University Physics Volume 3
17th Edition
ISBN: 9781938168185
Author: William Moebs, Jeff Sanny
Publisher: OpenStax
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 9, Problem 13CQ
The NaCl crystal structure is FCC. The equilibrium spacing is
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
In solid KCI the smallest distance between the centers of a. potassium ion and a chloride ion is 314 pm. Calculate the length of the edge of the unit cell and the density of KCI, assuming it has the same structure as sodium chloride.
The ionic crystal of NaCl has an fcc structure as
shown below with the position of the Cl atom
located at : (0 0 0); (½ ½ 0); ( ½ 0 %) and (0
½) and Na atom is located at : (½ ½½) + fcc
translation.
The following are the physical data of NaCl:
- Ionic radius Na = 0.98 A, Cl ion radius
1.81 A
Atomic mass of Na = 22.99 amu, Atomic
mass of Cl = 35.45 amu
NaCl bulk modulus = 2.40 x 1010 N/m
- Madelung's constant = 1.75
Young's modulus in the direction [100] = 5
x 1010 Nm-2
Debye temperature = 281 K
-
State the structural factors of NaCl, F in
fNa and fCl (f = atomic scattering factor).
Also determine the condition (h k 1) so that
the value of F = 0.
The elements A and B crystallize in bcc and fcc structures, respectively. Suppose that (i) the crystals of A
and B have the same density, and (ii) the nearest-neighbor distances in these crystals are equal. Calculate the
ratio MA/MB, where MA and MB denote the masses of the A and B atoms, respectively.
Chapter 9 Solutions
University Physics Volume 3
Ch. 9 - Check Your Understanding Why is the potential...Ch. 9 - Check Your Understanding What does the energy...Ch. 9 - Check Your Understanding If the dissociation...Ch. 9 - Check Your Understanding What happens to the...Ch. 9 - Check Your Understanding How does the magnitude of...Ch. 9 - Check Your Understanding What conditions are...Ch. 9 - What is the main difference between an ionic bond,...Ch. 9 - For the following cases, what type of bonding...Ch. 9 - Describe three steps to ionic bonding.Ch. 9 - What prevents a positive and negative ion from...
Ch. 9 - For the H2 molecule, why must the spins the...Ch. 9 - Does the absorption spectrum of the diatomic...Ch. 9 - Rank the energy spacing (E) of the following...Ch. 9 - Explain key features of a vibrational-rotation...Ch. 9 - Why is tbe equilibrium separation distance between...Ch. 9 - Describe the difference between a face-centered...Ch. 9 - In sodium chloride, how many Clatoms are “nearest...Ch. 9 - In cesium iodide, how many Clatoms are "nearest...Ch. 9 - The NaCl crystal structure is FCC. The equilibrium...Ch. 9 - Why does the Fermi energy (EF) increase with the...Ch. 9 - If the election number density (N/V) of a metal...Ch. 9 - Why does the horizontal Line in the graph in...Ch. 9 - Why does the graph in Figure 9.12 increase...Ch. 9 - Why are the sharp transitions at the Fermi energy...Ch. 9 - What are the two main approaches used to determine...Ch. 9 - Describe two features of energy levels for an...Ch. 9 - How does the number of energy levels in a band...Ch. 9 - Why are some materials very good conductors and...Ch. 9 - Why are some materials semiconductors?Ch. 9 - Why does the resistance of a semiconductor...Ch. 9 - What kind of semiconductor is produced if...Ch. 9 - What kind of semiconductor is produced if silicon...Ch. 9 - What is the Hall effect and what is it used for?Ch. 9 - For an n-type semiconductor, how do impurity atoms...Ch. 9 - For a p-type semiconductor, how do impurity atoms...Ch. 9 - When p- and n-type materials are joined, why is a...Ch. 9 - When p- and n-type materials are joined, why does...Ch. 9 - How do you know if a diode is in the forward...Ch. 9 - Why does the reverse bias configuration lead to a...Ch. 9 - What happens in the extreme case that where the n-...Ch. 9 - Explain how an audio amplifier works, using the...Ch. 9 - Describe two main features of a