CHEMISTRY-MOD.MASTERING (18W)
CHEMISTRY-MOD.MASTERING (18W)
8th Edition
ISBN: 9780136780922
Author: Robinson
Publisher: PEARSON
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Chapter 9, Problem 9.104SP
Interpretation Introduction

Interpretation:

The value of ΔΗ0f for SO3 in kJ/mol needs to be determined.

Concept introduction:

For a general reaction as follows:

reactantproducts

The value of change in enthalpy of the reaction can be represented as follows:

ΔHreaction=ΔHfproductsΔHfreactant

Here, ΔHf is the change in standard enthalpy of formation.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 9 Solutions

CHEMISTRY-MOD.MASTERING (18W)

Ch. 9 - PRACTICE 9.11 When 25.0 mL of 1.0 M H2SO4 is added...Ch. 9 - Prob. 9.12ACh. 9 - When 1.00 g of toluene, C7H8, is burned in a bomb...Ch. 9 - Prob. 9.14PCh. 9 - Water gas is the name for the mixture of CO and H2...Ch. 9 - Prob. 9.16ACh. 9 - Prob. 9.17PCh. 9 - Prob. 9.18ACh. 9 - Use the data in Table 9.3 to calculate an...Ch. 9 - Benzene ( C6H6 ) has two resonance structures,...Ch. 9 - Prob. 9.21PCh. 9 - Prob. 9.22ACh. 9 - Prob. 9.23PCh. 9 - Prob. 9.24ACh. 9 - Prob. 9.25PCh. 9 - Prob. 9.26ACh. 9 - Prob. 9.27PCh. 9 - Prob. 9.28PCh. 9 - Prob. 9.29PCh. 9 - Prob. 9.30PCh. 9 - Prob. 9.31PCh. 9 - Prob. 9.32PCh. 9 - PROBLEM 9.33 A 12.0 gallon hold 39.9 kg of...Ch. 9 - A piece of dry ice (solid CO2) is placed inside a...Ch. 9 - Imagine a reaction that results in a change in...Ch. 9 - 9.32 Redraw the following diagram to represent the...Ch. 9 - 9.33 A reaction is carried out in a cylinder...Ch. 9 - Prob. 9.38CPCh. 9 - Prob. 9.39CPCh. 9 - Prob. 9.40CPCh. 9 - Prob. 9.41CPCh. 9 - Prob. 9.42CPCh. 9 - Prob. 9.43CPCh. 9 - What is the difference between heat and...Ch. 9 - What is internal energy?Ch. 9 - Prob. 9.46SPCh. 9 - Prob. 9.47SPCh. 9 - Which of the following are state functions, and...Ch. 9 - Prob. 9.49SPCh. 9 - Calculate the work done in joules by a chemical...Ch. 9 - The addition of H2 to C=C double bonds is an...Ch. 9 - Prob. 9.52SPCh. 9 - Prob. 9.53SPCh. 9 - 9.50 A reaction inside a cylindrical container...Ch. 9 - At a constant pressure of 0.905 atm, a chemical...Ch. 9 - RANWhen a sample of a hydrocarbon fuel is ignited...Ch. 9 - Used in welding metals, the reaction of acetylene...Ch. 9 - What is the difference between the internal energy...Ch. 9 - Prob. 9.59SPCh. 9 - The explosion of 2.00 mol of solid trinitrotoluene...Ch. 9 - The reaction between hydrogen and oxygen to yield...Ch. 9 - The enthalpy change for the reaction of 50.0 mL of...Ch. 9 - Assume that a particular reaction evolves 244 kJ...Ch. 9 - What is the enthalpy change ( H ) for a reaction...Ch. 9 - Prob. 9.65SPCh. 9 - Indicate the direction of heat transfer between...Ch. 9 - Indicate the direction of heat transfer between...Ch. 9 - The familiar "ether" used as an anesthetic agent...Ch. 9 - How much energy in kilojoules is required to...Ch. 9 - Aluminum metal reacts with chlorine with a...Ch. 9 - How much heat in kilojoules is evolved or absorbed...Ch. 9 - How much heat in kilojoules is evolved or absorbed...Ch. 9 - Nitromethane sometimes used as a fuel in drag...Ch. 9 - Prob. 9.74SPCh. 9 - How much heat in kilojoules is evolved or absorbed...Ch. 9 - Prob. 9.76SPCh. 9 - Prob. 9.77SPCh. 9 - Sodium metal is