EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781119227946
Author: Willard
Publisher: VST
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Chapter 9, Problem 2RQ
Interpretation Introduction
Interpretation:
The information which is needed to convert grams into moles of a compound has to be given.
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Draw the anti-Markovnikov product of the hydration of this alkene.
this problem.
Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 9 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 9.1 - Prob. 9.1PCh. 9.2 - Prob. 9.2PCh. 9.2 - Prob. 9.3PCh. 9.3 - Prob. 9.4PCh. 9.3 - Prob. 9.5PCh. 9.4 - Prob. 9.6PCh. 9.4 - Prob. 9.7PCh. 9.5 - Prob. 9.8PCh. 9.5 - Prob. 9.9PCh. 9.5 - Prob. 9.10P
Ch. 9 - Prob. 1RQCh. 9 - Prob. 2RQCh. 9 - Prob. 3RQCh. 9 - Prob. 4RQCh. 9 - Prob. 5RQCh. 9 - Prob. 6RQCh. 9 - Prob. 7RQCh. 9 - Prob. 8RQCh. 9 - Prob. 1PECh. 9 - Prob. 2PECh. 9 - Prob. 3PECh. 9 - Prob. 4PECh. 9 - Prob. 5PECh. 9 - Prob. 6PECh. 9 - Prob. 7PECh. 9 - Prob. 8PECh. 9 - Prob. 9PECh. 9 - Prob. 10PECh. 9 - Prob. 11PECh. 9 - Prob. 12PECh. 9 - Prob. 13PECh. 9 - Prob. 14PECh. 9 - Prob. 15PECh. 9 - Prob. 16PECh. 9 - Prob. 17PECh. 9 - Prob. 18PECh. 9 - Prob. 19PECh. 9 - Prob. 20PECh. 9 - Prob. 21PECh. 9 - Prob. 22PECh. 9 - Prob. 23PECh. 9 - Prob. 24PECh. 9 - Prob. 25PECh. 9 - Prob. 26PECh. 9 - Prob. 27PECh. 9 - Prob. 28PECh. 9 - Prob. 29PECh. 9 - Prob. 30PECh. 9 - Prob. 31PECh. 9 - Prob. 33AECh. 9 - Prob. 34AECh. 9 - Prob. 35AECh. 9 - Prob. 36AECh. 9 - Prob. 37AECh. 9 - Prob. 39AECh. 9 - Prob. 42AECh. 9 - Prob. 43AECh. 9 - Prob. 44AECh. 9 - Prob. 45AECh. 9 - Prob. 46AECh. 9 - Prob. 47AECh. 9 - Prob. 48AECh. 9 - Prob. 49AECh. 9 - Prob. 50AECh. 9 - Prob. 51AECh. 9 - Prob. 52AECh. 9 - Prob. 53AECh. 9 - Prob. 54AECh. 9 - Prob. 55AECh. 9 - Prob. 56AECh. 9 - Prob. 57AECh. 9 - Prob. 59CECh. 9 - Prob. 60CECh. 9 - Prob. 61CECh. 9 - Prob. 62CECh. 9 - Prob. 63CE
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