superconductor.Ch. 9 - How does BCS theory explain superconductivity?Ch. 9 - What is the Meissner effect?Ch. 9 - What impact does an increasing magnetic field have...Ch. 9 - The electron configuration of carbon is 1s22s22p2....Ch. 9 - Potassium chloride (KCl) is a molecule formed by...Ch. 9 - The electron affinity of Cl is 3.89 eV and the...Ch. 9 - The measured energy dissociated energy of KC1 is...Ch. 9 - In a physics lab, you measure the vibrational-...Ch. 9 - For the preceding problem, find the equilibrium...Ch. 9 - The separation between oxygen atoms in an O2...Ch. 9 - The characteristic energy of the N2 molecule is...Ch. 9 - The characteristic energy for KCl is 1.4105eV ....Ch. 9 - A diatomic F2 molecule is in the l = 1 state, (a)...Ch. 9 - In a physics lab, you measure the vibrational-...Ch. 9 - The Csl crystal structure is BCC. The equilibrium...Ch. 9 - The potential energy of a crystal is - 8.10 eV/ion...Ch. 9 - The measured density of a NaF crystal is 2.558...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - Determine the dissociation energy of 12 moles of...Ch. 9 - The measured density of a KCl crystal is 1.984...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - The measured density of a CsCl crystal is 3.988...Ch. 9 - What is the difference in energy between the...Ch. 9 - An electron is confined to a metal cube of I = 0.8...Ch. 9 - What value of energy corresponds to a density of...Ch. 9 - Compare the density of states at 2.5 eV and 0.25...Ch. 9 - Consider a cube of copper with edges 1.50 mm long....Ch. 9 - If there is one free electron per atom of copper,...Ch. 9 - Determine the Fermi energy and temperature for...Ch. 9 - For a one-dimensional crystal, write the lattice...Ch. 9 - What is the main difference between an insulator...Ch. 9 - What is the longest wavelength for a photon that...Ch. 9 - A valence electron in a crystal absorbs a photon...Ch. 9 - An experiment is performed to demonstrate the Hall...Ch. 9 - Suppose that the cross-sectional area of the strip...Ch. 9 - A current-carrying copper wire with cross-section...Ch. 9 - The Hall effect is demonstrated in the laboratory....Ch. 9 - Show that for V less than zero, InetI0.Ch. 9 - A p-n diode has a reverse saturation current...Ch. 9 - The collector current of a transistor is 3.4 A for...Ch. 9 - Applying the positive end of a battery to the...Ch. 9 - The base current of a transistor is 4.4 A, and its...Ch. 9 - At what temperature, in terms of Tc, is the...Ch. 9 - What is the critical magnetic field for lead at T...Ch. 9 - A Pb wire wound in a tight solenoid of diameter of...Ch. 9 - A tightly wound solenoid at 4.0 K is 50 cm long...Ch. 9 - Potassium fluoride (KF) is a molecule formed by...Ch. 9 - For the preceding problem, sketch the potential...Ch. 9 - The separation between hydrogen atoms in a H2...Ch. 9 - The characteristic energy of the Cl2 molecule is...Ch. 9 - Determine the lowest three rotational energy...Ch. 9 - A carbon atom can hybridize in the...Ch. 9 - List five main characteristics of ionic crystals...Ch. 9 - Why is bonding in favorable? Express your answer...Ch. 9 - Astronomers claim to find evidence of He2 from...Ch. 9 - Show that the moment of inertia of a diatomic...Ch. 9 - Show that the average energy of an electron in a...Ch. 9 - Measurements of a superconductor's critical...Ch. 9 - Estimate the fraction of Si atoms that must be...Ch. 9 - Transition in the rotation spectrum are observed...Ch. 9 - Determine the Fermi energies for (a) Mg, (b) Na,...Ch. 9 - Find the average energy of an electron in a Zn...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - A physical model of a diamond suggests packing...Ch. 9 - For an electron in a three-dimensional metal, show...
Additional Science Textbook Solutions
Find more solutions based on key concepts
Find the following for path D in Figure 2.59: (a) The distance traveled. (b) The magnitude of the displacement ...
