The molecular formula of compound A is C 6 H 12 . It reacts with one molar equivalent of H 2 /Pd. It reacts with OsO 4 to give the diol B. When oxidized with KMnO 4 , A gives propanoic acid and a ketone . The structures of A, B, C are to be given. All the reactions are to be written and explained. Concept introduction: From the molecular formula the degree of unsaturation can be calculated. The reaction with H 2 /Pd and that with OsO 4 shows the presence of double bonds. When oxidized with KMnO 4 a disubstituted carbon in a double bond is converted in to a ketone and a monosubstituted carbon in double bond gives a carboxylic acid . To give: The structures of compounds A, B and C which accounts for the reactions

Question

Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.SE, Problem 59AP

Interpretation Introduction

Interpretation:

The molecular formula of compound A is C₆H₁₂. It reacts with one molar equivalent of H₂/Pd. It reacts with OsO₄ to give the diol B. When oxidized with KMnO₄, A gives propanoic acid and a ketone. The structures of A, B, C are to be given. All the reactions are to be written and explained.

Concept introduction:

From the molecular formula the degree of unsaturation can be calculated. The reaction with H₂/Pd and that with OsO₄ shows the presence of double bonds. When oxidized with KMnO₄ a disubstituted carbon in a double bond is converted in to a ketone and a monosubstituted carbon in double bond gives a carboxylic acid.

To give:

The structures of compounds A, B and C which accounts for the reactions

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Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)

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Draw a reasonable mechanism for the following reaction:

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.SE, Problem 59AP

Interpretation Introduction

Interpretation:

The molecular formula of compound A is C₆H₁₂. It reacts with one molar equivalent of H₂/Pd. It reacts with OsO₄ to give the diol B. When oxidized with KMnO₄, A gives propanoic acid and a ketone. The structures of A, B, C are to be given. All the reactions are to be written and explained.

Concept introduction:

From the molecular formula the degree of unsaturation can be calculated. The reaction with H₂/Pd and that with OsO₄ shows the presence of double bonds. When oxidized with KMnO₄ a disubstituted carbon in a double bond is converted in to a ketone and a monosubstituted carbon in double bond gives a carboxylic acid.

To give:

The structures of compounds A, B and C which accounts for the reactions

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.SE, Problem 59AP

Interpretation Introduction

Interpretation:

The molecular formula of compound A is C₆H₁₂. It reacts with one molar equivalent of H₂/Pd. It reacts with OsO₄ to give the diol B. When oxidized with KMnO₄, A gives propanoic acid and a ketone. The structures of A, B, C are to be given. All the reactions are to be written and explained.

Concept introduction:

From the molecular formula the degree of unsaturation can be calculated. The reaction with H₂/Pd and that with OsO₄ shows the presence of double bonds. When oxidized with KMnO₄ a disubstituted carbon in a double bond is converted in to a ketone and a monosubstituted carbon in double bond gives a carboxylic acid.

To give:

The structures of compounds A, B and C which accounts for the reactions

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.SE, Problem 59AP

Interpretation Introduction