Bundle: Chemistry, Loose-Leaf Version, 10th + OWLv2, 4 terms (24 months) Printed Access Card
10th Edition
ISBN: 9781337537933
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 9, Problem 88CWP
Pelargondin is the molecule responsible for the red color of the geranium flower. It also contributes to the color of ripe strawberries and raspberries. The structure of pelargondin is:
How many σ and π bonds exist in pelargondin? What is the hybridization of the carbon atoms marked 1–4?
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT
Chapter 9 Solutions
Bundle: Chemistry, Loose-Leaf Version, 10th + OWLv2, 4 terms (24 months) Printed Access Card
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