
Bundle: Chemistry, Loose-Leaf Version, 10th + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
10th Edition
ISBN: 9781337538015
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 9, Problem 35E
Interpretation Introduction
Interpretation: The reason for all the six atoms in
Concept introduction: When the atomic orbitals overlap with each other in the region where density of electrons is high, then molecular orbitals are formed. Overlap of the atomic orbitals determines the efficiency of the interaction between the atomic orbitals.
Energy of bonding molecular orbitals is less than the nonbonding molecular orbitals.
To determine: The reason for all the six atoms in
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Assign this HSQC Spectrum ( please editing clearly on the image)
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
Chapter 9 Solutions
Bundle: Chemistry, Loose-Leaf Version, 10th + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
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