(a) Interpretation: The substitutive name for the given compound is to be stated. Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Question

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Answer 1

Question

Chapter 8, Problem 8.5P

Interpretation Introduction

(a)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-butanol$ .

Explanation of Solution

The given compound is $CH3CH2CH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. Therefore, the name of this compound is $1-butanol$ .

Conclusion

The substitutive name for the given compound is $1-butanol$ .

Interpretation Introduction

(b)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Explanation of Solution

The given compound is $CH3CHBrCH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The bromo group is attached at the third carbon atom. Therefore, the name of this compound is $3-bromo-1-butanol$ .

Conclusion

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Interpretation Introduction

(c)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 1

Figure 1

The given compound has a longest chain of five carbon atoms with a double bond on third carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is pentene. One chloro group is attached at the first carbon atom, one methyl group is attached at the third carbon atom and one hydroxyl group is attached at the second carbon atom.

The use of prefix $E$ and $Z$ depends upon the location of the higher priority groups. When the priority groups located on the opposite side then it is an $E$ isomer, whereas when two higher priority groups located on the same side then it is an $Z$ isomer. The priority order depends upon the atomic number of the elements. Therefore, the name of this compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Conclusion

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Interpretation Introduction

(d)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 2

Figure 2

The given compound has a cyclic ring of five carbon atoms with a double bond on second carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $cyclopent-2-ene$ . One chloro group is attached at the second carbon atom, one methyl group is attached at the fifth carbon atom and one thiol group is attached at the first carbon atom.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Conclusion

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Interpretation Introduction

(e)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 3

Figure 3

The given compound has a chain of six carbon atoms with a double bond on fifth carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $hex-5-ene$ . One butyl group is attached at the third carbon atom and two hydroxyl groups are attached at the second and fourth carbon atoms.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Conclusion

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Interpretation Introduction

(f)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 4

Figure 4

It consists of a cyclic ring of six carbon atoms. Therefore, the parent name is cyclohexa. There are two double bonds present at the second and fifth carbon atom of the ring. Also, one hydroxyl group is attached at the first carbon atom. Therefore, the name of this compound is $cyclohexa-2, 5-diene-1-ol$ .

Conclusion

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Interpretation Introduction

(g)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 5

Figure 5

It consists of a chain of five carbon atoms with hydroxyl group attached at the second carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The –SH group is attached at the first carbon atom. Therefore, the name of this compound is $1-mercaptopentan-2-ol$ .

Conclusion

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Interpretation Introduction

(h)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 6

Figure 6

It consists of a chain of three carbon atoms with thiol group attached at the second carbon atom. One methyl group is attached at the second carbon atom. Therefore, the name of this compound is $2-methylpropan-2-thiol$ .

Conclusion

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

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In the scope of the SCH4U course, please thoroughly go through the second question

Answer 2

Question

Chapter 8, Problem 8.5P

Interpretation Introduction

(a)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-butanol$ .

Explanation of Solution

The given compound is $CH3CH2CH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. Therefore, the name of this compound is $1-butanol$ .

Conclusion

The substitutive name for the given compound is $1-butanol$ .

Interpretation Introduction

(b)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Explanation of Solution

The given compound is $CH3CHBrCH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The bromo group is attached at the third carbon atom. Therefore, the name of this compound is $3-bromo-1-butanol$ .

Conclusion

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Interpretation Introduction

(c)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 1

Figure 1

The given compound has a longest chain of five carbon atoms with a double bond on third carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is pentene. One chloro group is attached at the first carbon atom, one methyl group is attached at the third carbon atom and one hydroxyl group is attached at the second carbon atom.

