Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
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Question
Chapter 9, Problem 40PP
Interpretation Introduction
Interpretation:
The different alkene products formed for each given substrates when treated with a different reducing reagents are needed to be find out.
Concept Introduction:
Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.
Linder’s catalyst: The
Metal and ammonia reaction: The alkyne involves sodium (Na)/NH3. This end up reducing to alkyne to give the trans (E) alkene.
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Students have asked these similar questions
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Chapter 9 Solutions
Organic Chemistry
Ch. 9.2 - Prob. 1LTSCh. 9.2 - Prob. 1PTSCh. 9.2 - Prob. 2PTSCh. 9.2 - Prob. 3PTSCh. 9.2 - (+)-Citronella is the main compound responsible...Ch. 9.3 - Prob. 2LTSCh. 9.3 - Prob. 5PTSCh. 9.3 - Prob. 6ATSCh. 9.4 - Prob. 7CCCh. 9.4 - Prob. 8CC
Ch. 9.5 - Prob. 9CCCh. 9.5 - Prob. 10CCCh. 9.5 - Prob. 11CCCh. 9.5 - Prob. 12CCCh. 9.6 - Prob. 13CCCh. 9.6 - Prob. 14CCCh. 9.6 - Prob. 15CCCh. 9.7 - Prob. 3LTSCh. 9.7 - Prob. 16PTSCh. 9.7 - Prob. 17ATSCh. 9.7 - Prob. 18CCCh. 9.7 - Prob. 19CCCh. 9.7 - Prob. 20CCCh. 9.7 - Prob. 21CCCh. 9.7 - Prob. 4LTSCh. 9.7 - Prob. 22PTSCh. 9.7 - Proteases are enzymes that can break covalent...Ch. 9.9 - Prob. 24CCCh. 9.9 - Prob. 25CCCh. 9.9 - Prob. 26CCCh. 9.10 - Prob. 5LTSCh. 9.10 - Prob. 27PTSCh. 9.10 - (–)-Lepadiformine A, isolated from the marine...Ch. 9.11 - Prob. 6LTSCh. 9.11 - Prob. 29PTSCh. 9.11 - Prob. 30PTSCh. 9 - Prob. 32PPCh. 9 - Prob. 33PPCh. 9 - Prob. 34PPCh. 9 - Prob. 35PPCh. 9 - Prob. 36PPCh. 9 - Prob. 37PPCh. 9 - Prob. 38PPCh. 9 - Prob. 39PPCh. 9 - Prob. 40PPCh. 9 - Prob. 41PPCh. 9 - Prob. 42PPCh. 9 - Prob. 43PPCh. 9 - Prob. 44PPCh. 9 - Prob. 45PPCh. 9 - Prob. 46PPCh. 9 - Prob. 47PPCh. 9 - Prob. 48PPCh. 9 - Prob. 49PPCh. 9 - Prob. 50PPCh. 9 - Prob. 51PPCh. 9 - Prob. 52PPCh. 9 - Prob. 53PPCh. 9 - Prob. 54PPCh. 9 - Prob. 55PPCh. 9 - Prob. 56PPCh. 9 - Prob. 57IPCh. 9 - Prob. 58IPCh. 9 - Prob. 59IPCh. 9 - Prob. 60IPCh. 9 - Prob. 61IPCh. 9 - Prob. 62IPCh. 9 - Prob. 63IPCh. 9 - Prob. 64IPCh. 9 - Prob. 65IPCh. 9 - Prob. 66IPCh. 9 - Prob. 67IPCh. 9 - Prob. 68IPCh. 9 - Prob. 69IPCh. 9 - Prob. 70IPCh. 9 - Prob. 72IPCh. 9 - Prob. 73IPCh. 9 - Prob. 74IPCh. 9 - Prob. 75IPCh. 9 - Prob. 76CPCh. 9 - Prob. 77CPCh. 9 - The two lowest energy conformations of pentane are...Ch. 9 - Prob. 79CP
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