Resonance hybrid of the given species has to be drawn. Concept Introduction: Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

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Answer 1

Question

Chapter 8.5, Problem 5P

(a)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(b)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(c)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(d)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(e)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(f)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Answer 2

Question

Chapter 8.5, Problem 5P

(a)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(b)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(c)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(d)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(e)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(f)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

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Answer 3

Question

Chapter 8.5, Problem 5P

(a)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(b)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(c)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(d)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(e)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(f)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Expert Solution & Answer

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Answer 4

Question

Chapter 8.5, Problem 5P

(a)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(b)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(c)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(d)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(e)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(f)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Expert Solution & Answer

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Answer 5

Chapter 8.5, Problem 5P

(a)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(b)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(c)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(d)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(e)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

(f)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 6

Chapter 8.5, Problem 5P

(a)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 7

Chapter 8.5, Problem 5P

(a)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Resonance hybrid of the given species has to be drawn.

Concept Introduction:

Resonance hybrid is overall structure of a molecule or ion with delocalized or conjugated electrons which represents the various contributing forms of the molecule or ion. Those resonance forms are also termed as canonical forms.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 5P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 7P Ch. 8.6 - Prob. 8P Ch. 8.8 - Prob. 9P Ch. 8.9 - Prob. 10P Ch. 8.9 - Prob. 12P

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