Laboratory Experiments for Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321949912
Author: Theodore E. Brown, John H. Nelson, Kenneth C. Kemp
Publisher: PEARSON
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Chapter 9, Problem 63E
Interpretation Introduction
To determine: The structure of two possible dipeptides formed by the condensation reactions between histidine and aspartic acid.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 9 Solutions
Laboratory Experiments for Chemistry: The Central Science (13th Edition)
Ch. 9.2 - Prob. 9.1.1PECh. 9.2 - Prob. 9.1.2PECh. 9.2 - Prob. 9.2.1PECh. 9.2 - Prob. 9.2.2PECh. 9.2 - Prob. 9.3.1PECh. 9.2 - Prob. 9.3.2PECh. 9.3 - Prob. 9.4.1PECh. 9.3 - Prob. 9.4.2PECh. 9.5 - Prob. 9.5.1PECh. 9.5 - Prob. 9.5.2PE
Ch. 9.6 - Prob. 9.6.1PECh. 9.6 - Prob. 9.6.2PECh. 9.6 - Prob. 9.7.1PECh. 9.6 - Prob. 9.7.2PECh. 9.7 - Prob. 9.8.1PECh. 9.7 - Prob. 9.8.2PECh. 9.8 - Prob. 9.9.1PECh. 9.8 - Prob. 9.9.2PECh. 9 - Prob. 1DECh. 9 - Prob. 1ECh. 9 - Prob. 2ECh. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Prob. 5ECh. 9 - Prob. 6ECh. 9 - Prob. 7ECh. 9 - Prob. 8ECh. 9 - Prob. 9ECh. 9 - Prob. 10ECh. 9 - Prob. 11ECh. 9 - Prob. 12ECh. 9 - Prob. 13ECh. 9 - Prob. 14ECh. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Prob. 18ECh. 9 - Prob. 19ECh. 9 - Prob. 20ECh. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - Prob. 23ECh. 9 - Prob. 24ECh. 9 - Prob. 25ECh. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - Prob. 30ECh. 9 - Prob. 31ECh. 9 - Prob. 32ECh. 9 - Prob. 33ECh. 9 - Prob. 34ECh. 9 - Prob. 35ECh. 9 - Prob. 36ECh. 9 - Prob. 37ECh. 9 - Prob. 38ECh. 9 - Prob. 39ECh. 9 - Prob. 40ECh. 9 - Prob. 41ECh. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Describe the intermediate that is thought to form...Ch. 9 - Prob. 45ECh. 9 - Prob. 46ECh. 9 - Prob. 47ECh. 9 - Prob. 48ECh. 9 - (a) Starting with the orbital diagram of a boron...Ch. 9 - Prob. 50ECh. 9 - Prob. 51ECh. 9 - Prob. 52ECh. 9 - Prob. 53ECh. 9 - Prob. 54ECh. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - Prob. 58ECh. 9 - Prob. 59ECh. 9 - Prob. 60ECh. 9 - Prob. 61ECh. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - In the formate ion, HCO2-, the carbon atom is the...Ch. 9 -
9.66 Consider the Lewis structure shown below....Ch. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - Prob. 70ECh. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Prob. 73ECh. 9 - (a) What is the probability of finding an electron...Ch. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Prob. 77ECh. 9 - Prob. 78ECh. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 81ECh. 9 - Prob. 82ECh. 9 - Prob. 83ECh. 9 - Prob. 84ECh. 9 - Prob. 85AECh. 9 - Prob. 86AECh. 9 - Prob. 87AECh. 9 - Prob. 88AECh. 9 - Prob. 89AECh. 9 - Prob. 90AECh. 9 - Prob. 91AECh. 9 - Prob. 92AECh. 9 - Prob. 93AECh. 9 - Prob. 94AECh. 9 - Prob. 95AECh. 9 - Prob. 96AECh. 9 - Prob. 97AECh. 9 - Prob. 98AECh. 9 - A typical amino acid with one amino group and one...Ch. 9 - The azide ion, N3-, is linear with two N—N bonds...Ch. 9 - Prob. 101AECh. 9 - Prob. 102AECh. 9 - Prob. 103AECh. 9 - Prob. 104AECh. 9 - Prob. 105AECh. 9 - Prob. 106AECh. 9 - How many hydrogen atoms are in 2, 2-...Ch. 9 - Prob. 108AECh. 9 - Prob. 109AECh. 9 - Prob. 110AECh. 9 - Prob. 111AECh. 9 - Prob. 112AECh. 9 - Prob. 113IECh. 9 - Prob. 114IECh. 9 - Prob. 115IECh. 9 - Prob. 116IECh. 9 - Practice Exercise 2 Name the dipeptide and give...Ch. 9 - How many chiral carbon atoms are there in the...Ch. 9 - Prob. 119IECh. 9 - Prob. 120IECh. 9 - Prob. 121IECh. 9 - Prob. 122IE
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