Chemistry (Instructor's)
10th Edition
ISBN: 9781305957787
Author: ZUMDAHL
Publisher: CENGAGE L
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Textbook Question
Chapter 9, Problem 16Q
As compared with CO and O2, CS and S2 are very unstable molecules. Give an explanation based on the relative abilities of the sulfur and oxygen atoms to form π bonds.
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3.
2.
1.
On the graph below, plot the volume of rain in milliliters versus its height in centimeters for the 400 mL beaker. Draw a
straight line through the points and label it "400 mL beaker."
Volume (mL)
400
350
300
250
200
150
750 mL
Florence
Volume Versus Height of Water
400 mL
beaker
100
50
0
0
2 3
4
5
Height (cm)
6 7 8 9 10
Explain why the data points for the beaker lie roughly on a straight line. What kind of relationship is this? How do you know?
(see page 276 text) the design of the beaker is a uniform cylinder
the volume of liquid increases evenly with its height
resulting in a linear relationship.
What volume would you predict for 10.0 cm of water? Explain how you arrived at your answer. Use the data table and the
graph to assist you in answering the question.
4. Plot the volume of rain in milliliters versus its height in centimeters for the 250 mL Florence flask on the same graph. Draw a
best-fit curve through the points and label it "250 mL Florence flask."
oke came
Show work. Don't give Ai generated solution
In the video, we looked at the absorbance of a certain substance and how it varies
depending on what wavelength of light we are looking at. Below is a similar scan of a
different substance. What color BEST describes how this substance will appear?
Absorbance (AU)
Violet
Blue
Green
Orange
1.2
1.0-
0.8-
0.6-
0.4-
0.2
0.0
450
500
550
600
650
700
Wavelength (nm)
violet
indigo
blue
green
yellow orange
red
Red
O Cannot tell from this information
In the above graph, what causes -450 nm wavelength of light to have a higher
absorbance than light with a -550 nm wavelength? Check all that are true.
The distance the light travels is different
The different data points are for different substances
The concentration is different at different times in the experiment
Epsilon (molar absortivity) is different at different wavelengths
Chapter 9 Solutions
Chemistry (Instructor's)
Ch. 9 - Why do we hybtidize atomic orbitals to explain the...Ch. 9 - What hybridization is required for central atoms...Ch. 9 - Describe the bonding in H2S, CH4, H2CO and HCN...Ch. 9 - What hybridization is required for central atoms...Ch. 9 - Electrons in bonding molecular orbitals are most...Ch. 9 - What are molecular orbitals? How do they compare...Ch. 9 - Explain the difference between the and MOs for...Ch. 9 - Compare Figs. 4-47 and 4-49. Why are they...Ch. 9 - Which of the following would you expect to be more...Ch. 9 - Draw the Lewis structure for HCN. Indicate the...
Ch. 9 - Which is the more correct statement: The methane...Ch. 9 - Compare and contrast the MO model with the local...Ch. 9 - What are the relationships among bond order, bond...Ch. 9 - The molecules N2 and CO are isoelectronic but...Ch. 9 - Do lone pairs about a central atom affect the...Ch. 9 - In the hybrid orbital model, compare and contrast ...Ch. 9 - In the molecular orbital mode l, compare and...Ch. 9 - Why are d orbitals sometimes used to form hybrid...Ch. 9 - The atoms in a single bond can rotate about the...Ch. 9 - As compared with CO and O2, CS and S2 are very...Ch. 9 - Compare and contrast bonding molecular orbitals...Ch. 9 - What modification to the molecular orbital model...Ch. 9 - Why does the molecular orbital model do a better...Ch. 9 - The three NO bonds in NO3 are all equivalent in...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - Use the localized electron model to describe the...Ch. 9 - The space-filling models of ethane and ethanol are...Ch. 9 - The space-filling models of hydrogen cyanide and...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - Give the expected hybridization of the central...Ch. 9 - For each of the following molecules, write the...Ch. 9 - For each of the following molecules or ions that...Ch. 9 - Prob. 35ECh. 9 - The allene molecule has the following Lewis...Ch. 9 - Indigo is the dye used in coloring blue jeans. The...Ch. 9 - Urea, a compound formed in the liver, is one of...Ch. 9 - Biacetyl and acetoin are added to margarine to...Ch. 9 - Many important compounds in the chemical industry...Ch. 9 - Two molecules used in the polymer industry are...Ch. 9 - Hot and spicy foods contain molecules that...Ch. 9 - One of the first drugs to be approved for use in...Ch. 9 - Minoxidil (C9H15N15O) is a compound produced by...Ch. 9 - Consider the following molecular orbitals formed...Ch. 9 - Sketch the molecular orbital and label its type (...Ch. 9 - Which of the following are predicted by the...Ch. 9 - Which of the following are predicted by the...Ch. 9 - Using the molecular orbital model, write electron...Ch. 9 - Consider the following electron configuration:...Ch. 9 - Using