sometimes used as a cooling agent...Ch. 9 - Prob. 9.79SPCh. 9 - Assuming that Coca-Cola has the same specific heat...Ch. 9 - Calculate the amount of heat required to raise the...Ch. 9 - Instant cold packs used to treat athletic injuries...Ch. 9 - Instant hot packs contain a solid and a pouch of...Ch. 9 - When 1.045 g of CaO is added to 50.0 mL of water...Ch. 9 - When a solution containing 8.00 g of NaOH in 50.0...Ch. 9 - When 0.187 g of benzene, C6H6 , is burned in a...Ch. 9 - When 0.500 g of ethanol, C2H6O, is burned in a...Ch. 9 - When 1.50 g of magnesium metal is allowed to react...Ch. 9 - A 110.0 g piece of molybdenum metal is heated to...Ch. 9 - Citric acid has three dissociable hydrogens. When...Ch. 9 - Prob. 9.91SPCh. 9 - Prob. 9.92SPCh. 9 - Prob. 9.93SPCh. 9 - The industrial degreasing solvent methylene...Ch. 9 - Hess's law can be used to calculate reaction...Ch. 9 - Find H in kilojoules for the reaction of nitric...Ch. 9 - Set up a Hess's law cycle, and use the following...Ch. 9 - Prob. 9.98SPCh. 9 - Prob. 9.99SPCh. 9 - What phase of matter is associated with the...Ch. 9 - What is the phase of the standard states of the...Ch. 9 - Write balanced equations for the formation of the...Ch. 9 - Prob. 9.103SPCh. 9 - Prob. 9.104SPCh. 9 - Prob. 9.105SPCh. 9 - The standard enthalpy change for the reaction of...Ch. 9 - Prob. 9.107SPCh. 9 - Styrene ( C8H8 ), the precursor of polystyrene...Ch. 9 - Prob. 9.109SPCh. 9 - Prob. 9.110SPCh. 9 - Prob. 9.111SPCh. 9 - Prob. 9.112SPCh. 9 - Prob. 9.113SPCh. 9 - Prob. 9.114SPCh. 9 - Prob. 9.115SPCh. 9 - Prob. 9.116SPCh. 9 - Isooctane, C8H18, is the component of gasoline...Ch. 9 - Calculate an approximate heat of combustion for...Ch. 9 - Use the data in Table 9.3 to calculate an...Ch. 9 - Use the average bond dissociation energies in...Ch. 9 - Use the bond dissociation energies in Table 9.3 to...Ch. 9 - Prob. 9.122SPCh. 9 - Prob. 9.123SPCh. 9 - Prob. 9.124SPCh. 9 - Prob. 9.125SPCh. 9 - Tell whether the entropy changes for the following...Ch. 9 - Prob. 9.127SPCh. 9 - Prob. 9.128SPCh. 9 - Prob. 9.129SPCh. 9 - Prob. 9.130SPCh. 9 - Prob. 9.131SPCh. 9 - Tell whether reactions with the following values...Ch. 9 - Tell whether reactions with the following values...Ch. 9 - Suppose that a reaction has H=33kJ and S=58J/K. At...Ch. 9 - Suppose that a reaction has H=+41kJ and S=27J/K....Ch. 9 - Which of the reactions (a)-(d) in Problem 9.132...Ch. 9 - Vinyl chloride (H2C=CHCI), the starting material...Ch. 9 - Ethyl alcohol has Hfusion=5.02kJ/mol and melts at...Ch. 9 - Chloroform has Hvaporization=29.2kJ/mol and boils...Ch. 9 - The boiling point of a substance is defined as the...Ch. 9 - What is the melting point of benzene in kelvin if...Ch. 9 - Prob. 9.142SPCh. 9 - Methanol (CH3OH) is made industrially in two steps...Ch. 9 - Ethyl chloride ( C2H5CI ), a substance used as a...Ch. 9 - Prob. 9.145MPCh. 9 - For a process to be spontaneous, the total entropy...Ch. 9 - Prob. 9.147MPCh. 9 - Prob. 9.148MPCh. 9 - Prob. 9.149MPCh. 9 - Prob. 9.150MPCh. 9 - Phosgene, COCI2(g), is a toxic gas used as an...Ch. 9 - Prob. 9.152MPCh. 9 - Write a balanced equation for the reaction of...Ch. 9 - Hydrazine, a component of rocket fuel, undergoes...Ch. 9 - Prob. 9.155MP
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