INTRODUCTORY CHEMISTRY-W/MOD.MASTERING.
6th Edition
ISBN: 9780134809922
Author: Tro
Publisher: PEARSON
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Chapter 8, Problem 3E
Write the conversion factor that you would use to convert form moles of
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
Check
×
1
How many signals do you expect in the 'H NMR spectrum for this molecule?
CI CI
Cl
Write the answer in the table below.
Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all
other H atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum.
1
Number of signals in the 'H NMR spectrum.
☐
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same
signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional H atoms to highlight in
top molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the
same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at…
wrtie the balanced equation and find the E° when the following half- reactions are combined
Zn2+(aq) + 2e---> Zn(s) E°= -0.763V
Ag+(aq) + e---> Ag (s) E°=+0.799V
Chapter 8 Solutions
INTRODUCTORY CHEMISTRY-W/MOD.MASTERING.
Ch. 8 - Q1. Sulfur and fluorine react to form sulfur...Ch. 8 - Hydrogen chloride gas and oxygen gas react to form...Ch. 8 - Sodium reacts with fluorine to form sodium...Ch. 8 - Consider the hypothetical reaction shown here. If...Ch. 8 - Prob. 5SAQCh. 8 - Prob. 6SAQCh. 8 - Sodium and chlorine react to form sodium chloride....Ch. 8 - A reaction has a theoretical yield of 22.8 g. when...Ch. 8 - Titanium can be obtained from its oxide by the...Ch. 8 - Which statement best describes an exothermic...
Ch. 8 - Consider the generic reaction: A+2BAB2Hrxn=155kJ...Ch. 8 - Q12. Hydrogen gas reacts with oxygen to form...Ch. 8 - Prob. 1ECh. 8 - Nitrogen and hydrogen can react to from ammonia:...Ch. 8 - 3. Write the conversion factor that you would use...Ch. 8 - 4. What is wrong with this statement in reference...Ch. 8 - 5 what is the general from of the solution map...Ch. 8 - 6. Consider the recipe for making tomato and...Ch. 8 - 7 In a chemical reaction, what is the limiting...Ch. 8 - Prob. 8ECh. 8 - In a chemical reaction, what are the actual yield...Ch. 8 - If you are given a chemical equation and specific...Ch. 8 - 11. Consider the generic chemical...Ch. 8 - Prob. 12ECh. 8 - What is the enthalpy of reaction (Hrxn)? Why is...Ch. 8 - Explain the relationship between the sign of Hrxn...Ch. 8 - Consider the generic chemical reaction: A+2BC How...Ch. 8 - Consider the generic chemical reaction: 2A+3B3C...Ch. 8 - 17. For the reaction shown, calculate how many...Ch. 8 - 18. For the reaction shown, calculate how many...Ch. 8 - 19. Dihydrogen monosulfide reacts with sulfur...Ch. 8 - 20. Chlorine gas reacts with fluorine gas...Ch. 8 - For each reaction, calculate how many moles of...Ch. 8 - 22. For each reaction, calculate how many moles of...Ch. 8 - 23. For the reaction shown, calculate how many...Ch. 8 - 24. For the reaction shown, calculate how many...Ch. 8 - Consider the balanced equation:...Ch. 8 - 26. Consider the balance equation:
Complete the...Ch. 8 - 27. Consider the unbalanced equation for the...Ch. 8 - 28. Consider the unbalanced equation for the...Ch. 8 - 29. Consider the unbalanced equation for the...Ch. 8 - 30. Consider the unbalanced equation for the...Ch. 8 - Prob. 31ECh. 8 - 32. For the reaction shown, calculate how many...Ch. 8 - For each of the reactions, calculate how many...Ch. 8 - 34. For each of the reactions, calculate how many...Ch. 8 - 35. For the reaction shown, calculate how many...Ch. 8 - 36. For the reaction shown, calculate how many...Ch. 8 - Prob. 37ECh. 8 - Consider the balanced equation for the combustion...Ch. 8 - 39. For each acid–base reaction, calculate how...Ch. 8 - 40. For each precipitation reaction, calculate how...Ch. 8 - Sulfuric acid can dissolve aluminum metal...Ch. 8 - Hydrochloric acid can dissolve solid iron...Ch. 8 - 43. Consider the generic chemical equation:
a....Ch. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - 49. For the reaction shown, calculate the...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - Consider the generic reaction between reactants A...Ch. 8 - Consider the reaction between reactants S and O2:...Ch. 8 - Consider the reaction 4HCI(g)+O2(g)2H2O(g)+2Cl2(g)...Ch. 8 - 54. Consider the reaction
