EBK ORGANIC CHEMISTRY AS A SECOND LANGU
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
4th Edition
ISBN: 9781119234722
Author: Klein
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Chapter 7.7, Problem 7.48P
Interpretation Introduction

Interpretation:

Efficient synthesis has to be proposed for the given transformation.

EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 7.7, Problem 7.48P , additional homework tip  1

Expert Solution & Answer
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Explanation of Solution

Given transformation is,

EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 7.7, Problem 7.48P , additional homework tip  2

Looking into the reactant and product, it is found that the methoxy group is converted into chloride.  In order to accomplish the given transformation, the ester has to be converted into carboxylic acid and then to acid halide.

Conversion of carboxylic acid ester to carboxylic acid can be done using aqueous acid.

EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 7.7, Problem 7.48P , additional homework tip  3

Carboxylic acid when treated with thionyl chloride gives acid halide as the product.  This can be represented as,

EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 7.7, Problem 7.48P , additional homework tip  4

Therefore, the efficient synthesis can be given as,

EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 7.7, Problem 7.48P , additional homework tip  5

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Chapter 7 Solutions

EBK ORGANIC CHEMISTRY AS A SECOND LANGU

Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.4 - Predict the major products for each of the...Ch. 7.4 - Predict the major products for each of the...Ch. 7.4 - Predict the major products for each of the...Ch. 7.5 - Prob. 7.23PCh. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - In the space provided, draw a mechanism for each...Ch. 7.5 - In the space provided, draw a mechanism for each...Ch. 7.5 - Prob. 7.33PCh. 7.5 - Prob. 7.34PCh. 7.5 - Prob. 7.35PCh. 7.5 - Prob. 7.36PCh. 7.6 - Based on everything we have just seen, propose a...Ch. 7.6 - Prob. 7.39PCh. 7.6 - Prob. 7.40PCh. 7.6 - Prob. 7.41PCh. 7.6 - Propose a mechanism for the following reaction:Ch. 7.6 - Prob. 7.44PCh. 7.6 - Prob. 7.45PCh. 7.6 - Prob. 7.46PCh. 7.7 - Prob. 7.48PCh. 7.7 - Prob. 7.49PCh. 7.7 - Prob. 7.50PCh. 7.7 - Prob. 7.51PCh. 7.7 - Prob. 7.52PCh. 7.7 - Prob. 7.53PCh. 7.7 - Prob. 7.55PCh. 7.7 - Prob. 7.56PCh. 7.7 - Prob. 7.57PCh. 7.7 - Prob. 7.58PCh. 7.7 - Prob. 7.59PCh. 7.7 - Prob. 7.60PCh. 7.7 - Prob. 7.61PCh. 7.7 - Prob. 7.62PCh. 7.7 - Prob. 7.63PCh. 7.7 - Prob. 7.64PCh. 7.7 - Prob. 7.65P
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