College Physics
68. The horizontal pipe shown in Figure 13.45 has a cross-sectional area of 40.0 cm2 at the wider portions and ...
College Physics (10th Edition)
6. For a simple harmonic oscillator, when (if ever) are the displacement and velocity vectors in the same direc...
Physics: Principles with Applications
The force, when you push against a wall with your fingers, they bend.
Conceptual Physics (12th Edition)
1. If an object is not moving, does that mean that there are no forces acting on it? Explain.
College Physics: A Strategic Approach (4th Edition)
Knowledge Booster
Similar questions
- The measured density of a KCl crystal is 1.984 g/cm3. What is the equilibrium separation distance of K+ and Cl- ions?arrow_forwardThe measured density of a NaF crystal is 2.558 g/cm3 . What is the equilibrium separate distance of Na+ and Flions?arrow_forwardPls help ASAP. Pls show all work annd circle the final answer.arrow_forward
- Hcp structure . Show that the c/a ratio for an ideal hexagonal close- packed structure is (8/3)^1/2 = 1.633 . if c/a is significantly larger than this value , the crystal structure may be thought of as composed of planes of closely packed atoms, the planes being loosely stacked.arrow_forwardConsider a face centered cubic (fcc) crystal in which one atom is placed at each lattice point. The lattice constant is a = 0.7 \: nma=0.7nm. Calculate the volume density of atoms (i.e. number of atoms per unit volume) in units of cm^{-3}cm−3. Values within 5% error will be considered correct.arrow_forwardBody-centered cubic structure. (a) Show that for BCC the lattice length a in terms of the atomic radius is 4R/√3. (b) Calculate the volume of a BCC unit cell in terms of the atomic radius R. (c) Show that the atomic packing factor for the BCC crystal structure is 0.68.arrow_forward
- At 23° K, the crystal structure transforms from BCC to HCP keeping density same. The cubic face in BCC is a 3.42 A and in HCP is-1.53. The lattice constant in HCP structure is, (n) 2.64 A (b) 3.16 A () 2.16 A (4) 2.42 Aarrow_forwardCu Assume that the crystal structure of metallic copper (Cu) results in a density of atoms p = 8.46 × 10²m 3. Each Cu atom in the crystal donates one electron to the conduction band, which leads, for the 3-D Fermi gas, to a densityu of states g(ɛ) = 2 x = ( 2 m ² ) ² 1/2 where m is the effective mass of the conduction electrons. In the low temperature limit (i.c. T = 0 K), find the Fermi energy E, in units of eV. You may assume m* to be equal to the free electron mass marrow_forwardAt 23° K, the crystal structure transforms from BCC to HCP keeping density same. The cubic face in BCC is a= 3.42 A and in HCP is = 1.53. The lattice constant in HCP structure is, (а) 2.64 A (b) 3.16 А (c) 2.16 A (d) 2.42 Aarrow_forward
- SOLID STATE physicsarrow_forwardHcp structure. Show that the cla ratio for an ideal hexagonal close-packed strue- ture is 2 = 1.633. If cla is significantly larger than this value, the crystal structure be thought of as composed of planes of closely packed atoms, the planes being loosely stacked. %3D mayarrow_forwardWhen the ions at their equilibrium interionic separation, the force of attraction between a divalent (valency of 2) cation and a monovalent (valency of 1) anion is 7.32 × 10−9 N. If the ionic radius of the cation is 0.05 nm, what is the anion radius (nm)? Round your result to 2 decimal place.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Modern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage LearningUniversity Physics Volume 3PhysicsISBN:9781938168185Author:William Moebs, Jeff SannyPublisher:OpenStaxPhysics for Scientists and Engineers with Modern ...PhysicsISBN:9781337553292Author:Raymond A. Serway, John W. JewettPublisher:Cengage Learning
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning
University Physics Volume 3
Physics
ISBN:9781938168185
Author:William Moebs, Jeff Sanny
Publisher:OpenStax
Physics for Scientists and Engineers with Modern ...
Physics
ISBN:9781337553292
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning