(a) Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation. Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene . A concerted mechanism is followed for this type of reactions and by-products are also possible.

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Answer 1

Question

Chapter 8, Problem 35P

Interpretation Introduction

(a)

Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation.

Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene. A concerted mechanism is followed for this type of reactions and by-products are also possible.

Interpretation Introduction

(b)

Interpretation: The effect of the given change on the reaction rate is to be stated.

Concept introduction: In E2 elimination reactions, substituents which are adjacent to each other are eliminated from an alkyl halide to form an alkene. A concerted mechanism is followed for this type of reactions.

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bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

PROBLEM 4 Solved Show how 1-butanol can be converted into the following compounds: a. PROBLEM 5+ b. d. -C= N

Which alkene is the major product of this dehydration? OH H2SO4 heat

Answer 2

Question

Chapter 8, Problem 35P

Interpretation Introduction

(a)

Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation.

Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene. A concerted mechanism is followed for this type of reactions and by-products are also possible.

Interpretation Introduction

(b)

Interpretation: The effect of the given change on the reaction rate is to be stated.

Concept introduction: In E2 elimination reactions, substituents which are adjacent to each other are eliminated from an alkyl halide to form an alkene. A concerted mechanism is followed for this type of reactions.

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Answer 3

Question

Chapter 8, Problem 35P

Interpretation Introduction

(a)

Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation.

Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene. A concerted mechanism is followed for this type of reactions and by-products are also possible.

Interpretation Introduction

(b)

Interpretation: The effect of the given change on the reaction rate is to be stated.

Concept introduction: In E2 elimination reactions, substituents which are adjacent to each other are eliminated from an alkyl halide to form an alkene. A concerted mechanism is followed for this type of reactions.

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Answer 4

Question

Chapter 8, Problem 35P

Interpretation Introduction

(a)

Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation.

Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene. A concerted mechanism is followed for this type of reactions and by-products are also possible.

Interpretation Introduction

(b)

Interpretation: The effect of the given change on the reaction rate is to be stated.

Concept introduction: In E2 elimination reactions, substituents which are adjacent to each other are eliminated from an alkyl halide to form an alkene. A concerted mechanism is followed for this type of reactions.

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Answer 5

Chapter 8, Problem 35P

Interpretation Introduction

(a)

Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation.

Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene. A concerted mechanism is followed for this type of reactions and by-products are also possible.

Interpretation Introduction

(b)

Interpretation: The effect of the given change on the reaction rate is to be stated.

Concept introduction: In E2 elimination reactions, substituents which are adjacent to each other are eliminated from an alkyl halide to form an alkene. A concerted mechanism is followed for this type of reactions.

Answer 6

Chapter 8, Problem 35P

Interpretation Introduction

(a)

Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation.

Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene. A concerted mechanism is followed for this type of reactions and by-products are also possible.

Answer 7

Chapter 8, Problem 35P

Interpretation Introduction

(a)

Interpretation: The by-products of the given reaction are to be drawn and the movement of electrons is to be shown by using curved arrow notation.

Concept introduction: In E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene. A concerted mechanism is followed for this type of reactions and by-products are also possible.

Answer 8

Interpretation Introduction

(b)

Interpretation: The effect of the given change on the reaction rate is to be stated.

Concept introduction: In E2 elimination reactions, substituents which are adjacent to each other are eliminated from an alkyl halide to form an alkene. A concerted mechanism is followed for this type of reactions.

Answer 9

Interpretation Introduction

(b)

Interpretation: The effect of the given change on the reaction rate is to be stated.

Concept introduction: In E2 elimination reactions, substituents which are adjacent to each other are eliminated from an alkyl halide to form an alkene. A concerted mechanism is followed for this type of reactions.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.1 - Problem 8.1 Label the and carbons in each alkyl...Ch. 8.2 - Problem 8.2 Classify each alkene in the following...Ch. 8.2 - Prob. 3P Ch. 8.2 - Prob. 4P Ch. 8.2 - Problem 8.5 Label each pair of alkenes as...Ch. 8.2 - Problem 8.6 Which alkene in each pair is more...Ch. 8.2 - Problem 8.7 Several factors can affect alkene...Ch. 8.4 - Prob. 8P Ch. 8.4 - Prob. 9P Ch. 8.4 - Prob. 10P

Solution Summary: The author explains that in E2 elimination reactions, the proton is abstracted from the beta carbon to form an alkene.

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