Each molecular diagram...Ch. 8 - 55. For the reaction shown, find the limiting...Ch. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - 58. If the theoretical yield of a reaction is 24.8...Ch. 8 - If the theoretical yield of reaction is 0.118 g...Ch. 8 - 61. Consider the reaction between calcium oxide...Ch. 8 - Consider the reaction between sulfur trioxide and...Ch. 8 - Consider the reaction between NiS2 and O2:...Ch. 8 - Consider the reaction between HCI and O2...Ch. 8 - Lead ions can be precipitate form solution with...Ch. 8 -
Ch. 8 - Consider the reaction between TiO2 and C:...Ch. 8 - 68. Consider the raction between N2H4 and N2O4:
A...Ch. 8 - 69. Classify each process as exothermic or...Ch. 8 - 70. Classify each process as exothermic or...Ch. 8 - Consider the generic reaction: A+2BCHrxn=55kJ...Ch. 8 - Prob. 72ECh. 8 - Consider the equation for the combustion of...Ch. 8 - The equation for the combustion of CH4 (the main...Ch. 8 - 75. Octane (C8H18) is a component of gasoline that...Ch. 8 - 76. The evaporation of water is...Ch. 8 - Consider the reaction:...Ch. 8 - Prob. 78ECh. 8 - A solution contains an unknown mass of dissolved...Ch. 8 - 80. A solution contains an unknown mass of...Ch. 8 - 81. Sodium bicarbonate is often used as an antacid...Ch. 8 - Toilet bowl cleaners often contain hydrochloric...Ch. 8 - 83. The combustion of gasoline produces carbon...Ch. 8 - Many home barbecues are fueled with propane gas...Ch. 8 - Prob. 85ECh. 8 - 86. Magnesium ions can be precipitated from...Ch. 8 - Hydrogen gas can be prepared in the laboratory by...Ch. 8 - Sodium peroxide (Na2O2) reacts with water to form...Ch. 8 - Prob. 89ECh. 8 - Pure oxygen gas can be prepared in the laboratory...Ch. 8 - 91. Aspirin can be made in the laboratory by...Ch. 8 - 92. The combustion of liquid ethanol produces...Ch. 8 - Urea (CH4N2 O), a common fertilizer, can be...Ch. 8 - 94. Silicon, which occurs in nature as SiO2, is...Ch. 8 - 95. The ingestion of lead from food, water, or...Ch. 8 - Prob. 96ECh. 8 - The propane fuel (C3H8) used in gas barbecues...Ch. 8 - Charcoal is primarily carbon. Determine the mass...Ch. 8 - 99. A loud classroom demonstration involves...Ch. 8 - 100. A hydrochloric acid solution will neutralize...Ch. 8 - 101. Scientists have grown progressively more...Ch. 8 - Prob. 102ECh. 8 - What volume of air is needed to burn an entire...Ch. 8 - Have each member of your group choose a...Ch. 8 - 105. Consider the combustion of propane:
a....
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- Consider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 'H NMR spectrum? Note: A multiplet is considered one signal. ☐arrow_forwardStudy this 'H NMR spectrum, and then answer the questions about it in the table below. Check 1.0- 0.5- 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 What unit symbol should be written on the horizontal axis? What is the chemical shift & of the doublet? If there is no doublet, just check the box instead. Give your answer to 2 significant digits. What is the chemical shift of the signal immediately upfield of the doublet? If there is no doublet, or no signal upfield of it, check the box instead. What is the chemical shift & of the least deshielded proton? If you can't tell without more information, check the box instead. 血 8 = ☐ There is no doublet. 8 = ☐ No such signal. 8 = 0 Need more information.arrow_forwardhow many moles of H2O2 are required to react with 11g of N2H4 according to the following reaction? (atomic weights: N=14.01, H=1.008, O= 16.00) 7H2O2 + N2H4 -> 2HNO3 + 8H20arrow_forward
- calculate the number of moles of H2 produced from 0.78 moles of Ga and 1.92 moles HCL? 2Ga+6HCL->2GaCl3+3H2arrow_forwardan adult human breathes 0.50L of air at 1 atm with each breath. If a 50L air tank at 200 atm is available, how man y breaths will the tank providearrow_forwardWhat are the advantages and/or disadvantages of using the MOHR titration method & AOEC method?arrow_forward
- Are there any alternative methods better than the MOHR titration to quantitatively determine salt in a sample?arrow_forwardhybridization of nitrogen of complex moleculesarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1arrow_forward
- Why do we analyse salt?arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H H CH3OH, H+ H Select to Add Arrows H° 0:0 'H + Q HH ■ Select to Add Arrows CH3OH, H* H. H CH3OH, H+ HH ■ Select to Add Arrows i Please select a drawing or reagent from the question areaarrow_forwardWhat are examples of analytical methods that can be used to analyse salt in tomato sauce?arrow_forward
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