The resonance contributors for the given compound has to be drawn. Concept Introduction: Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure. Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds. Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 1

Question

Chapter 8, Problem 11P

a)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

b)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

c)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

d)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

e)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

f)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer d, e, and f

If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1

Briefly indicate the coordination forms of B and Si in borates and silicates, respectively.

Answer 2

Question

Chapter 8, Problem 11P

a)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

b)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

c)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

d)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

e)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

f)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 3

Question

Chapter 8, Problem 11P

a)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

b)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

c)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

d)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

e)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

f)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 4

Question

Chapter 8, Problem 11P

a)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

b)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

c)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

d)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

e)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

f)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 5

Chapter 8, Problem 11P

a)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

b)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

c)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

d)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

e)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

f)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 6

Chapter 8, Problem 11P

a)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 7

Chapter 8, Problem 11P

a)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 8

b)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 9

b)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 10

c)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 11

c)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 12

d)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 13

d)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 14

e)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 15

e)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 16

f)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 17

f)

Interpretation Introduction

Interpretation:

The resonance contributors for the given compound has to be drawn.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 5P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 7P Ch. 8.6 - Prob. 8P Ch. 8.8 - Prob. 9P Ch. 8.9 - Prob. 10P Ch. 8.9 - Prob. 12P

Solution Summary: The author explains how resonance contributors for a given compound are drawn. Delocalized electrons are shared between two or more atoms.

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Chapter 8 Solutions