Chemistry: The Central Science (13th Edition)
Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 8, Problem 1DE
Interpretation Introduction

Interpretation: The name or formula of the given coordination compounds is to be determined.

Concept Introduction: The name of the ligands is written first in the alphabetical order followed by the name and oxidation state of transition metal ion.

(a)

To determine: The name of the given coordination complex [Mo( NH 3)3Br3]NO3 .

Expert Solution
Check Mark

Answer to Problem 1DE

Solution:

The name of the given coordination compound is Triamminetribromomolybdenum(IV) nitrate.

Explanation of Solution


The nomenclature of coordination compound is based on the certain rules which are written as,

  1. The cation is named first followed by anion.
  2. The ligands are named before metal ion in the alphabetical order.
  3. The oxidation state of the metal ion is written just after the name of the metal.

The given complex contains three ammonia molecules which are named as triammine and three bromine molecules written as tribromo. Thus, the name of the given coordination compound is Triamminetribromomolybdenum(IV) nitrate.

Conclusion


The name of the given coordination compound is Triamminetribromomolybdenum(IV) nitrate.

(b)

Interpretation Introduction

To determine: The name of the given coordination complex ( NH3)2[CuBr4] .

(b)

Expert Solution
Check Mark

Answer to Problem 1DE

Solution:

The name of the given coordination compound is Ammonium tetrabromocuprate(II).

Explanation of Solution


The nomenclature of coordination compound is based on the certain rules which are written as,

  1. The cation is named first followed by anion.
  2. The ligands are named before metal ion in the alphabetical order.
  3. The oxidation state of the metal ion is written just after the name of the metal.

The given complex contains four bromine molecules written as tetrabromo. Thus, the name of the given coordination compound on the basis of the given rules is Ammonium tetrabromocuprate(II).

Conclusion

The name of the given coordination compound is Ammonium tetrabromocuprate(II).

(c)

Interpretation Introduction

To determine: The formula of the given coordination compound sodium diaquabis(oxalate)ruthenate(III).

(c)

Expert Solution
Check Mark

Answer to Problem 1DE

Solution: The formula of the given coordination compound is Na[Ru( H 2O)2( C 2 O 4)2] .

Explanation of Solution

The nomenclature of coordination compound is based on the certain rules which are written as,

  1. The cation is named first followed by anion.
  2. The ligands are named before metal ion in the alphabetical order.
  3. The oxidation state of the metal ion is written just after the name of the metal.
The given name has sodium as a cation, it is written first. After that the name of ligands is diaqua means two water molecules and bis oxalate means two oxalate molecules; thereby ruthenate as the transition metal ion. Thus, the formula of the given coordination compound on the basis of the given rules is Na[Ru( H 2O)2( C 2 O 4)2] .
Conclusion

The formula of the given coordination compound is Na[Ru( H 2O)2( C 2 O 4)2] .

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Chapter 8 Solutions

Chemistry: The Central Science (13th Edition)

Ch. 8.5 - Prob. 8.6.1PECh. 8.5 - Prob. 8.6.2PECh. 8.5 - Prob. 8.7.1PECh. 8.5 - Prob. 8.7.2PECh. 8.5 - Prob. 8.8.1PECh. 8.5 - Prob. 8.8.2PECh. 8.5 - Prob. 8.9.1PECh. 8.5 - Prob. 8.9.2PECh. 8.6 - Prob. 8.10.1PECh. 8.6 - Prob. 8.10.2PECh. 8.7 - Prob. 8.11.1PECh. 8.7 - Write the formulas for the following compounds,...Ch. 8.7 - Prob. 8.12.1PECh. 8.7 - Prob. 8.12.2PECh. 8 - Prob. 1DECh. 8 - Prob. 1ECh. 8 - The three graphs below show the variation in...Ch. 8 - Prob. 3ECh. 8 - Prob. 4ECh. 8 - Prob. 5ECh. 8 - Prob. 6ECh. 8 - The partial Lewis structure that follows Is for a...Ch. 8 - Prob. 8ECh. 8 - Prob. 9ECh. 8 - Prob. 10ECh. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Prob. 13ECh. 8 - Prob. 14ECh. 8 - Prob. 15ECh. 8 - Prob. 16ECh. 8 - Prob. 17ECh. 8 - Prob. 18ECh. 8 - What is the name of the compound [Rh(NH3)4Cl2]Cl ?...Ch. 8 - Prob. 20ECh. 8 - Which of the following complexes has an optical...Ch. 8 - Prob. 22ECh. 8 - Prob. 23ECh. 8 - Prob. 24ECh. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - Prob. 27ECh. 8 - Prob. 28ECh. 8 - Prob. 29ECh. 8 - Prob. 30ECh. 8 - Prob. 31ECh. 8 - Prob. 32ECh. 8 - Prob. 33ECh. 8 - Prob. 34ECh. 8 - Prob. 35ECh. 8 - Prob. 36ECh. 8 - Prob. 37ECh. 8 - Prob. 38ECh. 8 - Prob. 39ECh. 8 - Prob. 40ECh. 8 - Prob. 41ECh. 8 - Write out the ground-state electron configurations...Ch. 8 - Prob. 43ECh. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Prob. 48ECh. 8 - Prob. 49ECh. 8 - Prob. 50ECh. 8 - Prob. 51ECh. 8 - Indicate the coordination number and the oxidation...Ch. 8 - Prob. 53ECh. 8 - Prob. 54ECh. 8 - Prob. 55ECh. 8 - Prob. 56ECh. 8 - (a) Do the C—C bond lengths in benzene alternate...Ch. 8 - Prob. 58ECh. 8 - Prob. 59ECh. 8 - Write the formula for each of the following...Ch. 8 - Prob. 61ECh. 8 - Prob. 62ECh. 8 - Prob. 63ECh. 8 - Prob. 64ECh. 8 - Prob. 65ECh. 8 - Prob. 66ECh. 8 - Prob. 67ECh. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Prob. 71ECh. 8 - Prob. 72ECh. 8 - Prob. 73ECh. 8 - Prob. 74ECh. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Prob. 77AECh. 8 - Prob. 78AECh. 8 - Prob. 79AECh. 8 - Prob. 80AECh. 8 - Prob. 81AECh. 8 - Prob. 82AECh. 8 - Prob. 83AECh. 8 - Prob. 84AECh. 8 - 23.62 For each of the following metals, write the...Ch. 8 - Prob. 86AECh. 8 - Prob. 87AECh. 8 - Prob. 88AECh. 8 - Prob. 89AECh. 8 - Prob. 90AECh. 8 - (a) Determine the formal charge on the chlorine...Ch. 8 - Prob. 92AECh. 8 - Prob. 93AECh. 8 - Prob. 94AECh. 8 - Prob. 95AECh. 8 - Prob. 96AECh. 8 - Prob. 97AECh. 8 - Prob. 98AECh. 8 - Prob. 99AECh. 8 - Prob. 100AECh. 8 - Prob. 101IECh. 8 - Prob. 102IECh. 8 - Prob. 103IECh. 8 - Prob. 104IECh. 8 - Prob. 105IECh. 8 - Prob. 106IECh. 8 - Prob. 107IECh. 8 - Prob. 108IECh. 8 - Prob. 109IECh. 8 - Prob. 110IECh. 8 - 8.11 I Consider benzene (C6H6) in the gas phase....Ch. 8 - 8.112 Average bond enthalpies are generally...Ch. 8 - Prob. 113IE
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