CHEMISTRY: AN INTRODUCTION TO GENERAL, O
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT
Chapter 8 Solutions
CHEMISTRY: AN INTRODUCTION TO GENERAL, O
Ch. 8.1 - Prob. 8.1PPCh. 8.1 - Use the kinetic molecular theory of gases to...Ch. 8.1 - Identify the property of a gas that is measured in...Ch. 8.1 - Identify the property of a gas that is measured in...Ch. 8.1 - Prob. 8.5PPCh. 8.1 - Prob. 8.6PPCh. 8.1 - Prob. 8.7PPCh. 8.1 - On a climb up Mount Whitney, the atmospheric...Ch. 8.2 - Why do scuba divers need to exhale air when they...Ch. 8.2 - Why does a sealed bag of chips expand when you...
Ch. 8.2 - The air in a cylinder with a piston has a volume...Ch. 8.2 - A balloon is filled with helium gas. When each of...Ch. 8.2 - Prob. 8.13PPCh. 8.2 - Prob. 8.14PPCh. 8.2 - A 10.0-L balloon contains helium gas at a pressure...Ch. 8.2 - Prob. 8.16PPCh. 8.2 - A sample of nitrogen N2 has a volume of 50.0 L at...Ch. 8.2 - A sample of methane CH4 has a volume of 25 mL at a...Ch. 8.2 - A sample of Ar gas has a volume of 5.40 L with an...Ch. 8.2 - A sample of Ne gas has a pressure of 654 mmHg with...Ch. 8.2 - Prob. 8.21PPCh. 8.2 - A patient’s oxygen tank holds 20.0 L of oxygen O2...Ch. 8.2 - Prob. 8.23PPCh. 8.2 - Prob. 8.24PPCh. 8.3 - Select the diagram that shows the final volume of...Ch. 8.3 - Indicate whether the final volume of gas in each...Ch. 8.3 - A sample of neon initially has a volume of 2.50 L...Ch. 8.3 - Prob. 8.28PPCh. 8.3 - A balloon contains 2500 ml- of helium gas at 75C ....Ch. 8.3 - Prob. 8.30PPCh. 8.3 - A gas sample has a volume of 0.256 L with an...Ch. 8.3 - Prob. 8.32PPCh. 8.4 - Prob. 8.33PPCh. 8.4 - Prob. 8.34PPCh. 8.4 - Calculate the final temperature, in degrees...Ch. 8.4 - Calculate the final temperature, in degrees...Ch. 8.4 - A gas sample has a pressure of 744 mmHg when the...Ch. 8.4 - Prob. 8.38PPCh. 8.4 - A tank contains isoflurane, an inhaled anesthetic,...Ch. 8.4 - Bacteria and viruses are inactivated by...Ch. 8.5 - Prob. 8.41PPCh. 8.5 - Prob. 8.42PPCh. 8.5 - Prob. 8.43PPCh. 8.5 - A sample of argon gas has a volume of 735 mL at a...Ch. 8.5 - A 124-mL bubble of hot gas initially at 212 °C and...Ch. 8.5 - A scuba diver 60 ft below the ocean surface...Ch. 8.6 - What happens to the volume of a bicycle tire or a...Ch. 8.6 - Prob. 8.48PPCh. 8.6 - Prob. 8.49PPCh. 8.6 - Prob. 8.50PPCh. 8.6 - Prob. 8.51PPCh. 8.6 - Prob. 8.52PPCh. 8.7 - A typical air sample in the lungs contains oxygen...Ch. 8.7 - Prob. 8.54PPCh. 8.7 - Prob. 8.55PPCh. 8.7 - In a gas mixture, the partial pressures are argon...Ch. 8.7 - A gas mixture containing oxygen, nitrogen, and...Ch. 8.7 - A gas mixture containing oxygen, nitrogen, and...Ch. 8.7 - Prob. 8.59PPCh. 8.7 - Prob. 8.60PPCh. 8.7 - Prob. 8.61PPCh. 8.7 - Prob. 8.62PPCh. 8 - Two flasks of equal volume and at the same...Ch. 8 - Prob. 8.64UTCCh. 8 - At 100 °C, which of the following diagrams (1, 2,...Ch. 8 - Indicate which diagram (1, 2, or 3) represents the...Ch. 8 - A balloon is filled with helium gas with a partial...Ch. 8 - Prob. 8.68UTCCh. 8 - Prob. 8.69UTCCh. 8 - Prob. 8.70UTCCh. 8 - Prob. 8.71APPCh. 8 - Prob. 8.72APPCh. 8 - Prob. 8.73APPCh. 8 - Prob. 8.74APPCh. 8 - A weather balloon has a volume of 750 L when...Ch. 8 - Prob. 8.76APPCh. 8 - A weather balloon is partially filled with Helium...Ch. 8 - Prob. 8.78APPCh. 8 - A gas mixture contains Oxygen and Argon at partial...Ch. 8 - Prob. 8.80APPCh. 8 - Prob. 8.81CPCh. 8 - You are doing research on planet X. The...Ch. 8 - Prob. 8.83CPCh. 8 - Prob. 8.84CP
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- For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects Resonance Effects Overall Electron-Density × NO2 ○ donating O donating O withdrawing O withdrawing O electron-rich electron-deficient no inductive effects O no resonance effects O similar to benzene E [ CI O donating withdrawing O no inductive effects Explanation Check ○ donating withdrawing no resonance effects electron-rich electron-deficient O similar to benzene © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accesarrow_forwardUnderstanding how substituents activate Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation HN NH2 Check X (Choose one) (Choose one) (Choose one) (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Aarrow_forwardIdentifying electron-donating and electron-withdrawing effects on benzene For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Inductive Effects Resonance Effects Overall Electron-Density Molecule CF3 O donating O donating O withdrawing O withdrawing O no inductive effects O no resonance effects electron-rich electron-deficient O similar to benzene CH3 O donating O withdrawing O no inductive effects O donating O withdrawing Ono resonance effects O electron-rich O electron-deficient O similar to benzene Explanation Check Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forward
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