EBK BASIC CHEMISTRY
6th Edition
ISBN: 9780134987088
Author: Timberlake
Publisher: PEARSON CO
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Textbook Question
Chapter 9, Problem 61APP
Pentane gas (
a. How many moles of
b. How many grams of
c. How many grams of
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Consider the reaction below to answer the following questions:
Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate.
1. NaOEt, EtOH
H&C
OCH CH3 2 H30
H3C
CH2
OCH2CH3
A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and
draw all intermediate structures.
B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents
and structures for all intermediates in this preparation.
C. Give the structures of the ester precursors for the following Claisen condensation product and
formulate the reaction.
OEt
Use the phase diagram of Substance X below to find the temperature at which X turns to a gas, if the pressure above the solid is 3.7 atm.
pressure (atm)
32
16
solid
liquid
gas
0
0
200
temperature (K)
Note: your answer must be within 20 °C of the exact answer to be graded correct.
Шос
☑
ك
Starting from bromoethane, how could you prepare the following compounds:
a. Ethanol.
b. Acetaldehyde
f. Acetone.
e. 2-Propanol
i. Acetoacetic ester.
d. 2-Bromoacetic acid.
c. Acetic acid
g. Acetamide.
j. Ethylmalonate
k. Gama ketoacid.
h. Ethyl magnesium bromide.
Chapter 9 Solutions
EBK BASIC CHEMISTRY
Ch. 9.1 - Calculate the total mass of the reactants and the...Ch. 9.1 - Calculate the total mass of the reactants and the...Ch. 9.2 - Calculate the total mass of the reactants and the...Ch. 9.2 - Write all of the mole-mole factors for each of the...Ch. 9.2 - For the chemical equations in problem 9.3, write...Ch. 9.2 - For the chemical equations in problem 9.4, write...Ch. 9.2 - The chemical reaction of hydrogen with oxygen...Ch. 9.2 - Ammonia is produced by the chemical reaction of...Ch. 9.2 - Carbon disulfide and carbon monoxide are produced...Ch. 9.2 - In the acetylene torch, acetylene gas burns in...
Ch. 9.3 - Sodium reacts with oxygen to produce sodium oxide....Ch. 9.3 - Nitrogen reacts with hydrogen to produce ammonia....Ch. 9.3 - Ammonia and oxygen react to form nitrogen and...Ch. 9.3 - Iron(III) oxide reacts with carbon to give iron...Ch. 9.3 - Prob. 15PPCh. 9.3 - Calcium cyanamide, CaCN2 , reacts with water to...Ch. 9.3 - Prob. 17PPCh. 9.3 - Prob. 18PPCh. 9.4 - A taxi company has 10 taxis. a. On a certain day,...Ch. 9.4 - Prob. 20PPCh. 9.4 - Prob. 21PPCh. 9.4 - Iron and oxygen react to form iron(III) oxide....Ch. 9.4 - For each of the following reactions, 20.0 g of...Ch. 9.4 - For each of the following reactions, 20.0 g of...Ch. 9.4 - For each of the following reactions, calculate the...Ch. 9.4 - For each of the following reactions, calculate the...Ch. 9.5 - Carbon disulfide is produced by the reaction of...Ch. 9.5 - Iron (III) oxide reacts with carbon monoxide to...Ch. 9.5 - Aluminum reacts with oxygen to produce aluminum...Ch. 9.5 - Propane ( C3H8 ) bums in oxygen to produce carbon...Ch. 9.5 - Prob. 31PPCh. 9.5 - When 56.6 g of calcium is reacted with nitrogen...Ch. 9.6 - In an exothermic reaction, is the energy of the...Ch. 9.6 - In an endothermic reaction, is the energy of the...Ch. 9.6 - Prob. 35PPCh. 9.6 - Prob. 36PPCh. 9.6 - Classify each of the following as exothermic or...Ch. 9.6 - Classify each of the following as exothermic or...Ch. 9.6 - Prob. 39PPCh. 9.6 - a. How many kilojoules are released when 75.0 g of...Ch. 9.6 - Prob. 41PPCh. 9.6 - Calculate the energy change for the reaction...Ch. 9.6 - Prob. 43PPCh. 9.6 - Prob. 44PPCh. 9.6 - In one step in the synthesis of the insecticide...Ch. 9.6 - Another widely used insecticide is carbofuran...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - Prob. 55APPCh. 9 - Prob. 56APPCh. 9 - Prob. 57APPCh. 9 - Prob. 58APPCh. 9 - Prob. 59APPCh. 9 - Prob. 60APPCh. 9 - Pentane gas ( C5H12 ) reacts with oxygen to...Ch. 9 - Prob. 62APPCh. 9 - Prob. 63APPCh. 9 - Prob. 64APPCh. 9 - Prob. 65APPCh. 9 - Prob. 66APPCh. 9 - Prob. 67APPCh. 9 - Prob. 68APPCh. 9 - Prob. 69APPCh. 9 - The equation for the reaction of iron and oxygen...Ch. 9 - Prob. 71APPCh. 9 - Prob. 72APPCh. 9 - Prob. 73CPCh. 9 - Prob. 74CPCh. 9 - Prob. 75CPCh. 9 - The following problems are related to the topics...Ch. 9 - Prob. 77CPCh. 9 - Prob. 78CPCh. 9 - Prob. 79CPCh. 9 - Prob. 80CPCh. 9 - The following problems are related to the topics...Ch. 9 - Prob. 82CPCh. 9 - Prob. 83CPCh. 9 - The following problems are related to the topics...Ch. 9 - Prob. 85CPCh. 9 - Prob. 86CP
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