ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
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Chapter 9, Problem 41P

Deduce the structure of the compound that gives the following 1 H , 13 C , and IR spectra (Fig. 9.43-9.45). Assign all aspects of the 1 H and 13 C spectra to the structure you propose. Use letters to correlate protons with the signals in the 1 H NMR spectrum, and numbers to correlate carbons with the signals in the 13 C spectrum. The mass spectrum of this compound shows the molecular ion at m/z 148.

Chapter 9, Problem 41P, Deduce the structure of the compound that gives the following 1H, 13C, and IR spectra (Fig. , example  1

Figure 9.43 The 1 H NMR spectrum (simulated) for Problem 9.41.

Chapter 9, Problem 41P, Deduce the structure of the compound that gives the following 1H, 13C, and IR spectra (Fig. , example  2

Figure 9.44 A simulated broadband proton-decoupled 13 C NMR spectrum for Problem 9.41. Information from the DEPT 13 C spectra is given above each peak.

Chapter 9, Problem 41P, Deduce the structure of the compound that gives the following 1H, 13C, and IR spectra (Fig. , example  3

Figure 9.45 The IR spectrum for Problem 9.41. (SDBS, National Institute of Advanced Industrial Science and Technology)

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Chapter 9 Solutions

ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT

Ch. 9 - PRACTICE PROBLEM 9.11 Draw the most stable chair...Ch. 9 - Prob. 12PPCh. 9 - PRACTICE PROBLEM 9.13 How many signals would you...Ch. 9 - Prob. 14PPCh. 9 - Prob. 15PPCh. 9 - Prob. 16PPCh. 9 - Prob. 17PPCh. 9 - PRACTICE PROBLEM 9.18 What are the expected ratios...Ch. 9 - Prob. 19PPCh. 9 - How many 1H NMR signals (not peaks) would you...Ch. 9 - How many 13C NMR signals would you predict for...Ch. 9 - Prob. 22PCh. 9 - Prob. 23PCh. 9 - Prob. 24PCh. 9 - Compound Q has the molecular formula C7H8. The...Ch. 9 - 9.26 Explain in detail how you would distinguish...Ch. 9 - Compound S (C8H16) reacts with one mole of bromine...Ch. 9 - A compound with molecular formula C4H8O has a...Ch. 9 - In the mass spectrum of 2, 6-dimethyl-4-heptanol...Ch. 9 - Prob. 30PCh. 9 - What are the masses and structures of the ions...Ch. 9 - Prob. 32PCh. 9 - Ethyl bromide and methoxybenzene (shown below)...Ch. 9 - 9.34 The homologous series of primary amines, ,...Ch. 9 - Propose a structure that is consistent with each...Ch. 9 - 9.36 Propose structures for compounds E and F....Ch. 9 - 9.37 Use the NMR and IR data below to propose a...Ch. 9 - 9.38 When dissolved in , a compound (K) with the...Ch. 9 - Compound T (C5H8O) has a strong IR absorption band...Ch. 9 - Prob. 40PCh. 9 - Deduce the structure of the compound that gives...Ch. 9 - Deduce the structure of the compound that gives...Ch. 9 - The 1H NMR spectrum of a solution of 1,...Ch. 9 - Acetic acid has a mass spectrum showing a...Ch. 9 - The 1H NMR peak for the hydroxyl proton of...Ch. 9 - The 1H NMR study of DMF (N, N-dimethylformamide)...Ch. 9 - 9.48 The mass spectra of many benzene derivatives...Ch. 9 - Prob. 49PCh. 9 - 1. Given the following information, elucidate the...Ch. 9 - Two compounds with the molecular formula C5H10O...
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