the molecular orbital model to describe the...Ch. 9 - A Lewis structure obeying the octet rule can be...Ch. 9 - Using the molecular orbital model, write electron...Ch. 9 - Using the molecular orbital model, write electron...Ch. 9 - In which of the following diatomic molecules would...Ch. 9 - In terms of the molecular orbital model, which...Ch. 9 - Show how two 2p atomic orbitals can combine to...Ch. 9 - Show how a hydrogen 1s atomic orbital and a...Ch. 9 - Use Figs. 4-54 and 4-55 to answer the following...Ch. 9 - Acetylene (C2H2) can be produced from the reaction...Ch. 9 - Describe the bonding in NO+, NO, and NO, using...Ch. 9 - Describe the bonding in the O3 molecule and the...Ch. 9 - Describe the bonding in the CO32 ion using the...Ch. 9 - Draw the Lewis structures, predict the molecular...Ch. 9 - The antibiotic thiarubin-A was discovered by...Ch. 9 - Two structures can be drawn for cyanuric acid: a....Ch. 9 - Give the expected hybridization for the molecular...Ch. 9 - Vitamin B6 is an organic compound whose deficiency...Ch. 9 - Aspartame is an artificial sweetener marketed...Ch. 9 - Prob. 73AECh. 9 - The three most stable oxides of carbon are carbon...Ch. 9 - Complete the following resonance structures for...Ch. 9 - Prob. 77AECh. 9 - The transport of O2 in the blood is carried out by...Ch. 9 - Using molecular orbital theory, explain why the...Ch. 9 - Describe the bonding in the first excited state of...Ch. 9 - Using an MO energy-level diagram, would you expect...Ch. 9 - Show how a dxz. atomic orbital and a pz, atomic...Ch. 9 - What type of molecular orbital would result from...Ch. 9 - Consider three molecules: A, B, and C. Molecule A...Ch. 9 - Draw the Lewis structures for TeCl4, ICl5, PCl5,...Ch. 9 - A variety of chlorine oxide fluorides and related...Ch. 9 - Pelargondin is the molecule responsible for the...Ch. 9 - Complete a Lewis structure for the compound shown...Ch. 9 - Which of the following statements concerning SO2...Ch. 9 - Consider the molecular orbital electron...Ch. 9 - Place the species B2+ , B2, and B2 in order of...Ch. 9 - Consider the following computer-generated model of...Ch. 9 - Cholesterol (C27liu;O) has the following...Ch. 9 - Cyanamide (H2NCN), an important industrial...Ch. 9 - A flask containing gaseous N2 is irradiated with...Ch. 9 - Values of measured bond energies may vary greatly...Ch. 9 - Use the MO model to explain the bonding in BeH2....Ch. 9 - Prob. 101CPCh. 9 - Arrange the following from lowest to highest...Ch. 9 - Use the MO model to determine which of the...Ch. 9 - Given that the ionization energy of F2 is 290...Ch. 9 - Carbon monoxide (CO) forms bonds to a variety of...Ch. 9 - Prob. 106CPCh. 9 - As the bead engineer of your starship in charge of...Ch. 9 - Determine the molecular structure and...Ch. 9 - Although nitrogen trifluoride (NF3) is a thermally...
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- 2. Give the ground state electron configuration (e.g., 02s² σ*2s² П 2p²) for these molecules and deduce its bond order. Ground State Configuration Bond Order H2+ 02- N2arrow_forward1. This experiment is more about understanding the colligative properties of a solution rather than the determination of the molar mass of a solid. a. Define colligative properties. b. Which of the following solutes has the greatest effect on the colligative properties for a given mass of pure water? Explain. (i) 0.01 mol of CaCl2 (ii) 0.01 mol of KNO3 (iii) 0.01 mol of CO(NH2)2 (an electrolyte) (an electrolyte) (a nonelectrolyte)arrow_forward5. b. For Trials 2 and 3, the molar mass of the solute was 151 g/mol and 143 g/mol respectively. a. What is the average molar mass of the solute ? b. What are the standard deviation and the relative standard deviation (%RSD) for the molar mass of the solute ?arrow_forward
- Show work. Don't give Ai generated solutionarrow_forward2. Explain why ice cubes formed from water of a glacier freeze at a higher temperature than ice cubes formed from water of an under- ground aquifer. Photodynamic/iStockphotoarrow_forwardShow reaction mechanism. don't give Ai generated solutionarrow_forward
- 7. Draw the Lewis structures and molecular orbital diagrams for CO and NO. What are their bond orders? Are the molecular orbital diagrams similar to their Lewis structures? Explain. CO Lewis Structure NO Lewis Structure CO Bond Order NO Bond Order NO Molecular Orbital Diagram CO Molecular Orbital Diagramarrow_forward5. The existence of compounds of the noble gases was once a great surprise and stimulated a great deal of theoretical work. Label the molecular orbital diagram for XeF (include atom chemical symbol, atomic orbitals, and molecular orbitals) and deduce its ground state electron configuration. Is XeF likely to have a shorter bond length than XeF+? Bond Order XeF XeF+arrow_forward6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic. B22+ B22+, B2, C22, B22 and N22+ Molecular Orbital Diagram B2 C22- B22- N22+ Which molecule is paramagnetic?arrow_forward
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