Organic Chemistry, 12e Study Guide/Student Solutions Manual

12th Edition

ISBN: 9781119077329

Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder

Publisher: WILEY

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Textbook Question

Chapter 9, Problem 47P

The 1 H NMR study of DMF (N, N-dimethylformamide) results in different spectra according to the temperature of the sample. At room temperature, two signals are observed for the protons of the two methyl groups. On the other hand, at elevated temperatures (> 130 °C a singlet is observed that integrates for six hydrogens. Explain these differences.

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Chapter 9, Problem 46P

Chapter 9, Problem 48P

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Chapter 9 Solutions

Organic Chemistry, 12e Study Guide/Student Solutions Manual

Ch. 9 - Prob. 1PP Ch. 9 - PRACTICE PROBLEM 9.2 What compound with molecular...Ch. 9 - PRACTICE PROBLEM 9.3 Using the method of Section...Ch. 9 - PRACTICE PROBLEM 9.4 How many signals would each...Ch. 9 - Prob. 5PP Ch. 9 - Prob. 6PP Ch. 9 - PRACTICE PROBLEM 9.7 The relative chemical shifts...Ch. 9 - Prob. 8PP Ch. 9 - PRACTICE PROBLEM 9.9 Propose a structure for...Ch. 9 - PRACTICE PROBLEM 9.10 What is the dihedral angle...

Ch. 9 - PRACTICE PROBLEM 9.11 Draw the most stable chair...Ch. 9 - Prob. 12PP Ch. 9 - PRACTICE PROBLEM 9.13 How many signals would you...Ch. 9 - Prob. 14PP Ch. 9 - Prob. 15PP Ch. 9 - Prob. 16PP Ch. 9 - Prob. 17PP Ch. 9 - PRACTICE PROBLEM 9.18 What are the expected ratios...Ch. 9 - Prob. 19PP Ch. 9 - How many 1H NMR signals (not peaks) would you...Ch. 9 - How many 13C NMR signals would you predict for...Ch. 9 - Prob. 22P Ch. 9 - Prob. 23P Ch. 9 - Prob. 24P Ch. 9 - Compound Q has the molecular formula C7H8. The...Ch. 9 - 9.26 Explain in detail how you would distinguish...Ch. 9 - Compound S (C8H16) reacts with one mole of bromine...Ch. 9 - A compound with molecular formula C4H8O has a...Ch. 9 - In the mass spectrum of 2, 6-dimethyl-4-heptanol...Ch. 9 - Prob. 30P Ch. 9 - What are the masses and structures of the ions...Ch. 9 - Prob. 32P Ch. 9 - Ethyl bromide and methoxybenzene (shown below)...Ch. 9 - 9.34 The homologous series of primary amines, ,...Ch. 9 - Propose a structure that is consistent with each...Ch. 9 - 9.36 Propose structures for compounds E and F....Ch. 9 - 9.37 Use the NMR and IR data below to propose a...Ch. 9 - 9.38 When dissolved in , a compound (K) with the...Ch. 9 - Compound T (C5H8O) has a strong IR absorption band...Ch. 9 - Prob. 40P Ch. 9 - Deduce the structure of the compound that gives...Ch. 9 - Deduce the structure of the compound that gives...Ch. 9 - The 1H NMR spectrum of a solution of 1,...Ch. 9 - Acetic acid has a mass spectrum showing a...Ch. 9 - The 1H NMR peak for the hydroxyl proton of...Ch. 9 - The 1H NMR study of DMF (N, N-dimethylformamide)...Ch. 9 - 9.48 The mass spectra of many benzene derivatives...Ch. 9 - Prob. 49P Ch. 9 - 1. Given the following information, elucidate the...Ch. 9 - Two compounds with the molecular formula C5H10O...

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