
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 8, Problem 8.53E
Interpretation Introduction
Interpretation:
The oxidation of
Concept introduction:
The
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
1800
1600
1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 8 Solutions
Physical Chemistry
Ch. 8 - 8.1. What is the charge on a small sphere that is...Ch. 8 - 8.2. The force of attraction due to gravity...Ch. 8 - 8.3. Two small metallic bodies are given opposite...Ch. 8 - Prob. 8.4ECh. 8 - What is the force of attraction between a...Ch. 8 - Prob. 8.6ECh. 8 - 8.7. How much work is required to move a single...Ch. 8 - 8.8. Explain why an electromotive force is not, in...Ch. 8 - Prob. 8.9ECh. 8 - For each of the following reactions, determine the...
Ch. 8 - Prob. 8.11ECh. 8 - Prob. 8.12ECh. 8 - 8.13. Is the disproportionation reaction...Ch. 8 - Prob. 8.14ECh. 8 - Prob. 8.15ECh. 8 - Prob. 8.16ECh. 8 - Prob. 8.17ECh. 8 - 8.18. Determine and for each of the following...Ch. 8 - Prob. 8.19ECh. 8 - Prob. 8.20ECh. 8 - Prob. 8.21ECh. 8 - Prob. 8.22ECh. 8 - Prob. 8.23ECh. 8 - Prob. 8.24ECh. 8 - Prob. 8.25ECh. 8 - Prob. 8.26ECh. 8 - Prob. 8.27ECh. 8 - What is the Zn2+:Cu2+ ratio on a Daniell cell that...Ch. 8 - Prob. 8.29ECh. 8 - Determine the voltage of this reaction with the...Ch. 8 - The thermite reaction can act as the basis of an...Ch. 8 - A concentration cell has different concentrations...Ch. 8 - Prob. 8.34ECh. 8 - Prob. 8.35ECh. 8 - a What is the equilibrium constant for the...Ch. 8 - Prob. 8.37ECh. 8 - Prob. 8.38ECh. 8 - Prob. 8.39ECh. 8 - Prob. 8.40ECh. 8 - Prob. 8.41ECh. 8 - Consider the following formation reaction for HI:...Ch. 8 - Prob. 8.43ECh. 8 - 8.44. Determine an expression for , the change in...Ch. 8 - Prob. 8.45ECh. 8 - Prob. 8.46ECh. 8 - Determine the equilibrium constant for the...Ch. 8 - Prob. 8.48ECh. 8 - Prob. 8.49ECh. 8 - What is the solubility product constant of Hg2Cl2,...Ch. 8 - Prob. 8.51ECh. 8 - Prob. 8.52ECh. 8 - Prob. 8.53ECh. 8 - Prob. 8.54ECh. 8 - Prob. 8.55ECh. 8 - Prob. 8.56ECh. 8 - Prob. 8.57ECh. 8 - Show that a can be written as n+mnn+n+nn, where m...Ch. 8 - Prob. 8.59ECh. 8 - Prob. 8.60ECh. 8 - What molality of NaCl is necessary to have the...Ch. 8 - Prob. 8.62ECh. 8 - Prob. 8.63ECh. 8 - Calculate the molar enthalpy of formation of I(aq)...Ch. 8 - Prob. 8.65ECh. 8 - Hydrofluoric acid, HF(aq), is a weak acid that is...Ch. 8 - Prob. 8.68ECh. 8 - Prob. 8.69ECh. 8 - Prob. 8.70ECh. 8 - Prob. 8.71ECh. 8 - Prob. 8.72ECh. 8 - The mean activity coefficient for an aqueous...Ch. 8 - Human blood plasma is approximately 0.9NaCl. What...Ch. 8 - Under what conditions does the extended...Ch. 8 - Prob. 8.76ECh. 8 - Approximate the expected voltage for the following...Ch. 8 - Prob. 8.78ECh. 8 - Prob. 8.79ECh. 8 - Prob. 8.80ECh. 8 - a The salt NaNO3 can be thought of as...Ch. 8 - Prob. 8.82ECh. 8 - What is the estimated velocity for Cu2+ ions...Ch. 8 - Prob. 8.84ECh. 8 - Prob. 8.85ECh. 8 - Prob. 8.86ECh. 8 - Calculate a the solubility product constant for...
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