Chemistry: The Central Science, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (13th Edition)
13th Edition
ISBN: 9780321934826
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 8, Problem 65E
(a)
Interpretation Introduction
To determine: The complexes that can have geometric isomers from the given complexes.
(b)
Interpretation Introduction
To determine: The complexes that can have linkage isomers from the given complexes.
(c)
Interpretation Introduction
To determine: The complexes that can have optical isomers from the given complexes.
(d)
Interpretation Introduction
To determine: The complexes that can have coordination-sphere isomers from the given complexes.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 8 Solutions
Chemistry: The Central Science, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (13th Edition)
Ch. 8.2 - Prob. 8.1.1PECh. 8.2 - Prob. 8.1.2PECh. 8.2 - Prob. 8.2.1PECh. 8.2 - Prob. 8.2.2PECh. 8.3 - Prob. 8.3.1PECh. 8.3 - Prob. 8.3.2PECh. 8.4 - Prob. 8.4.1PECh. 8.4 - Prob. 8.4.2PECh. 8.4 - Prob. 8.5.1PECh. 8.4 - Prob. 8.5.2PE
Ch. 8.5 - Prob. 8.6.1PECh. 8.5 - Prob. 8.6.2PECh. 8.5 - Prob. 8.7.1PECh. 8.5 - Prob. 8.7.2PECh. 8.5 - Prob. 8.8.1PECh. 8.5 - Prob. 8.8.2PECh. 8.5 - Prob. 8.9.1PECh. 8.5 - Prob. 8.9.2PECh. 8.6 - Prob. 8.10.1PECh. 8.6 - Prob. 8.10.2PECh. 8.7 - Prob. 8.11.1PECh. 8.7 - Write the formulas for the following compounds,...Ch. 8.7 - Prob. 8.12.1PECh. 8.7 - Prob. 8.12.2PECh. 8 - Prob. 1DECh. 8 - Prob. 1ECh. 8 - The three graphs below show the variation in...Ch. 8 - Prob. 3ECh. 8 - Prob. 4ECh. 8 - Prob. 5ECh. 8 - Prob. 6ECh. 8 - The partial Lewis structure that follows Is for a...Ch. 8 - Prob. 8ECh. 8 - Prob. 9ECh. 8 - Prob. 10ECh. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Prob. 13ECh. 8 - Prob. 14ECh. 8 - Prob. 15ECh. 8 - Prob. 16ECh. 8 - Prob. 17ECh. 8 - Prob. 18ECh. 8 - What is the name of the compound [Rh(NH3)4Cl2]Cl ?...Ch. 8 - Prob. 20ECh. 8 - Which of the following complexes has an optical...Ch. 8 - Prob. 22ECh. 8 - Prob. 23ECh. 8 - Prob. 24ECh. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - Prob. 27ECh. 8 - Prob. 28ECh. 8 - Prob. 29ECh. 8 - Prob. 30ECh. 8 - Prob. 31ECh. 8 - Prob. 32ECh. 8 - Prob. 33ECh. 8 - Prob. 34ECh. 8 - Prob. 35ECh. 8 - Prob. 36ECh. 8 - Prob. 37ECh. 8 - Prob. 38ECh. 8 - Prob. 39ECh. 8 - Prob. 40ECh. 8 - Prob. 41ECh. 8 - Write out the ground-state electron configurations...Ch. 8 - Prob. 43ECh. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Prob. 48ECh. 8 - Prob. 49ECh. 8 - Prob. 50ECh. 8 - Prob. 51ECh. 8 - Indicate the coordination number and the oxidation...Ch. 8 - Prob. 53ECh. 8 - Prob. 54ECh. 8 - Prob. 55ECh. 8 - Prob. 56ECh. 8 - (a) Do the C—C bond lengths in benzene alternate...Ch. 8 - Prob. 58ECh. 8 - Prob. 59ECh. 8 - Write the formula for each of the following...Ch. 8 - Prob. 61ECh. 8 - Prob. 62ECh. 8 - Prob. 63ECh. 8 - Prob. 64ECh. 8 - Prob. 65ECh. 8 - Prob. 66ECh. 8 - Prob. 67ECh. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Prob. 71ECh. 8 - Prob. 72ECh. 8 - Prob. 73ECh. 8 - Prob. 74ECh. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Prob. 77AECh. 8 - Prob. 78AECh. 8 - Prob. 79AECh. 8 - Prob. 80AECh. 8 - Prob. 81AECh. 8 - Prob. 82AECh. 8 - Prob. 83AECh. 8 - Prob. 84AECh. 8 - 23.62 For each of the following metals, write the...Ch. 8 - Prob. 86AECh. 8 - Prob. 87AECh. 8 - Prob. 88AECh. 8 - Prob. 89AECh. 8 - Prob. 90AECh. 8 - (a) Determine the formal charge on the chlorine...Ch. 8 - Prob. 92AECh. 8 - Prob. 93AECh. 8 - Prob. 94AECh. 8 - Prob. 95AECh. 8 - Prob. 96AECh. 8 - Prob. 97AECh. 8 - Prob. 98AECh. 8 - Prob. 99AECh. 8 - Prob. 100AECh. 8 - Prob. 101IECh. 8 - Prob. 102IECh. 8 - Prob. 103IECh. 8 - Prob. 104IECh. 8 - Prob. 105IECh. 8 - Prob. 106IECh. 8 - Prob. 107IECh. 8 - Prob. 108IECh. 8 - Prob. 109IECh. 8 - Prob. 110IECh. 8 -
8.11 I Consider benzene (C6H6) in the gas phase....Ch. 8 -
8.112 Average bond enthalpies are generally...Ch. 8 - Prob. 113IE
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