EBK CHEMISTRY: PRINCIPLES AND REACTIONS
8th Edition
ISBN: 8220100547966
Author: Hurley
Publisher: CENGAGE L
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Textbook Question
Chapter 8, Problem 60QAP
For the vaporization of one mole of bromine at 59°C, determine
(a) ΔH (Table 8.2)
(b) ΔPV(c) ΔE
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Don't used hand raiting
It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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protons, neutrons
Chapter 8 Solutions
EBK CHEMISTRY: PRINCIPLES AND REACTIONS
Ch. 8 - Principles of Heat Flow Titanium is a metal used...Ch. 8 - Prob. 2QAPCh. 8 - Copper is used in building the integrated...Ch. 8 - Mercury was once used in thermometers and...Ch. 8 - The specific heat of aluminum is 0.902J/gC. How...Ch. 8 - Chromium has a specific heat of 0.450J/gC. How...Ch. 8 - Magnesium sulfate is often used in first-aid hot...Ch. 8 - Sodium chloride is added in cooking to enhance the...Ch. 8 - When 375 mL of water (d=1.00g/mL) at 32C are mixed...Ch. 8 - How many mL of water at 10C (2 significant...
Ch. 8 - When one mol of KOH is neutralized by sulfuric...Ch. 8 - The heat of neutralization, Hneut, can be defined...Ch. 8 - Fructose is a sugar commonly found in fruit. A...Ch. 8 - In earlier times, ethyl ether was commonly used as...Ch. 8 - Isooctane is a primary component of gasoline and...Ch. 8 - Ethyl alcohol, C2H5OH, is the intoxicating agent...Ch. 8 - Acetic acid, HC2H3O2, is responsible for the sour...Ch. 8 - Acetylene, C2H2, is used in welding torches. It...Ch. 8 - Salicylic acid, C7H6O3, is one of the starting...Ch. 8 - Methanol (CH3OH) is also known as wood alcohol and...Ch. 8 - Nitrogen oxide (NO) has been found to be a key...Ch. 8 - Small amounts of oxygen gas can be prepared in the...Ch. 8 - In the late eighteenth century Priestley prepared...Ch. 8 - Prob. 24QAPCh. 8 - Strontium metal is responsible for the red color...Ch. 8 - Nitroglycerin, C3H5(NO3)3(l), is an explosive most...Ch. 8 - A typical fat in the body is glyceryl trioleate,...Ch. 8 - Use the same fat described in Question 27. (a)...Ch. 8 - Which requires the absorption of a greater amount...Ch. 8 - Which evolves more heat—freezing 100.0 g of...Ch. 8 - A student is asked to calculate the amount of heat...Ch. 8 - Follow the step-wise process outlined in Problem...Ch. 8 - A lead ore, galena, consisting mainly of lead(II)...Ch. 8 - A reaction used to produce the silicon for...Ch. 8 - Given the following thermochemical equations,...Ch. 8 - Given the following thermochemical equations:...Ch. 8 - Write thermochemical equations for the...Ch. 8 - Write thermochemical equations for the formation...Ch. 8 - Given 2Al2O3(s)4Al(s)+3O2(g)H=3351.4kJ (a) What is...Ch. 8 - Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What...Ch. 8 - Limestone, CaCO3, when subjected to a temperature...Ch. 8 - When hydrazine reacts with oxygen, nitrogen gas...Ch. 8 - Use Table 8.3 to obtain AHO for the following...Ch. 8 - Use Table 8.3 to obtain H for the following...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - When one mole of nitroglycerine, C3H5(NO3)3(l)...Ch. 8 - When one mole of calcium carbonate reacts with...Ch. 8 - Chlorine trifluoride is a toxic, intensely...Ch. 8 - When one mole of ethylene gas, C2H4, reacts with...Ch. 8 - Glucose, C6H12O6(s), (H f =1275.2kJ/mol) is...Ch. 8 - When ammonia reacts with dinitrogen oxide gas (H f...Ch. 8 - How many kJ are equal to 3.27 L atm of work?Ch. 8 - How many L atm are equal to 12.2 kJ of work?Ch. 8 - Find (a) E when a gas absorbs 18 J of heat and has...Ch. 8 - Calculate (a) q when a system does 54 J of work...Ch. 8 - Consider the following reaction in a vessel with a...Ch. 8 - Consider the following reaction in the vessel...Ch. 8 - Determine the difference between H and E at 25C...Ch. 8 - For the vaporization of one mole of bromine at...Ch. 8 - Consider the combustion of propane, C3H8, the fuel...Ch. 8 - Consider the combustion of one mole of methyl...Ch. 8 - Butane gas, C4H10, is sold to campers as bottled...Ch. 8 - The BTU (British thermal unit) is the unit of...Ch. 8 - Natural gas companies in the United States use the...Ch. 8 - Prob. 66QAPCh. 8 - Given the following reactions,...Ch. 8 - In World War II, the Germans made use of otherwise...Ch. 8 - Prob. 69QAPCh. 8 - Consider the reaction between methane and oxygen...Ch. 8 - Consider burning ethane gas, C2H6 in oxygen...Ch. 8 - On complete combustion at constant pressure, a...Ch. 8 - Microwave ovens convert radiation to energy. A...Ch. 8 - In 2010, 3.30109 gallons of gasoline were consumed...Ch. 8 - Some solar-heated homes use large beds of rocks to...Ch. 8 - Consider a solution prepared by dissolving 10.00 g...Ch. 8 - Draw a cylinder with a movable piston containing...Ch. 8 - Redraw the cylinder in Question 77 after work has...Ch. 8 - Which statement(s) is/are true about bond...Ch. 8 - Equal masses of liquid A, initially at 100C, and...Ch. 8 - Determine whether the statements given below are...Ch. 8 - An exothermic reaction is carried out in a...Ch. 8 - Determine whether the statements given below are...Ch. 8 - Microwave ovens emit microwave radiation that is...Ch. 8 - On a hot day, you take a six-pack ot a on a pcmc,...Ch. 8 - Prob. 86QAPCh. 8 - The thermite reaction was once used to weld rails:...Ch. 8 - A sample of sucrose, C12H22O11, is contaminated by...Ch. 8 - A wad of steel wool (specific heat=0.45J/gC) at...Ch. 8 - Consider a metal ion A2+ and its nitrate salt, In...
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