Laboratory Experiments For Chemistry: The Central Science, Si Edition
14th Edition
ISBN: 9781292221335
Author: Theodore E. Brown
Publisher: PEARSON
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Chapter 9, Problem 13E
Interpretation Introduction
(a) To determine:
The number of non bonding electron pairs present around
Interpretation Introduction
(b) To determine:
The number of non bonding electrons around Xe in XeF2.
Interpretation Introduction
(c) To determine:
Is XeF2 linear.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
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mixture to facilitate their separation into different phases. The key to understanding how liquid-
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The following liquid-liquid extraction is different from the one you performed in Experiment
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. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
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b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 9 Solutions
Laboratory Experiments For Chemistry: The Central Science, Si Edition
Ch. 9.2 - Consider the following AB3 molecules and ions-...Ch. 9.2 - Prob. 9.1.2PECh. 9.2 - Prob. 9.2.1PECh. 9.2 - Prob. 9.2.2PECh. 9.2 - Prob. 9.3.1PECh. 9.2 - Prob. 9.3.2PECh. 9.3 - Prob. 9.4.1PECh. 9.3 - Determine whether the following molecules are...Ch. 9.5 - Prob. 9.5.1PECh. 9.5 - Prob. 9.5.2PE
Ch. 9.6 - Prob. 9.6.1PECh. 9.6 - Prob. 9.6.2PECh. 9.6 - Prob. 9.7.1PECh. 9.6 - Prob. 9.7.2PECh. 9.7 - Prob. 9.8.1PECh. 9.7 - Prob. 9.8.2PECh. 9.8 - Prob. 9.9.1PECh. 9.8 - Prob. 9.9.2PECh. 9 - Prob. 1DECh. 9 - 9.1 A certain AB4, molecule has a "seesaw" shape...Ch. 9 - Prob. 2ECh. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Prob. 5ECh. 9 - Prob. 6ECh. 9 - In the hydrocarbon a. What is the hybridization at...Ch. 9 - The drawing below shows the overlap of two hybrid...Ch. 9 - Prob. 9ECh. 9 -
9.10 The following is part of a molecular...Ch. 9 - Prob. 11ECh. 9 - Prob. 12ECh. 9 -
9.13
a. An AB2 molecule is linear. How...Ch. 9 - a. Methane (CH4) and the perchlorate ion (C104-)...Ch. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Prob. 18ECh. 9 - In which of these molecules or ions does the...Ch. 9 - Prob. 20ECh. 9 - How many nonbonding electron pairs are there in...Ch. 9 - Prob. 22ECh. 9 - Prob. 23ECh. 9 - Prob. 24ECh. 9 - Give the electron-domain and molecular geometries...Ch. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - Prob. 30ECh. 9 - Ammonia, NH3 reacts with incredibly strong bases...Ch. 9 - In which of the following AFn molecules or ions is...Ch. 9 - a. Explain why BrF4 is square planar, whereas...Ch. 9 -
9.34 Name the proper three-dimensional molecule...Ch. 9 - Prob. 35ECh. 9 - Prob. 36ECh. 9 - Prob. 37ECh. 9 - Prob. 38ECh. 9 - a. (a) Is the molecule BF3 polar or nonpolar? b....Ch. 9 - Prob. 40ECh. 9 - Predict whether each of the following molecules is...Ch. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Prob. 44ECh. 9 - For each statement, irldicate whether it is true...Ch. 9 - Draw sketches illustrating the overlap between the...Ch. 9 - For each statement, indicate whether it is true or...Ch. 9 - Prob. 48ECh. 9 - Prob. 49ECh. 9 - Consider the SC12 molecule. a. What IS the...Ch. 9 - Indicate the hybridization of the central atom in...Ch. 9 - Prob. 52ECh. 9 - Prob. 53ECh. 9 - Prob. 54ECh. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - a. Draw Lewis structures for ethane (C2He),...Ch. 9 - a. Draw Lewis structures for ethane (C2He),...Ch. 9 - Prob. 59ECh. 9 - Ethyl acetate. C4H802, is a fragrant substance...Ch. 9 - Prob. 61ECh. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - In the formate ion, HC02- , the carbon atom is the...Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - a. If you combine two atomic orbitals on two...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Prob. 73ECh. 9 - Indicate whether each statement is true or false....Ch. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Prob. 77ECh. 9 - Prob. 78ECh. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Determine the electron configurations for CN+, CN,...Ch. 9 - Prob. 82ECh. 9 - Consider the molecular orbitals of the P2...Ch. 9 - The iodine bromide molecule, IBr, is an...Ch. 9 - Prob. 85AECh. 9 - Prob. 86AECh. 9 - Consider the following XF4 ions: PF4, BrF4-,...Ch. 9 -
9.88 Consider the molecule PF4Cl....Ch. 9 - Prob. 89AECh. 9 - Fill in the blank spaces in the following chart....Ch. 9 - Prob. 91AECh. 9 - Prob. 92AECh. 9 - Prob. 93AECh. 9 - Prob. 94AECh. 9 - Prob. 95AECh. 9 - Prob. 96AECh. 9 - Prob. 97AECh. 9 - Prob. 98AECh. 9 - Prob. 99AECh. 9 - Prob. 100AECh. 9 - In ozone, 03, the two oxygen atoms on the ends Of...Ch. 9 - Butadiene, C4H6, is a planar molecule that has the...Ch. 9 - The structure of borazine, B3N3H6, is a...Ch. 9 - Prob. 104AECh. 9 - Prob. 105AECh. 9 - Prob. 106AECh. 9 - Prob. 107AECh. 9 - Prob. 108AECh. 9 - Azo dyes are organic dyes that are used for many...Ch. 9 - a. Using only the valence atomic orbitals of a...Ch. 9 - Carbon monoxide, CO, is isoelectronic to N2. a....Ch. 9 - The energy-level diagram in Figure 9.36 shows that...Ch. 9 - A compound composed of 2.1 29.8%N, and 68.1%O has...Ch. 9 -
9.114 Sulfur tetrafluoride (SR4) reacts slowly...Ch. 9 - Prob. 115IECh. 9 - The molecule 2-butene, C4Hs, can undergo a...Ch. 9 - Prob. 117IECh. 9 - Use average bond enthalpies (Table 8.3 ) to...Ch. 9 - Prob. 119IECh. 9 - Prob. 120IECh. 9 - Prob. 121IECh. 9 - Prob. 122IE
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
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