introduction

To Determine:

The electron dot structure for Phosgene

(b)

Interpretation Introduction

To Determine:

Using the table of bond dissociation energies and the value of Δ∘Hf=716.7kJ/mol for C(g) , estimate Δ∘Hf for COCl2 at 25 ∘C.Compare the answer to the actual Δ∘Hf given and explain why your calculation is only an estimate.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 9, Problem 9.151MP

(a)

Interpretation Introduction