4th Edition

ISBN: 9781259288722

Author: BAUER

Publisher: MCG

Concept explainers

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Textbook Question

Chapter 8, Problem 151QP

Which of the following always violets the octet rule?

A. a molecule or ion with sulfur as the central atom

B. a molecule with a central atom from the third period

C. a molecule with an odd no of electrons

D. a molecule with carbon as the central atom

E. a molecule containing multiple bonds

For each of the responses not selected, provide an example of a compound that illustrate why that response is not correct.

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Chapter 8, Problem 150QP

Chapter 8, Problem 152QP

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN

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Chapter 8 Solutions

Introduction to Chemistry

Ch. 8 - Prob. 1QC Ch. 8 - Prob. 2QC Ch. 8 - Prob. 3QC Ch. 8 - Prob. 4QC Ch. 8 - Prob. 5QC Ch. 8 - Prob. 1PP Ch. 8 - Prob. 2PP Ch. 8 - Prob. 3PP Ch. 8 - Prob. 4PP Ch. 8 - Prob. 5PP

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Solution Summary: The author explains that the octet rule states that each atom should have eight electrons in its valence shell, thus providing the same electronic configuration as that of a noble gas.

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