(a) Interpretation: The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial − OH group while illustrated compound B exists mostly in chair conformation with an axial − OH group is to be stated. Concept introduction: The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

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Answer 1

Question

Chapter 8, Problem 8.55AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial −OH group while illustrated compound B exists mostly in chair conformation with an axial −OH group is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the racemate of 2, 2, 5, 5-tetramethyl-3, 4-hexanediol has the strong intramolecular hydrogen bonds while meso isomer of this does not is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon bond is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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Answer 2

Question

Chapter 8, Problem 8.55AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial −OH group while illustrated compound B exists mostly in chair conformation with an axial −OH group is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the racemate of 2, 2, 5, 5-tetramethyl-3, 4-hexanediol has the strong intramolecular hydrogen bonds while meso isomer of this does not is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon bond is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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Answer 3

Question

Chapter 8, Problem 8.55AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial −OH group while illustrated compound B exists mostly in chair conformation with an axial −OH group is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the racemate of 2, 2, 5, 5-tetramethyl-3, 4-hexanediol has the strong intramolecular hydrogen bonds while meso isomer of this does not is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon bond is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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Answer 4

Question

Chapter 8, Problem 8.55AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial −OH group while illustrated compound B exists mostly in chair conformation with an axial −OH group is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the racemate of 2, 2, 5, 5-tetramethyl-3, 4-hexanediol has the strong intramolecular hydrogen bonds while meso isomer of this does not is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon bond is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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Answer 5

Chapter 8, Problem 8.55AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial −OH group while illustrated compound B exists mostly in chair conformation with an axial −OH group is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the racemate of 2, 2, 5, 5-tetramethyl-3, 4-hexanediol has the strong intramolecular hydrogen bonds while meso isomer of this does not is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon bond is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

Answer 6

Chapter 8, Problem 8.55AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial −OH group while illustrated compound B exists mostly in chair conformation with an axial −OH group is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Answer 7

Chapter 8, Problem 8.55AP

Interpretation Introduction

(a)

Interpretation:

The reason as to why illustrated compound A exist mostly in chair conformation with the equatorial −OH group while illustrated compound B exists mostly in chair conformation with an axial −OH group is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why the racemate of 2, 2, 5, 5-tetramethyl-3, 4-hexanediol has the strong intramolecular hydrogen bonds while meso isomer of this does not is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon bond is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why the racemate of 2, 2, 5, 5-tetramethyl-3, 4-hexanediol has the strong intramolecular hydrogen bonds while meso isomer of this does not is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon bond is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8 - Prob. 8.1P Ch. 8 - Prob. 8.2P Ch. 8 - Prob. 8.3P Ch. 8 - Prob. 8.4P Ch. 8 - Prob. 8.5P Ch. 8 - Prob. 8.6P Ch. 8 - Prob. 8.7P Ch. 8 - Prob. 8.8P Ch. 8 - Prob. 8.9P Ch. 8 - Prob. 8.10P

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