The use of prefix $E$ and $Z$ depends upon the location of the higher priority groups. When the priority groups located on the opposite side then it is an $E$ isomer, whereas when two higher priority groups located on the same side then it is an $Z$ isomer. The priority order depends upon the atomic number of the elements. Therefore, the name of this compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Conclusion

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Interpretation Introduction

(d)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 2

Figure 2

The given compound has a cyclic ring of five carbon atoms with a double bond on second carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $cyclopent-2-ene$ . One chloro group is attached at the second carbon atom, one methyl group is attached at the fifth carbon atom and one thiol group is attached at the first carbon atom.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Conclusion

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Interpretation Introduction

(e)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 3

Figure 3

The given compound has a chain of six carbon atoms with a double bond on fifth carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $hex-5-ene$ . One butyl group is attached at the third carbon atom and two hydroxyl groups are attached at the second and fourth carbon atoms.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Conclusion

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Interpretation Introduction

(f)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 4

Figure 4

It consists of a cyclic ring of six carbon atoms. Therefore, the parent name is cyclohexa. There are two double bonds present at the second and fifth carbon atom of the ring. Also, one hydroxyl group is attached at the first carbon atom. Therefore, the name of this compound is $cyclohexa-2, 5-diene-1-ol$ .

Conclusion

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Interpretation Introduction

(g)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 5

Figure 5

It consists of a chain of five carbon atoms with hydroxyl group attached at the second carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The –SH group is attached at the first carbon atom. Therefore, the name of this compound is $1-mercaptopentan-2-ol$ .

Conclusion

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Interpretation Introduction

(h)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 6

Figure 6

It consists of a chain of three carbon atoms with thiol group attached at the second carbon atom. One methyl group is attached at the second carbon atom. Therefore, the name of this compound is $2-methylpropan-2-thiol$ .

Conclusion

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

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Answer 3

Question

Chapter 8, Problem 8.5P

Interpretation Introduction

(a)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-butanol$ .

Explanation of Solution

The given compound is $CH3CH2CH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. Therefore, the name of this compound is $1-butanol$ .

Conclusion

The substitutive name for the given compound is $1-butanol$ .

Interpretation Introduction

(b)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Explanation of Solution

The given compound is $CH3CHBrCH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The bromo group is attached at the third carbon atom. Therefore, the name of this compound is $3-bromo-1-butanol$ .

Conclusion

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Interpretation Introduction

(c)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 1

Figure 1

The given compound has a longest chain of five carbon atoms with a double bond on third carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is pentene. One chloro group is attached at the first carbon atom, one methyl group is attached at the third carbon atom and one hydroxyl group is attached at the second carbon atom.

The use of prefix $E$ and $Z$ depends upon the location of the higher priority groups. When the priority groups located on the opposite side then it is an $E$ isomer, whereas when two higher priority groups located on the same side then it is an $Z$ isomer. The priority order depends upon the atomic number of the elements. Therefore, the name of this compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Conclusion

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Interpretation Introduction

(d)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 2

Figure 2

The given compound has a cyclic ring of five carbon atoms with a double bond on second carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $cyclopent-2-ene$ . One chloro group is attached at the second carbon atom, one methyl group is attached at the fifth carbon atom and one thiol group is attached at the first carbon atom.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Conclusion

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Interpretation Introduction

(e)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 3

Figure 3

The given compound has a chain of six carbon atoms with a double bond on fifth carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $hex-5-ene$ . One butyl group is attached at the third carbon atom and two hydroxyl groups are attached at the second and fourth carbon atoms.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Conclusion

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Interpretation Introduction

(f)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 4

Figure 4

It consists of a cyclic ring of six carbon atoms. Therefore, the parent name is cyclohexa. There are two double bonds present at the second and fifth carbon atom of the ring. Also, one hydroxyl group is attached at the first carbon atom. Therefore, the name of this compound is $cyclohexa-2, 5-diene-1-ol$ .

Conclusion

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Interpretation Introduction

(g)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 5

Figure 5

It consists of a chain of five carbon atoms with hydroxyl group attached at the second carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The –SH group is attached at the first carbon atom. Therefore, the name of this compound is $1-mercaptopentan-2-ol$ .

Conclusion

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Interpretation Introduction

(h)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 6

Figure 6

It consists of a chain of three carbon atoms with thiol group attached at the second carbon atom. One methyl group is attached at the second carbon atom. Therefore, the name of this compound is $2-methylpropan-2-thiol$ .

Conclusion

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

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Answer 4

Question

Chapter 8, Problem 8.5P

Interpretation Introduction

(a)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-butanol$ .

