
Selected Solutions Manual for Chemistry: Structure and Properties
2nd Edition
ISBN: 9780134460673
Author: Nivaldo J. Tro, Kathy Thrush-Shaginaw, Mary Beth Kramer
Publisher: PEARSON
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Question
Chapter 8, Problem 10SAQ
Interpretation Introduction
Interpretation:
To find out thesodium reaction with water according to the reqaction.
Concept Introduction:
The oxidation substance that causes the oxidation of other substance is called oxidation agents.
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3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
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P
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-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
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1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 8 Solutions
Selected Solutions Manual for Chemistry: Structure and Properties
Ch. 8 - What is an aqueous solution? What is the...Ch. 8 - What is molarity? How is it useful?Ch. 8 - Explain how a strong electrolyte, a weak...Ch. 8 - What is an acid? Explain the difference between a...Ch. 8 - What does it mean for a compound to be soluble?...Ch. 8 - What are the solubility rules? How are they...Ch. 8 - Which cations and anions form compounds that are...Ch. 8 - What is a precipitation reaction? Give an example.Ch. 8 - How can you predict whether a precipitation...Ch. 8 - Explain how a molecular equation, a complete ionic...
Ch. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Prob. 13ECh. 8 - Explain the principles behind an acid-base...Ch. 8 - Prob. 15ECh. 8 - Which reactant types give rise to gas-evolution...Ch. 8 - Prob. 17ECh. 8 - What are oxidation states? How can oxidation...Ch. 8 - What happens to a substance when it becomes...Ch. 8 - In a redox reaction, which reactant is the...Ch. 8 - Prob. 21ECh. 8 - Prob. 22ECh. 8 - What is the molarity of NO3- in each solution?...Ch. 8 - What is the molarity of Cl- in each solution?...Ch. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - A laboratory procedure calls for making 400.0 mL...Ch. 8 - Prob. 28ECh. 8 - If 123 mL of a 1.1 M glucose solution is diluted...Ch. 8 - If 3.5 L of a 4.8 M SrCl2 solution is diluted to...Ch. 8 - To what volume should you dilute 50.0 mL of a 12 M...Ch. 8 - Prob. 32ECh. 8 - Consider the precipitation reaction:...Ch. 8 - Consider the reaction:...Ch. 8 - What is the minimum amount of 6.0 M H2SO4...Ch. 8 - What molarity of ZnCl2forms when 25.0 g of zinc...Ch. 8 - You mix a 25.0 mL sample of a 1.20 M potassium...Ch. 8 - Prob. 38ECh. 8 - For each compound (all water soluble), would you...Ch. 8 - Classify each compound as a strong electrolyte or...Ch. 8 - Determine whether each compound is soluble or...Ch. 8 - Prob. 42ECh. 8 - Prob. 43ECh. 8 - Complete and balance each equation. If no reaction...Ch. 8 - Write a molecular equation for the precipitation...Ch. 8 - Write a molecular equation for the precipitation...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - Mercury ions (Hg22+) can be removed from solution...Ch. 8 - Lead ions can be removed from solution by...Ch. 8 - Name each acid. Hl(aq) HNO3(aq) H2CO3(aq)Ch. 8 - Name each acid HCI(aq) HClO2(aq) H2SO4(aq)Ch. 8 - Provide the formula for each acid hydrofluoric...Ch. 8 - Provide the formula for each acid phosphoric acid...Ch. 8 - Write balanced molecular and net ionic equations...Ch. 8 - Write balanced molecular and net ionic equations...Ch. 8 - Complete and balance each acid-base equation...Ch. 8 - Complete and balance each acid-base equation...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - Write balanced complete ionic and net ionic...Ch. 8 - A 25.00-mL sample of an unknown HClO4solution...Ch. 8 - A 30.00-mL sample of an unknown H3PO4 solution is...Ch. 8 - Complete and balance each gas-evolution equation:...Ch. 8 - Prob. 64ECh. 8 - Write a balanced equation for the reaction between...Ch. 8 - Prob. 66ECh. 8 - Assign oxidation states to each atom in each...Ch. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Determine whether or not each reaction is a redox...Ch. 8 - Determine whether or not each reaction is a redox...Ch. 8 - Determine whether each redox reaction occurs...Ch. 8 - Determine whether each redox reaction occurs...Ch. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Which metal in the activity series reduce Al3+...Ch. 8 - Prob. 78ECh. 8 - Prob. 79ECh. 8 - Prob. 80ECh. 8 - People often use sodium bicarbonate as an antacid...Ch. 8 - Toilet bowl cleaners often contain hydrochloric...Ch. 8 - Prob. 83ECh. 8 - Prob. 84ECh. 8 - Predict the products and write a balanced...Ch. 8 - Predict the products and write a balanced...Ch. 8 - Prob. 87ECh. 8 - Prob. 88ECh. 8 - Prob. 89ECh. 8 - A solution contains Cr3+ ion and Mg2+ ion. The...Ch. 8 - Find the volume of 0.110 M hydrochloric acid...Ch. 8 - Find the volume of 0.150 M sulfuric acid necessary...Ch. 8 - Treatment of gold metal with BrF3 and KF produces...Ch. 8 - We prepare a solution by mixing 0.10 L of 0.12 M...Ch. 8 - A solution contains Ag +and Hg2+ions. The addition...Ch. 8 - The water in lakes that have been acidified by...Ch. 8 - Recall from Section 8.5 that sodium carbonate is...Ch. 8 - A solution contains one or more of the following...Ch. 8 - A solution contains one or more of the following...Ch. 8 - Prob. 100ECh. 8 - Prob. 101ECh. 8 - Prob. 102ECh. 8 - Prob. 103ECh. 8 - Prob. 104ECh. 8 - Review the solubility rules. Without referring...Ch. 8 - Define and give an example of each of the...Ch. 8 - Prob. 107ECh. 8 - Prob. 108ECh. 8 - Prob. 1SAQCh. 8 - What mass (in grams) of Mg(NO3)2 is present in 145...Ch. 8 - Prob. 3SAQCh. 8 - Potassium iodide reacts with lead(ll) nitrate in...Ch. 8 - Which solution forms a precipitate when mixed with...Ch. 8 - What is the net ionic equation for the reaction...Ch. 8 - What is the net ionic equation for the reaction...Ch. 8 - What is the net ionic equation for the reaction...Ch. 8 - What is the oxidation state of carbon in CO32-? +3...Ch. 8 - Prob. 10SAQCh. 8 - Prob. 11SAQCh. 8 - Which of these ions will spontaneously react with...
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