Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 8, Problem 1E
Interpretation Introduction
Interpretation: The importance of reaction stoichiometry is to be explained with the help of examples.
Concept introduction: Reaction stoichiometry is defined as the numerical relationships between the quantities in a balanced chemical equation.
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 8 Solutions
Introductory Chemistry (6th Edition)
Ch. 8 - Q1. Sulfur and fluorine react to form sulfur...Ch. 8 - Hydrogen chloride gas and oxygen gas react to form...Ch. 8 - Sodium reacts with fluorine to form sodium...Ch. 8 - Consider the hypothetical reaction shown here. If...Ch. 8 - Prob. 5SAQCh. 8 - Prob. 6SAQCh. 8 - Sodium and chlorine react to form sodium chloride....Ch. 8 - A reaction has a theoretical yield of 22.8 g. when...Ch. 8 - Titanium can be obtained from its oxide by the...Ch. 8 - Which statement best describes an exothermic...
Ch. 8 - Consider the generic reaction: A+2BAB2Hrxn=155kJ...Ch. 8 - Q12. Hydrogen gas reacts with oxygen to form...Ch. 8 - Prob. 1ECh. 8 - Nitrogen and hydrogen can react to from ammonia:...Ch. 8 - 3. Write the conversion factor that you would use...Ch. 8 - 4. What is wrong with this statement in reference...Ch. 8 - 5 what is the general from of the solution map...Ch. 8 - 6. Consider the recipe for making tomato and...Ch. 8 - 7 In a chemical reaction, what is the limiting...Ch. 8 - Prob. 8ECh. 8 - In a chemical reaction, what are the actual yield...Ch. 8 - If you are given a chemical equation and specific...Ch. 8 - 11. Consider the generic chemical...Ch. 8 - Prob. 12ECh. 8 - What is the enthalpy of reaction (Hrxn)? Why is...Ch. 8 - Explain the relationship between the sign of Hrxn...Ch. 8 - Consider the generic chemical reaction: A+2BC How...Ch. 8 - Consider the generic chemical reaction: 2A+3B3C...Ch. 8 - 17. For the reaction shown, calculate how many...Ch. 8 - 18. For the reaction shown, calculate how many...Ch. 8 - 19. Dihydrogen monosulfide reacts with sulfur...Ch. 8 - 20. Chlorine gas reacts with fluorine gas...Ch. 8 - For each reaction, calculate how many moles of...Ch. 8 - 22. For each reaction, calculate how many moles of...Ch. 8 - 23. For the reaction shown, calculate how many...Ch. 8 - 24. For the reaction shown, calculate how many...Ch. 8 - Consider the balanced equation:...Ch. 8 - 26. Consider the balance equation:
Complete the...Ch. 8 - 27. Consider the unbalanced equation for the...Ch. 8 - 28. Consider the unbalanced equation for the...Ch. 8 - 29. Consider the unbalanced equation for the...Ch. 8 - 30. Consider the unbalanced equation for the...Ch. 8 - Prob. 31ECh. 8 - 32. For the reaction shown, calculate how many...Ch. 8 - For each of the reactions, calculate how many...Ch. 8 - 34. For each of the reactions, calculate how many...Ch. 8 - 35. For the reaction shown, calculate how many...Ch. 8 - 36. For the reaction shown, calculate how many...Ch. 8 - Prob. 37ECh. 8 - Consider the balanced equation for the combustion...Ch. 8 - 39. For each acid–base reaction, calculate how...Ch. 8 - 40. For each precipitation reaction, calculate how...Ch. 8 - Sulfuric acid can dissolve aluminum metal...Ch. 8 - Hydrochloric acid can dissolve solid iron...Ch. 8 - 43. Consider the generic chemical equation:
a....Ch. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - 49. For the reaction shown, calculate the...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - Consider the generic reaction between reactants A...Ch. 8 - Consider the reaction between reactants S and O2:...Ch. 8 - Consider the reaction 4HCI(g)+O2(g)2H2O(g)+2Cl2(g)...Ch. 8 - 54. Consider the reaction
Each molecular diagram...Ch. 8 - 55. For the reaction shown, find the limiting...Ch. 8 - For the reaction shown, find the limiting reactant...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - 58. If the theoretical yield of a reaction is 24.8...Ch. 8 - If the theoretical yield of reaction is 0.118 g...Ch. 8 - 61. Consider the reaction between calcium oxide...Ch. 8 - Consider the reaction between sulfur trioxide and...Ch. 8 - Consider the reaction between NiS2 and O2:...Ch. 8 - Consider the reaction between HCI and O2...Ch. 8 - Lead ions can be precipitate form solution with...Ch. 8 -
Ch. 8 - Consider the reaction between TiO2 and C:...Ch. 8 - 68. Consider the raction between N2H4 and N2O4:
A...Ch. 8 - 69. Classify each process as exothermic or...Ch. 8 - 70. Classify each process as exothermic or...Ch. 8 - Consider the generic reaction: A+2BCHrxn=55kJ...Ch. 8 - Prob. 72ECh. 8 - Consider the equation for the combustion of...Ch. 8 - The equation for the combustion of CH4 (the main...Ch. 8 - 75. Octane (C8H18) is a component of gasoline that...Ch. 8 - 76. The evaporation of water is...Ch. 8 - Consider the reaction:...Ch. 8 - Prob. 78ECh. 8 - A solution contains an unknown mass of dissolved...Ch. 8 - 80. A solution contains an unknown mass of...Ch. 8 - 81. Sodium bicarbonate is often used as an antacid...Ch. 8 - Toilet bowl cleaners often contain hydrochloric...Ch. 8 - 83. The combustion of gasoline produces carbon...Ch. 8 - Many home barbecues are fueled with propane gas...Ch. 8 - Prob. 85ECh. 8 - 86. Magnesium ions can be precipitated from...Ch. 8 - Hydrogen gas can be prepared in the laboratory by...Ch. 8 - Sodium peroxide (Na2O2) reacts with water to form...Ch. 8 - Prob. 89ECh. 8 - Pure oxygen gas can be prepared in the laboratory...Ch. 8 - 91. Aspirin can be made in the laboratory by...Ch. 8 - 92. The combustion of liquid ethanol produces...Ch. 8 - Urea (CH4N2 O), a common fertilizer, can be...Ch. 8 - 94. Silicon, which occurs in nature as SiO2, is...Ch. 8 - 95. The ingestion of lead from food, water, or...Ch. 8 - Prob. 96ECh. 8 - The propane fuel (C3H8) used in gas barbecues...Ch. 8 - Charcoal is primarily carbon. Determine the mass...Ch. 8 - 99. A loud classroom demonstration involves...Ch. 8 - 100. A hydrochloric acid solution will neutralize...Ch. 8 - 101. Scientists have grown progressively more...Ch. 8 - Prob. 102ECh. 8 - What volume of air is needed to burn an entire...Ch. 8 - Have each member of your group choose a...Ch. 8 - 105. Consider the combustion of propane:
a....
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