The intermediate in first step of given halogenation reaction has to be drawn. Concept Introduction: Halogenation of Alkynes : Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products. Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

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Answer 1

Question

Chapter 9, Problem 70IP

(a)

Interpretation Introduction

Interpretation:

The intermediate in first step of given halogenation reaction has to be drawn.

Concept Introduction:

Halogenation of Alkynes:

Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products.

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(b)

Interpretation Introduction

Interpretation:

During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(c)

Interpretation Introduction

Interpretation:

The reaction mechanism of halogenation with both steps has to be given.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 9, Problem 70IP

(a)

Interpretation Introduction

Interpretation:

The intermediate in first step of given halogenation reaction has to be drawn.

Concept Introduction:

Halogenation of Alkynes:

Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products.

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(b)

Interpretation Introduction

Interpretation:

During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(c)

Interpretation Introduction

Interpretation:

The reaction mechanism of halogenation with both steps has to be given.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

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Answer 3

Question

Chapter 9, Problem 70IP

(a)

Interpretation Introduction

Interpretation:

The intermediate in first step of given halogenation reaction has to be drawn.

Concept Introduction:

Halogenation of Alkynes:

Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products.

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(b)

Interpretation Introduction

Interpretation:

During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(c)

Interpretation Introduction

Interpretation:

The reaction mechanism of halogenation with both steps has to be given.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

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Answer 4

Question

Chapter 9, Problem 70IP

(a)

Interpretation Introduction

Interpretation:

The intermediate in first step of given halogenation reaction has to be drawn.

Concept Introduction:

Halogenation of Alkynes:

Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products.

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(b)

Interpretation Introduction

Interpretation:

During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(c)

Interpretation Introduction

Interpretation:

The reaction mechanism of halogenation with both steps has to be given.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

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Answer 5

Chapter 9, Problem 70IP

(a)

Interpretation Introduction

Interpretation:

The intermediate in first step of given halogenation reaction has to be drawn.

Concept Introduction:

Halogenation of Alkynes:

Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products.

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(b)

Interpretation Introduction

Interpretation:

During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

(c)

Interpretation Introduction

Interpretation:

The reaction mechanism of halogenation with both steps has to be given.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

Answer 6

Chapter 9, Problem 70IP

(a)

Interpretation Introduction

Interpretation:

The intermediate in first step of given halogenation reaction has to be drawn.

Concept Introduction:

Halogenation of Alkynes:

Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products.

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Answer 7

Chapter 9, Problem 70IP

(a)

Interpretation Introduction

Interpretation:

The intermediate in first step of given halogenation reaction has to be drawn.

Concept Introduction:

Halogenation of Alkynes:

Intermediate: It is a molecular entity formed from the reactants and then reacts further to give the products.

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Answer 9

(b)

Interpretation Introduction

Interpretation:

During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reaction mechanism of halogenation with both steps has to be given.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reaction mechanism of halogenation with both steps has to be given.

Concept Introduction:

Halogenation of Alkynes:

Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

Mechanism of the reaction is the step-by-step description of the process by which reactants are changed into products.

Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.

Answer 12

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Answer 15

Ch. 9.2 - Prob. 1LTS Ch. 9.2 - Prob. 1PTS Ch. 9.2 - Prob. 2PTS Ch. 9.2 - Prob. 3PTS Ch. 9.2 - (+)-Citronella is the main compound responsible...Ch. 9.3 - Prob. 2LTS Ch. 9.3 - Prob. 5PTS Ch. 9.3 - Prob. 6ATS Ch. 9.4 - Prob. 7CC Ch. 9.4 - Prob. 8CC

Interpretation: During the second step of halogenation mechanism, a high energy carbocation is formed which has to be drawn and explained. Concept Introduction: Halogenation of Alkynes: Alkynes react with excess of halogens in presence of carbon tetrachloride to form tetrahalo-substituted compound.

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