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Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt = 41°C. Reversible melting experiments indicate that at Tm AHm=37.7 kJ mol-1. Calculate: A. The entropy of melting, ASm- B. The Gibbs free energy of melting, AGm- C. Does the membrane become more or less ordered upon melting? D. There are 32 rotatable CH2 CH2 bonds in each molecule that can rotate more freely if the membrane melts. What is the increase in multiplicity on melting a mole of bonds?
5. Heat capacity often has a temperature dependence for real molecules, particularly if you go over a large temperature range. The heat capacity for liquid n-butane can be fit to the equation Cp(T) = a + bT where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K) to its boiling point (T₁ = 270 K). A. Compute AH for heating butane from 170 K to 270 K. B. Compute AS for the same temperature range.
4. How much energy must be transferred as heat to cause the quasi-static isothermal expansion of one mole of an ideal gas at 300 K from PA = 1 bar to PB = 0.5 bar? A. What is VA? B. What is VB? C. What is AU for the process? D. What is AH for the process? E. What is AS for the process?

Chapter 8 Solutions

Modified Mastering Physics without Pearson eText-- Instant Access -- for Physics for Scientists & Engineers with Modern Physics

Ch. 8 - Can the total mechanical energy E=K+Uever be...Ch. 8 - Describe the energy transformations when a child...Ch. 8 - Prob. 10QCh. 8 - Recall from Chapter 4, Example 414, that you can...Ch. 8 - Two identical arrows, one with twice the speed of...Ch. 8 - In Mg. 825, water balloons are tossed from the...Ch. 8 - Suppose that you wish to launch a rocket from the...Ch. 8 - Suppose you lift a suitcase from the floor to a...Ch. 8 - Repeat Question 23 for the power needed instead of...Ch. 8 - Why is it easier to climb a mountain via a zigzag...Ch. 8 - Prob. 18QCh. 8 - Prob. 19QCh. 8 - (a) Describe in detail the velocity changes of a...Ch. 8 - Prob. 1MCQCh. 8 - Prob. 2MCQCh. 8 - Prob. 3MCQCh. 8 - Prob. 4MCQCh. 8 - Prob. 5MCQCh. 8 - Prob. 6MCQCh. 8 - Prob. 7MCQCh. 8 - Prob. 8MCQCh. 8 - Prob. 9MCQCh. 8 - Prob. 10MCQCh. 8 - Prob. 11MCQCh. 8 - Prob. 12MCQCh. 8 - Prob. 13MCQCh. 8 - Prob. 1PCh. 8 - Prob. 2PCh. 8 - Prob. 3PCh. 8 - Prob. 4PCh. 8 - Prob. 5PCh. 8 - Prob. 6PCh. 8 - (II) A particle is constrained to move in one...Ch. 8 - (II) If U=3x2+2xy+4y2z, what is the force, F?Ch. 8 - Prob. 9PCh. 8 - Prob. 10PCh. 8 - Prob. 11PCh. 8 - (I) Jane, looking for Tarzan, is running at top...Ch. 8 - Prob. 13PCh. 8 - Prob. 14PCh. 8 - Prob. 15PCh. 8 - Prob. 16PCh. 8 - Prob. 17PCh. 8 - Prob. 18PCh. 8 - Prob. 19PCh. 8 - (II) A roller-coaster car shown in Fig. 832 is...Ch. 8 - (II) When a mass m sits at rest on a spring, the...Ch. 8 - Prob. 22PCh. 8 - Prob. 23PCh. 8 - Prob. 24PCh. 8 - Prob. 25PCh. 8 - (III) A skier of mass m starts from rest at the...Ch. 8 - Prob. 27PCh. 8 - Prob. 28PCh. 8 - (II) A ski starts from rest and slides down a 28...Ch. 8 - Prob. 30PCh. 8 - Prob. 31PCh. 8 - Prob. 32PCh. 8 - Prob. 33PCh. 8 - Prob. 34PCh. 8 - Prob. 35PCh. 8 - Prob. 36PCh. 8 - Prob. 37PCh. 8 - (III) A spring (k = 75 N/m) has an equilibrium...Ch. 8 - Prob. 39PCh. 8 - Prob. 40PCh. 8 - Prob. 41PCh. 8 - (I) For a satellite of mass mS in a circular orbit...Ch. 8 - (II) Show that Eq. 816 for gravitational potential...Ch. 8 - (II) Determine the escape velocity from the Sun...Ch. 8 - Prob. 45PCh. 8 - Prob. 46PCh. 8 - (II) Take into account the Earths rotational speed...Ch. 8 - (II) (a) Determine a formula for the maximum...Ch. 8 - Prob. 49PCh. 8 - Prob. 50PCh. 8 - (II) How much work would be required to move a...Ch. 8 - (II) A sphere of radius r1 has a concentric...Ch. 8 - (II) (a) Show that the total mechanical energy of...Ch. 8 - Prob. 54PCh. 8 - Prob. 55PCh. 8 - Prob. 56PCh. 8 - (I) An 85-kg football player traveling 5.0 m/s is...Ch. 8 - (I) If a car generates 18 hp when traveling at a...Ch. 8 - Prob. 59PCh. 8 - Prob. 60PCh. 8 - Prob. 61PCh. 8 - Prob. 62PCh. 8 - Prob. 63PCh. 8 - Prob. 64PCh. 8 - Prob. 65PCh. 8 - Prob. 66PCh. 8 - Prob. 67PCh. 8 - Prob. 68PCh. 8 - Prob. 69PCh. 8 - (III) A bicyclist coasts clown a 6.0 hill at a...Ch. 8 - Draw a potential energy diagram, U vs. x, and...Ch. 8 - Prob. 72PCh. 8 - Prob. 73PCh. 8 - (III) The potential energy of the two atoms in a...Ch. 8 - (III) The binding energy of a two-particle system...Ch. 8 - Prob. 78GPCh. 8 - Prob. 79GPCh. 8 - Prob. 80GPCh. 8 - Prob. 81GPCh. 8 - A ball is attached to a horizontal cord of length ...Ch. 8 - Show the h must be greater than 0.60 if the ball...Ch. 8 - Prob. 84GPCh. 8 - Prob. 85GPCh. 8 - Prob. 86GPCh. 8 - Prob. 87GPCh. 8 - Prob. 88GPCh. 8 - The small mass m sliding without friction along...Ch. 8 - Some electric power companies use water to store...Ch. 8 - A film of Jesse Owenss famous long jump (Fig. 849)...Ch. 8 - The nuclear force between two neutrons in a...Ch. 8 - Prob. 93GPCh. 8 - A fire hose for use in urban areas must be able to...Ch. 8 - Prob. 95GPCh. 8 - (II) (a) Suppose we have three masses, m1, m2, and...Ch. 8 - Prob. 97GPCh. 8 - Prob. 98GPCh. 8 - Prob. 99GPCh. 8 - Suppose the gravitational potential energy of an...Ch. 8 - A particle of mass m moves under the influence of...Ch. 8 - Prob. 102GPCh. 8 - Prob. 103GPCh. 8 - Prob. 104GP
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