Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 9, Problem 22E
The space-filling models of hydrogen cyanide and phosgene are shown below.
Use the localized electron model to describe the bonding in hydrogen cyanide and phosgene.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Suppose that a molecule has four bonding groups and one lone pair on the central atom. Suppose further that the molecule is confined to two dimensions (this is a purely hypothetical assumption for the sake of understanding the principles behind VSEPR theory). Draw the molecule and estimate the bond angles.
Suppose that a molecule has four bonding groups and one lone pair on the central atom. Suppose further that the molecule is confined to two dimensions (this is a purely hypothetical assumption for the sake of understanding the principles behind VSEPR theory). Make a sketch of the molecule and estimate the bond angles.
The caffeine molecule is shown below. Indicate the electron geometry AND the molecular shape around each of the indicated atoms (six answers in total). Be aware that the angles may not be drawn correctly in this Lewis structure.
Chapter 9 Solutions
Chemistry
Ch. 9 - Why do we hybtidize atomic orbitals to explain the...Ch. 9 - What hybridization is required for central atoms...Ch. 9 - Describe the bonding in H2S, CH4, H2CO and HCN...Ch. 9 - What hybridization is required for central atoms...Ch. 9 - Electrons in bonding molecular orbitals are most...Ch. 9 - What are molecular orbitals? How do they compare...Ch. 9 - Explain the difference between the and MOs for...Ch. 9 - Compare Figs. 4-47 and 4-49. Why are they...Ch. 9 - Which of the following would you expect to be more...Ch. 9 - Draw the Lewis structure for HCN. Indicate the...
Ch. 9 - Which is the more correct statement: The methane...Ch. 9 - Compare and contrast the MO model with the local...Ch. 9 - What are the relationships among bond order, bond...Ch. 9 - In the hybrid orbital model, compare and contrast ...Ch. 9 - In the molecular orbital mode l, compare and...Ch. 9 - Why are d orbitals sometimes used to form hybrid...Ch. 9 - The atoms in a single bond can rotate about the...Ch. 9 - Compare and contrast bonding molecular orbitals...Ch. 9 - What modification to the molecular orbital model...Ch. 9 - Why does the molecular orbital model do a better...Ch. 9 - The three NO bonds in NO3 are all equivalent in...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - The space-filling models of ethane and ethanol are...Ch. 9 - The space-filling models of hydrogen cyanide and...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - For each of the following molecules, write the...Ch. 9 - For each of the following molecules or ions that...Ch. 9 - Prob. 31ECh. 9 - The allene molecule has the following Lewis...Ch. 9 - Indigo is the dye used in coloring blue jeans. The...Ch. 9 - Urea, a compound formed in the liver, is one of...Ch. 9 - Biacetyl and acetoin are added to margarine to...Ch. 9 - Many important compounds in the chemical industry...Ch. 9 - Two molecules used in the polymer industry are...Ch. 9 - Hot and spicy foods contain molecules that...Ch. 9 - One of the first drugs to be approved for use in...Ch. 9 - The antibiotic thiarubin-A was discovered by...Ch. 9 - Consider the following molecular orbitals formed...Ch. 9 - Sketch the molecular orbital and label its type (...Ch. 9 - Which of the following are predicted by the...Ch. 9 - Which of the following are predicted by the...Ch. 9 - Using the molecular orbital model, write electron...Ch. 9 - Consider the following electron configuration:...Ch. 9 - Using molecular orbital theory, explain why the...Ch. 9 - Using the molecular orbital model to describe the...Ch. 9 - The transport of O2 in the blood is carried out by...Ch. 9 - A Lewis structure obeying the octet rule can be...Ch. 9 - Using the molecular orbital model, write electron...Ch. 9 - Using the molecular orbital model, write electron...Ch. 9 - In which of the following diatomic molecules would...Ch. 9 - In terms of the molecular orbital model, which...Ch. 9 - Show how two 2p atomic orbitals can combine to...Ch. 9 - Show how a hydrogen 1s atomic orbital and a...Ch. 9 - Use Figs. 4-54 and 4-55 to answer the following...Ch. 9 - Acetylene (C2H2) can be produced from the reaction...Ch. 9 - Describe the bonding in NO+, NO, and NO, using...Ch. 9 - Describe the bonding in the O3 molecule and the...Ch. 9 - Describe the bonding in the CO32 ion using the...Ch. 9 - Draw the Lewis structures, predict the molecular...Ch. 9 - FClO2 and F3ClO can both gain a fluoride ion to...Ch. 9 - Two structures can be drawn for cyanuric acid: a....Ch. 9 - Give the expected hybridization for the molecular...Ch. 9 - Vitamin B6 is an organic compound whose deficiency...Ch. 9 - Aspartame is an artificial sweetener marketed...Ch. 9 - Prob. 69AECh. 9 - The three most stable oxides of carbon are carbon...Ch. 9 - Complete the following resonance structures for...Ch. 9 - Prob. 73AECh. 9 - Describe the bonding in the first excited state of...Ch. 9 - Using an MO energy-level diagram, would you expect...Ch. 9 - Show how a dxz. atomic orbital and a pz, atomic...Ch. 9 - What type of molecular orbital would result from...Ch. 9 - Consider three molecules: A, B, and C. Molecule A...Ch. 9 - Draw the Lewis structures for TeCl4, ICl5, PCl5,...Ch. 9 - A variety of chlorine oxide fluorides and related...Ch. 9 - Pelargondin is the molecule responsible for the...Ch. 9 - Complete a Lewis structure for the compound