Explanation of Solution

The given compound is $CH3CH2CH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. Therefore, the name of this compound is $1-butanol$ .

Conclusion

The substitutive name for the given compound is $1-butanol$ .

Interpretation Introduction

(b)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Explanation of Solution

The given compound is $CH3CHBrCH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The bromo group is attached at the third carbon atom. Therefore, the name of this compound is $3-bromo-1-butanol$ .

Conclusion

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Interpretation Introduction

(c)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 1

Figure 1

The given compound has a longest chain of five carbon atoms with a double bond on third carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is pentene. One chloro group is attached at the first carbon atom, one methyl group is attached at the third carbon atom and one hydroxyl group is attached at the second carbon atom.

The use of prefix $E$ and $Z$ depends upon the location of the higher priority groups. When the priority groups located on the opposite side then it is an $E$ isomer, whereas when two higher priority groups located on the same side then it is an $Z$ isomer. The priority order depends upon the atomic number of the elements. Therefore, the name of this compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Conclusion

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Interpretation Introduction

(d)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 2

Figure 2

The given compound has a cyclic ring of five carbon atoms with a double bond on second carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $cyclopent-2-ene$ . One chloro group is attached at the second carbon atom, one methyl group is attached at the fifth carbon atom and one thiol group is attached at the first carbon atom.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Conclusion

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Interpretation Introduction

(e)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 3

Figure 3

The given compound has a chain of six carbon atoms with a double bond on fifth carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $hex-5-ene$ . One butyl group is attached at the third carbon atom and two hydroxyl groups are attached at the second and fourth carbon atoms.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Conclusion

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Interpretation Introduction

(f)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 4

Figure 4

It consists of a cyclic ring of six carbon atoms. Therefore, the parent name is cyclohexa. There are two double bonds present at the second and fifth carbon atom of the ring. Also, one hydroxyl group is attached at the first carbon atom. Therefore, the name of this compound is $cyclohexa-2, 5-diene-1-ol$ .

Conclusion

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Interpretation Introduction

(g)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 5

Figure 5

It consists of a chain of five carbon atoms with hydroxyl group attached at the second carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The –SH group is attached at the first carbon atom. Therefore, the name of this compound is $1-mercaptopentan-2-ol$ .

Conclusion

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Interpretation Introduction

(h)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 6

Figure 6

It consists of a chain of three carbon atoms with thiol group attached at the second carbon atom. One methyl group is attached at the second carbon atom. Therefore, the name of this compound is $2-methylpropan-2-thiol$ .

Conclusion

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

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Answer 5

Chapter 8, Problem 8.5P

Interpretation Introduction

(a)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-butanol$ .

Explanation of Solution

The given compound is $CH3CH2CH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. Therefore, the name of this compound is $1-butanol$ .

Conclusion

The substitutive name for the given compound is $1-butanol$ .

Interpretation Introduction

(b)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Explanation of Solution

The given compound is $CH3CHBrCH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The bromo group is attached at the third carbon atom. Therefore, the name of this compound is $3-bromo-1-butanol$ .

Conclusion

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Interpretation Introduction

(c)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 1

Figure 1

The given compound has a longest chain of five carbon atoms with a double bond on third carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is pentene. One chloro group is attached at the first carbon atom, one methyl group is attached at the third carbon atom and one hydroxyl group is attached at the second carbon atom.

The use of prefix $E$ and $Z$ depends upon the location of the higher priority groups. When the priority groups located on the opposite side then it is an $E$ isomer, whereas when two higher priority groups located on the same side then it is an $Z$ isomer. The priority order depends upon the atomic number of the elements. Therefore, the name of this compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Conclusion

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Interpretation Introduction

(d)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 2

Figure 2

The given compound has a cyclic ring of five carbon atoms with a double bond on second carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $cyclopent-2-ene$ . One chloro group is attached at the second carbon atom, one methyl group is attached at the fifth carbon atom and one thiol group is attached at the first carbon atom.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Conclusion

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Interpretation Introduction

(e)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 3

Figure 3

The given compound has a chain of six carbon atoms with a double bond on fifth carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $hex-5-ene$ . One butyl group is attached at the third carbon atom and two hydroxyl groups are attached at the second and fourth carbon atoms.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Conclusion

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Interpretation Introduction

(f)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 4

Figure 4

It consists of a cyclic ring of six carbon atoms. Therefore, the parent name is cyclohexa. There are two double bonds present at the second and fifth carbon atom of the ring. Also, one hydroxyl group is attached at the first carbon atom. Therefore, the name of this compound is $cyclohexa-2, 5-diene-1-ol$ .

