CHEM FOR ENGNRNG SDNTS (EBOOK) W/ACCES
3rd Edition
ISBN: 9781337739382
Author: Brown
Publisher: CENGAGE L
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Chapter 8, Problem 8.86PAE
Interpretation Introduction
Interpretation:
Micro actuators function should be identified.
Concept introduction:
Micro actuators convert input energy (electrical signal) into controlled mechanical energy. It produces motion of very small magnitude from
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NaCl and KF have the same crystal structure. The only differencebetween the two is the distance that separates cationsand anions. (a) The lattice energies of NaCl and KF are givenin Table 8.1. Based on the lattice energies, would you expectthe Na¬Cl or the K¬F distance to be longer? (b) Use theionic radii given in Figure 7.8 to estimate the Na¬Cl andK¬F distances.
Calculate the lattice energy of AgBr(s) using the following thermodynamic data (all data is in kJ/mol).
Ag(s)
ΔHsublimation = 265 kJ/mol
Ag(g)
Ionization energy = 711 kJ/mol
Br-Br(g)
Bond energy = 173 kJ/mol
Br(g)
Electron affinity = -345 kJ/mol
AgBr(s)
ΔH°f = -120 kJ/mol
______________ kJ/mol
Why does the ionization enthalpy gradually decreases in a group?
Chapter 8 Solutions
CHEM FOR ENGNRNG SDNTS (EBOOK) W/ACCES
Ch. 8 - Prob. 1COCh. 8 - • describe the arrangement of atoms in the common...Ch. 8 - • use bind theory to describe bonding in solids.Ch. 8 - Prob. 4COCh. 8 - Prob. 5COCh. 8 - Prob. 6COCh. 8 - Prob. 7COCh. 8 - • explain the connection between intermolecular...Ch. 8 - Prob. 9COCh. 8 - Prob. 10CO
Ch. 8 - Prob. 8.1PAECh. 8 - Why is the C 60form of carbon called...Ch. 8 - Prob. 8.3PAECh. 8 - Prob. 8.4PAECh. 8 - What is the relationship between the structures of...Ch. 8 - Use the web to look up information on nanotubes....Ch. 8 - Prob. 8.7PAECh. 8 - Prob. 8.8PAECh. 8 - Prob. 8.9PAECh. 8 - Using circles, draw regular two-dimensional...Ch. 8 - Prob. 8.11PAECh. 8 - Prob. 8.12PAECh. 8 - Prob. 8.13PAECh. 8 - Prob. 8.14PAECh. 8 - 8.13 What is the coordination number of atoms in...Ch. 8 - Prob. 8.16PAECh. 8 - Prob. 8.17PAECh. 8 - 8.16 Iridium forms a face-centered cubic lattice,...Ch. 8 - 8.17 Europium forms a body-centered cubic unit...Ch. 8 - 8.18 Manganese has a body-centered cubic unit cell...Ch. 8 - Prob. 8.21PAECh. 8 - 8.20 How many electrons per atom are delocalized...Ch. 8 - Prob. 8.23PAECh. 8 - Prob. 8.24PAECh. 8 - Prob. 8.25PAECh. 8 - 8.24 What is the key difference between metallic...Ch. 8 - Prob. 8.27PAECh. 8 - Prob. 8.28PAECh. 8 - 8.25 Draw a depiction of the band structure of a...Ch. 8 - Prob. 8.30PAECh. 8 - Prob. 8.31PAECh. 8 - Prob. 8.32PAECh. 8 - Prob. 8.33PAECh. 8 - Prob. 8.34PAECh. 8 - Prob. 8.35PAECh. 8 - Prob. 8.36PAECh. 8 - Prob. 8.37PAECh. 8 - Suppose that a device is using a 15.0-mg sample of...Ch. 8 - 8.35 What is an instantancous dipole?Ch. 8 - 8.36 Why are dispersion forces attractive?Ch. 8 - 8.37 If a molecule is not very polarizable, how...Ch. 8 - 8.38 What is the relationship between...Ch. 8 - Prob. 8.43PAECh. 8 - Prob. 8.44PAECh. 8 - 8.39 Under what circumstances are ion-dipole...Ch. 8 - 8.40 Which of the following compounds would be...Ch. 8 - 8.41 What is the specific feature of N, O, and F...Ch. 8 - Prob. 8.48PAECh. 8 - 8.43 Identify the kinds of intermolecular forces...Ch. 8 - Prob. 8.50PAECh. 8 - Prob. 8.51PAECh. 8 - Explain from a molecular perspective why graphite...Ch. 8 - 8.45 Describe how interactions between molecules...Ch. 8 - 8.46 What makes a chemical compound volatile?Ch. 8 - 8.47 Answer each of the following questions with...Ch. 8 - 8.48 Why must the vapor pressure of a substance be...Ch. 8 - Prob. 8.57PAECh. 8 - Prob. 8.58PAECh. 8 - Prob. 8.59PAECh. 8 - Suppose that three unknown pure substances are...Ch. 8 - 8.51 Suppose that three unknown pure substances...Ch. 8 - 8.52 Rank the following hydrocarbons in order of...Ch. 8 - Prob. 8.63PAECh. 8 - Prob. 8.64PAECh. 8 - Prob. 8.65PAECh. 8 - Prob. 8.66PAECh. 8 - Prob. 8.67PAECh. 8 - Prob. 8.68PAECh. 8 - Why is there no isotactic or syndiotactic form of...Ch. 8 - Prob. 8.70PAECh. 8 - Prob. 8.71PAECh. 8 - Prob. 8.72PAECh. 8 - 8.61 Distinguish between a block copolymer and a...Ch. 8 - Prob. 8.74PAECh. 8 - Prob. 8.75PAECh. 8 - Prob. 8.76PAECh. 8 - Prob. 8.77PAECh. 8 - 8.66 What structural characteristics are needed...Ch. 8 - Prob. 8.79PAECh. 8 - Prob. 8.80PAECh. 8 - Prob. 8.81PAECh. 8 - Prob. 8.82PAECh. 8 - Prob. 8.83PAECh. 8 - Prob. 8.84PAECh. 8 - Prob. 8.85PAECh. 8 - Prob. 8.86PAECh. 8 - 8.87 Use the vapor pressure curves illustrated...Ch. 8 - Prob. 8.88PAECh. 8 - 8.89 The following data show the vapor pressure of...Ch. 8 - Prob. 8.90PAECh. 8 - Prob. 8.91PAECh. 8 - Prob. 8.92PAECh. 8 - Prob. 8.93PAECh. 8 - Prob. 8.94PAECh. 8 - Prob. 8.95PAECh. 8 - 8.96 A business manager wants to provide a wider...Ch. 8 - 8.97 The doping of semiconductors can be done with...Ch. 8 - 8.98 If you know the density of material and the...Ch. 8 - Prob. 8.99PAECh. 8 - Prob. 8.100PAECh. 8 - Prob. 8.101PAECh. 8 - Prob. 8.102PAECh. 8 - 8.103 In previous chapters, we have noted that...Ch. 8 - Prob. 8.104PAECh. 8 - Prob. 8.105PAE
