INTO TO CHEMISTRY (EBOOK ACCESS CODE)
5th Edition
ISBN: 9781307892864
Author: BAUER
Publisher: MCG
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Chapter 9, Problem 16PP
Interpretation Introduction
Interpretation:
The volume is to be calculated at the pressure of
Concept Introduction:
A graph is plotted between two variables to describe or study how one variable affects the values of another variable. The value of one variable for a particular value of another variable can be calculated using the drawn graph.
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3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Show the mechanism for these reactions
Chapter 9 Solutions
INTO TO CHEMISTRY (EBOOK ACCESS CODE)
Ch. 9 - Prob. 1QCCh. 9 - Prob. 2QCCh. 9 - Prob. 3QCCh. 9 - Prob. 4QCCh. 9 - Prob. 5QCCh. 9 - Prob. 1PPCh. 9 - Prob. 2PPCh. 9 - What pressure is needed to compress 455 mL of...Ch. 9 - Prob. 4PPCh. 9 - Prob. 5PP
Ch. 9 - Prob. 6PPCh. 9 - Prob. 7PPCh. 9 - Prob. 8PPCh. 9 - Prob. 9PPCh. 9 - Prob. 10PPCh. 9 - Prob. 11PPCh. 9 - Prob. 12PPCh. 9 - Prob. 13PPCh. 9 - Prob. 14PPCh. 9 - Prob. 15PPCh. 9 - Prob. 16PPCh. 9 - Prob. 17PPCh. 9 - Prob. 18PPCh. 9 - Prob. 1QPCh. 9 - Prob. 2QPCh. 9 - Prob. 3QPCh. 9 - Prob. 4QPCh. 9 - A series of organic compounds called the alkanes...Ch. 9 - Prob. 6QPCh. 9 - Prob. 7QPCh. 9 - Prob. 8QPCh. 9 - Prob. 9QPCh. 9 - Prob. 10QPCh. 9 - Prob. 11QPCh. 9 - Prob. 12QPCh. 9 - Prob. 13QPCh. 9 - Prob. 14QPCh. 9 - Prob. 15QPCh. 9 - Prob. 16QPCh. 9 - Prob. 17QPCh. 9 - Prob. 18QPCh. 9 - Prob. 19QPCh. 9 - Prob. 20QPCh. 9 - Prob. 21QPCh. 9 - Prob. 22QPCh. 9 - Prob. 23QPCh. 9 - Prob. 24QPCh. 9 - Prob. 25QPCh. 9 - Prob. 26QPCh. 9 - Prob. 27QPCh. 9 - Prob. 28QPCh. 9 - Prob. 29QPCh. 9 - Prob. 30QPCh. 9 - Prob. 31QPCh. 9 - Prob. 32QPCh. 9 - Prob. 33QPCh. 9 - Prob. 34QPCh. 9 - Prob. 35QPCh. 9 - Prob. 36QPCh. 9 - Prob. 37QPCh. 9 - Prob. 38QPCh. 9 - Prob. 39QPCh. 9 - Prob. 40QPCh. 9 - Prob. 41QPCh. 9 - Prob. 42QPCh. 9 - Prob. 43QPCh. 9 - Prob. 44QPCh. 9 - Prob. 45QPCh. 9 - Prob. 46QPCh. 9 - Prob. 47QPCh. 9 - Prob. 48QPCh. 9 - Prob. 49QPCh. 9 - Prob. 50QPCh. 9 - Prob. 51QPCh. 9 - Prob. 52QPCh. 9 - Prob. 53QPCh. 9 - Prob. 54QPCh. 9 - Prob. 55QPCh. 9 - Prob. 56QPCh. 9 - Prob. 57QPCh. 9 - Prob. 58QPCh. 9 - Prob. 59QPCh. 9 - Prob. 60QPCh. 9 - Prob. 61QPCh. 9 - Prob. 62QPCh. 9 - Prob. 63QPCh. 9 - Prob. 64QPCh. 9 - Prob. 65QPCh. 9 - Prob. 66QPCh. 9 - Prob. 67QPCh. 9 - Prob. 68QPCh. 9 - Prob. 69QPCh. 9 - Prob. 70QPCh. 9 - Prob. 71QPCh. 9 - Prob. 72QPCh. 9 - Prob. 73QPCh. 9 - Prob. 74QPCh. 9 - Prob. 75QPCh. 9 - Prob. 76QPCh. 9 - Prob. 77QPCh. 9 - Prob. 78QPCh. 9 - Prob. 79QPCh. 9 - Prob. 80QPCh. 9 - Prob. 81QPCh. 9 - Prob. 82QPCh. 9 - Prob. 83QPCh. 9 - Prob. 84QPCh. 9 - Prob. 85QPCh. 9 - Prob. 86QPCh. 9 - Prob. 87QPCh. 9 - Prob. 88QPCh. 9 - Prob. 89QPCh. 9 - Prob. 90QPCh. 9 - Prob. 91QPCh. 9 - Prob. 92QPCh. 9 - Prob. 93QPCh. 9 - Prob. 94QPCh. 9 - Prob. 95QPCh. 9 - Prob. 96QPCh. 9 - Prob. 97QPCh. 9 - Prob. 98QPCh. 9 - Prob. 99QPCh. 9 - Prob. 100QPCh. 9 - Prob. 101QPCh. 9 - Prob. 102QPCh. 9 - Prob. 103QPCh. 9 - Prob. 104QPCh. 9 - Prob. 105QPCh. 9 - Prob. 106QPCh. 9 - Prob. 107QPCh. 9 - Prob. 108QPCh. 9 - Prob. 109QPCh. 9 - Prob. 110QPCh. 9 - Prob. 111QPCh. 9 - Prob. 112QPCh. 9 - Prob. 113QPCh. 9 - Prob. 114QPCh. 9 - Prob. 115QPCh. 9 - Prob. 116QPCh. 9 - Prob. 117QPCh. 9 - Prob. 118QPCh. 9 - Prob. 119QPCh. 9 - Prob. 120QPCh. 9 - Prob. 121QPCh. 9 - Prob. 122QPCh. 9 - Prob. 123QPCh. 9 - Prob. 124QPCh. 9 - Prob. 125QPCh. 9 - Prob. 126QPCh. 9 - Prob. 127QPCh. 9 - Prob. 128QPCh. 9 - Prob. 129QPCh. 9 - Prob. 130QPCh. 9 - Prob. 131QPCh. 9 - Prob. 132QPCh. 9 - Prob. 133QPCh. 9 - Prob. 134QPCh. 9 - Prob. 135QPCh. 9 - Prob. 136QPCh. 9 - Prob. 137QPCh. 9 - Prob. 138QPCh. 9 - Prob. 139QPCh. 9 - Prob. 140QPCh. 9 - Prob. 141QPCh. 9 - Prob. 142QPCh. 9 - Prob. 143QPCh. 9 - Prob. 144QPCh. 9 - Prob. 145QPCh. 9 - Prob. 146QPCh. 9 - Prob. 147QPCh. 9 - Prob. 148QPCh. 9 - Prob. 149QPCh. 9 - Prob. 150QPCh. 9 - Prob. 151QPCh. 9 - Prob. 152QPCh. 9 - Prob. 153QPCh. 9 - Prob. 154QPCh. 9 - Prob. 155QPCh. 9 - Prob. 156QPCh. 9 - Prob. 157QPCh. 9 - Prob. 158QPCh. 9 - Prob. 159QPCh. 9 - Prob. 160QPCh. 9 - Prob. 161QPCh. 9 - Prob. 162QPCh. 9 - Prob. 163QPCh. 9 - Prob. 164QPCh. 9 - Prob. 165QPCh. 9 - Butane burns with oxygen according to the...Ch. 9 - Prob. 167QP
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- Draw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forward
- Draw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forward
- What are the IUPAC Names of all the compounds in the picture?arrow_forward1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forward
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