shown...Ch. 9 - Which of the following statements concerning SO2...Ch. 9 - Consider the molecular orbital electron...Ch. 9 - Place the species B2+ , B2, and B2 in order of...Ch. 9 - Consider the following computer-generated model of...Ch. 9 - Cholesterol (C27liu;O) has the following...Ch. 9 - Cyanamide (H2NCN), an important industrial...Ch. 9 - A flask containing gaseous N2 is irradiated with...Ch. 9 - Prob. 92CPCh. 9 - Values of measured bond energies may vary greatly...Ch. 9 - Use the MO model to explain the bonding in BeH2....Ch. 9 - Prob. 95CPCh. 9 - Arrange the following from lowest to highest...Ch. 9 - Use the MO model to determine which of the...Ch. 9 - Given that the ionization energy of F2 is 290...Ch. 9 - Carbon monoxide (CO) forms bonds to a variety of...Ch. 9 - Prob. 100CPCh. 9 - As the bead engineer of your starship in charge of...Ch. 9 - Determine the molecular structure and...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What aspect of the following Lewis structure indicates that the concept of coordinate covalency is needed to explain the bonding in the molecule?arrow_forwardThe Lewis structure for SF6 is shown below. This sulfur S atom in this molecule has an expanded octet, and you are not expected to be familiar with the specific electron geometry and molecular geometry for expanded octets. Still, we can make some predictions with the knowledge that we have. Would you predict the electron geometry and molecular geometry for SF6 to be the same or to differ? Please briefly explain your answer.arrow_forwardPredicting the arrangement of electron groups around the central atom of a molecule.arrow_forward
- A nonmetal atom from group 15 is designated X. Determine the number of bonding valence electrons and the number of nonbonding valence electrons in the structure of XCl3.arrow_forwardDescribe the bonding (including σ and п bonds) on an N atom in dinitrogen difluoride, N2F2, using valence bond theory.arrow_forwardGiven below is a Lewis structure skeleton of a molecule. Rank the C-N bonds, A, B, C, in terms of decreasing bond strength.arrow_forward
- Which statement best captures the fundamental idea behind VSEPR theory? Explain what is wrong with the statements you do not choose. a. The angle between two or more bonds is determined primarily by the repulsions between the electrons within those bonds and other (lone pair) electrons on the central atom of a molecule. Each of these electron groups (bonding electrons or lone pair electrons) lowers its potential energy by maximizing its separation from other electron groups, thus determining the geometry of the molecule. b. The angle between two or more bonds is determined primarily by the repulsions between the electrons within those bonds. Each of these bonding electrons lowers its potential energy by maximizing its separation from other electron groups, thus determining the geometry of the molecule. c. The geometry of a molecule is determined by the shapes of the overlapping orbitals that form the chemical bonds. Therefore, to determine the geometry of a molecule, you must determine…arrow_forwardThe molecular structure of hinokitiol is represented below (See attached image) Draw a complete Lewis structure of the molecule and answer the following questions. Complete the structure by adding ONLY hydrogen atoms to carbon atoms where needed. You must not create any other bonds. Atoms such as oxygen or nitrogen may have lone pairs to complete their octets. Each of the non-hydrogen atoms of this skeletal structure has been randomly numbered. Match the atom number with the orbital hybridization invoked for sigma bonding. Match these to the below (A)) (Options: sp3, sp2, sp, s, p, d2sp3, dsp3) A) 12, 9, 7, 2, 4 B) How many pairs of non-bonding electrons are there in the molecule? C) How many CH3 (methyl) groups are there in the molecule? D) How many CH2 (methylene) groups are there in the molecule? (i.e. # of C-atoms having exactly two bonded H-atoms) E) How many CH (methyne) groups are there in the molecule? (i.e. # of C-atoms having exactly one bonded H-atom) F) How many…arrow_forwardWhat The previous lesson helped us understand the compositions of molecules and their bonds through the Lewis structure theory. However, Lewis structures do not demonstrate one of the most important features of molecules-their overall shapes. The size and shapes of molecules are defined by the distances and angles between the nuclei of the atoms involved. In this lesson, we learn how to portrait a molecule by writing a two-dimensional structure for it and translating it to a three-dimensional shape, and we examine the effects of molecular shape on molecular polarity. What's New Activity 1: Review on Geometry Directions: Draw a two-dimensional or three-dimensional illustration of the following geometries: Example: Square Pyramidal: 1. Trigonal planar (2D) 2. Square Planar (3D) 3. Octahedral (3D) 4. Trigonal bipyramidal (3D) 5. Seesaw (3D) 13arrow_forward
- Why do you not need to specify the molecular shape for an atom with 1 electron group, such as AX1EN?arrow_forwardNitrogen is capable of forming single, double, or triple bonds, and the figure that follows shows the potential energy as a function of internuclear distance for each of these types of bonds. Match the three curves in the figure (A, B and C) to the three types of bonds. Explain your reasoning.arrow_forwardWhat is the molecular formula for this bond line structure?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY