EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
Publisher: VST
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Chapter 8, Problem 49E
Calculate the theoretical yield of the product (in moles) for each initial amount of reactants Ti(s) + 2 Cl2(g) → TiCl4(s)
- 4 mol Ti, 4 mol Cl 2
- 7 mol Ti. 17 mol Cl 2
- 12.4 mol Ti, 18.8 mol Cl 2
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Synthesis of Dibenzalacetone
[References]
Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the enone below.
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You do not have to consider stereochemistry.
. Draw the enolate ion in its carbanion form.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
⚫ Separate multiple reactants using the + sign from the drop-down menu.
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4
Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)
Chapter 8 Solutions
EBK CHEMISTRY
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