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- Compare the properties of an ionic material such as sodium chloride with a room-temperature ionic liquid. Explain this difference.arrow_forward(A) Balance this reaction. Then use the bond enthapies given in the table below to calculate the enthalpy of reaction for the balanced reaction. kJ/mol(B) Balance this reaction. Then use the bond enthapies given in the table below to calculate the enthalpy of reaction for the balanced reaction. kJ/mol(C) Balance this reaction. Then use the bond enthapies given in the table below to calculate the enthalpy of reaction for the balanced reaction kJ/molarrow_forward5. Which of the following alkali metal halides has the larger lattice energy, and which has the smaller lattice energy? Explain. (a) (b)arrow_forward
- and S. 4. How much energy, in joules, is required to break the bond in one chlorine molecule? The bond energy of Cl₂ is 242.6 kJ/mol.arrow_forwardAnswer the following questions that relate to the chemistry of nitrogen. (a) Two nitrogen atoms combine to form a nitrogen molecule, as represented by the following equation. 2 N(g) ® N2(g) Using the table of average bond energies below, determine the enthalpy change, AH, for the reaction. Average Bond Energy (k) mol-1) Bond N-N 160 N=N 420 N°N 950 (b) The reaction between nitrogen and hydrogen to form ammonia is represented below. N2(g) + 3 H2(g)® 2 NH3(g) AH° = -92.2 kJ Predict the sign of the standard entropy change, AS', for the reaction. Justify your answer. (C) The value of AG° for the reaction represented in part (b) is negative at low temperatures but positive at high temperatures. Explain.arrow_forward(a) Does the lattice energy of an ionic solid increase or decrease (i) as the charges of the ions increase, (ii) as the sizes of the ions increase? (b) Arrange the following substances not listed in Table 8.2 according to their expected lattice energies, listing them from lowest lattice energy to the highest: MgS, KI, GaN, LiBr. Table 8.2arrow_forward
- What is the most reactive, second most reactive, second least reactive, and least reactive out of the following metals: Magnesium, Copper, Nickel, and Silver?arrow_forward3. Chemical Formulas and Thermodynamics (continued) From the bond energy data given below, (a) write a balanced equation for the formation of C. liquid formic acid from its elements (solid carbon, hydrogen gas and oxygen gas) and (b) calculate its reaction energy in kJ. 415 kJ/mol 345 kl/mol 460 kJ/mol 490 kJ/mol 436 kJ/mol C-H O-H C-o 360 kl/mol O=0 800 kJ/mol 799 kl/mol C-C C=C H-H C=0 a. Write the equation for formation of Formic Acid from its elements: b. Show your AHrmx calculations. It may help to review the Lewis Structure of formic acid on page 4. Box your final answer.arrow_forwardTwo identical small charged spheres are a certain distance apart, and each one initially experiences an electrostatic force of magnitude F due to the other. With time, charge gradually leaks off of both spheres. When each of the spheres has lost half its initial charge, what will the magnitude of the electrostatic force be?arrow_forward
- 9. Use the following data to calculate the lattice energy of Cao. The enthalpy of formation of Cao is –636 kj/mol. The enthalpy of sublimation of Ca is +192 kj/mol, the first ionization energy of Ca is +590 kj/mol, and the second ionization energy of Ca is +1145 kj/mol. The enthalpy of dissociation of 02 is +494 kj/mol of 02 molecules, the first electron affinity of O is -141 kj/mol of 0 atoms, and the second electron affinity of 0 is +845 kj/mol of 0¯ ions.arrow_forwardExplain the decomposition of nitroglycerin in terms of relative bond enthalpies.arrow_forwardBond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forward
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