Conclusion

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Interpretation Introduction

(g)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 5

Figure 5

It consists of a chain of five carbon atoms with hydroxyl group attached at the second carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The –SH group is attached at the first carbon atom. Therefore, the name of this compound is $1-mercaptopentan-2-ol$ .

Conclusion

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Interpretation Introduction

(h)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 6

Figure 6

It consists of a chain of three carbon atoms with thiol group attached at the second carbon atom. One methyl group is attached at the second carbon atom. Therefore, the name of this compound is $2-methylpropan-2-thiol$ .

Conclusion

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Answer 6

Chapter 8, Problem 8.5P

Interpretation Introduction

(a)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-butanol$ .

Explanation of Solution

The given compound is $CH3CH2CH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. Therefore, the name of this compound is $1-butanol$ .

Conclusion

The substitutive name for the given compound is $1-butanol$ .

Answer 7

Chapter 8, Problem 8.5P

Interpretation Introduction

(a)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 8

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-butanol$ .

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The given compound is $CH3CH2CH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. Therefore, the name of this compound is $1-butanol$ .

Answer 13

Conclusion

The substitutive name for the given compound is $1-butanol$ .

Answer 14

Interpretation Introduction

(b)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Explanation of Solution

The given compound is $CH3CHBrCH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The bromo group is attached at the third carbon atom. Therefore, the name of this compound is $3-bromo-1-butanol$ .

Conclusion

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Answer 15

Interpretation Introduction

(b)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 16

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The given compound is $CH3CHBrCH2CH2OH$ . It consists of a chain of four carbon atoms with hydroxyl group attached at the first carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The bromo group is attached at the third carbon atom. Therefore, the name of this compound is $3-bromo-1-butanol$ .

Answer 21

Conclusion

The substitutive name for the given compound is $3-bromo-1-butanol$ .

Answer 22

Interpretation Introduction

(c)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 1

Figure 1

The given compound has a longest chain of five carbon atoms with a double bond on third carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is pentene. One chloro group is attached at the first carbon atom, one methyl group is attached at the third carbon atom and one hydroxyl group is attached at the second carbon atom.

The use of prefix $E$ and $Z$ depends upon the location of the higher priority groups. When the priority groups located on the opposite side then it is an $E$ isomer, whereas when two higher priority groups located on the same side then it is an $Z$ isomer. The priority order depends upon the atomic number of the elements. Therefore, the name of this compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Conclusion

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Answer 23

Interpretation Introduction

(c)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 24

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 1

Figure 1

The given compound has a longest chain of five carbon atoms with a double bond on third carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is pentene. One chloro group is attached at the first carbon atom, one methyl group is attached at the third carbon atom and one hydroxyl group is attached at the second carbon atom.

The use of prefix $E$ and $Z$ depends upon the location of the higher priority groups. When the priority groups located on the opposite side then it is an $E$ isomer, whereas when two higher priority groups located on the same side then it is an $Z$ isomer. The priority order depends upon the atomic number of the elements. Therefore, the name of this compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Answer 29

Conclusion

The substitutive name for the given compound is $(E)-1-chloro-3-methyl-3-pentene-2-ol$ .

