CNCT ORG CHEM 6 2020
CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Chapter 8, Problem 63P
Interpretation Introduction

Interpretation: The stereoisomer of 1, 2, 3, 4, 5, 6-hexachlorocyclohexane that reacts 7000 times more slowly than any of the other isomer in an E2 elimination is to be drawn and the reason for the same is to be stated.

Concept introduction: The one-step bimolecular elimination reaction that favors the removal of a proton by a base from carbon adjacent to the leaving group that results in the formation of a carbocation is termed as E2 elimination reaction. The formation of a double bond takes place simultaneously through the carbocation to form an alkene as the desired product. In case of E2 elimination, the anti-periplanar geometry should exist between the halogen and the proton that is being abstracted.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1
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Chapter 8 Solutions

CNCT ORG CHEM 6 2020

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