Answer 30

Interpretation Introduction

(d)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 2

Figure 2

The given compound has a cyclic ring of five carbon atoms with a double bond on second carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $cyclopent-2-ene$ . One chloro group is attached at the second carbon atom, one methyl group is attached at the fifth carbon atom and one thiol group is attached at the first carbon atom.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Conclusion

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Answer 31

Interpretation Introduction

(d)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 32

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 2

Figure 2

The given compound has a cyclic ring of five carbon atoms with a double bond on second carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $cyclopent-2-ene$ . One chloro group is attached at the second carbon atom, one methyl group is attached at the fifth carbon atom and one thiol group is attached at the first carbon atom.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Answer 37

Conclusion

The substitutive name for the given compound is $(1S,5R)-2-chloro-5-methylcyclopent-2-enethiol$ .

Answer 38

Interpretation Introduction

(e)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 3

Figure 3

The given compound has a chain of six carbon atoms with a double bond on fifth carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $hex-5-ene$ . One butyl group is attached at the third carbon atom and two hydroxyl groups are attached at the second and fourth carbon atoms.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Conclusion

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Answer 39

Interpretation Introduction

(e)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 40

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 3

Figure 3

The given compound has a chain of six carbon atoms with a double bond on fifth carbon atom. It is an alkene, the suffix used for an alkene is –ene. Therefore, the parent name is $hex-5-ene$ . One butyl group is attached at the third carbon atom and two hydroxyl groups are attached at the second and fourth carbon atoms.

The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other. Therefore, the name of this compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Answer 45

Conclusion

The substitutive name for the given compound is $(2R,3R,4S)-3-butylhex-5-ene-2, 4-diol$ .

Answer 46

Interpretation Introduction

(f)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 4

Figure 4

It consists of a cyclic ring of six carbon atoms. Therefore, the parent name is cyclohexa. There are two double bonds present at the second and fifth carbon atom of the ring. Also, one hydroxyl group is attached at the first carbon atom. Therefore, the name of this compound is $cyclohexa-2, 5-diene-1-ol$ .

Conclusion

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Answer 47

Interpretation Introduction

(f)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 48

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 4

Figure 4

It consists of a cyclic ring of six carbon atoms. Therefore, the parent name is cyclohexa. There are two double bonds present at the second and fifth carbon atom of the ring. Also, one hydroxyl group is attached at the first carbon atom. Therefore, the name of this compound is $cyclohexa-2, 5-diene-1-ol$ .

Answer 53

Conclusion

The substitutive name for the given compound is $cyclohexa-2, 5-diene-1-ol$ .

Answer 54

Interpretation Introduction

(g)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 5

Figure 5

It consists of a chain of five carbon atoms with hydroxyl group attached at the second carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The –SH group is attached at the first carbon atom. Therefore, the name of this compound is $1-mercaptopentan-2-ol$ .

Conclusion

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Answer 55

Interpretation Introduction

(g)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 56

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Answer 57

Expert Solution

Answer 58

Expert Solution

Answer 59

Expert Solution

Answer 60

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 5

Figure 5

It consists of a chain of five carbon atoms with hydroxyl group attached at the second carbon atom. The alcohols contain hydroxyl $(OH)$ functional group in their parent chain and are named by adding suffix –ol. The –SH group is attached at the first carbon atom. Therefore, the name of this compound is $1-mercaptopentan-2-ol$ .

Answer 61

Conclusion

The substitutive name for the given compound is $1-mercaptopentan-2-ol$ .

Answer 62

Interpretation Introduction

(h)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 6

Figure 6

It consists of a chain of three carbon atoms with thiol group attached at the second carbon atom. One methyl group is attached at the second carbon atom. Therefore, the name of this compound is $2-methylpropan-2-thiol$ .

Conclusion

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Answer 63

Interpretation Introduction

(h)

Interpretation:

The substitutive name for the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.

The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order.

Answer 64

Expert Solution

Answer to Problem 8.5P

The substitutive name for the given compound is $2-methylpropan-2-thiol$ .

Answer 65

Expert Solution

Answer 66

Expert Solution

Answer 67

Expert Solution

Answer 68

Explanation of Solution

The given compound is shown below.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 8, Problem 8.5P , additional homework tip 6

Figure 6

It consists of a chain of three carbon atoms with thiol group attached at the second carbon atom. One methyl group is attached at the second carbon atom. Therefore, the name of this compound is $2-methylpropan-2-thiol$ .