EBK BASIC CHEMISTRY
6th Edition
ISBN: 9780134987088
Author: Timberlake
Publisher: PEARSON CO
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Chapter 7.6, Problem 57PP
A sample of nicotine, a poisonous compound found in tobacco leaves, contains 74.0% C, 8.70% H, and 17.3% N. If the experi-mental molar mass of nicotine is 162 g, what is its molecular formula?
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How would you use infrared spectroscopy to distinguish between the following pairs of constitutional isomers?
(a)
CH3C=CCH3
||
and
CH3CH2C=CH
(b)
CH3CCH=CHCH3
and
CH3CCH2CH=CH2
Problem 12-41
The mass spectrum (a) and the infrared spectrum (b) of an unknown hydrocarbon are shown. Propose as many
structures as you can.
(a)
100
Relative abundance (%)
80
60
60
40
200
20
(b)
100
Transmittance (%)
10
20
20
80-
60-
40-
20
40
60
80
100
120
140
m/z
500
4000 3500
3000
2500
2000
1500
Wavenumber (cm-1)
1000
Propagation of uncertainty. You have a stock solution certified by the manufacturer to contain 150.0±0.03 µg SO42-/mL. You would like to dilute it by a factor of 100 to obtain 1.500 µg/mL. Calculate the uncertainty in the two methods of dilution below. Use the following uncertainty values for glassware:
Glassware
Uncertainty
(assume glassware has been calibrated and treat the values below as random error)
1.00 mL volumetric pipet
0.01 mL
10.00 mL volumetric pipet
0.02 mL
100.00 mL volumetric flask
0.08 mL
Transfer 10.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask. Then take 10.00 mL of the resulting solution and dilute it a second time with a 100 mL flask.
2. Transfer 1.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask.
Chapter 7 Solutions
EBK BASIC CHEMISTRY
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 2.00...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Quinine, C20H24N2O2 , is a component of tonic...Ch. 7.1 - Aluminum sulfate, Al2(SO4)3 , is used in some...Ch. 7.1 - Naproxen is used to treat pain and inflammation...Ch. 7.1 - Benadryl is an over-the-counter drug used to treat...
Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, in 0.150 mol of each...Ch. 7.3 - Calculate the mass, in grams, in 2.28 mol of each...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in 25.0 g of each of...Ch. 7.3 - Calculate the number of moles in 4.00 g of each of...Ch. 7.3 - Calculate the mass, in grams, of C in each of the...Ch. 7.3 - Calculate the mass, in grams, of N in each of the...Ch. 7.3 - Propane gas, C3H8 , is used as a fuel for many...Ch. 7.3 - Allyl sulfide, (C3H5)2S , gives garlic, onions,...Ch. 7.3 - a. The compound MgSO4 , Epsom salts, is used to...Ch. 7.3 - Prob. 34PPCh. 7.3 - Prob. 35PPCh. 7.3 - Prob. 36PPCh. 7.4 - Calculate the mass percent composition of each of...Ch. 7.4 - Calculate the mass percent composition of each of...Ch. 7.4 - Prob. 39PPCh. 7.4 - Prob. 40PPCh. 7.4 - Prob. 41PPCh. 7.4 - Calculate the mass percent of S in each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.6 - Write the empirical formula for each of the...Ch. 7.6 - Prob. 48PPCh. 7.6 - The carbohydrate fructose found in honey and...Ch. 7.6 - Caffeine has an empirical formula of C4H5N2O . If...Ch. 7.6 - Prob. 51PPCh. 7.6 - Glyoxal, used in textiles; maleic acid, used to...Ch. 7.6 - Prob. 53PPCh. 7.6 - Prob. 54PPCh. 7.6 - Vanillic acid contains 57.14% C, 4.80% H, and...Ch. 7.6 - Lactic acid, the substance that builds up in...Ch. 7.6 - A sample of nicotine, a poisonous compound found...Ch. 7.6 - Adenine, a nitrogen-containing compound found in...Ch. 7.6 - Clavulanic acid has a molecular formula of C8H9NO5...Ch. 7.6 - Phenylpropanolamine (PPA) is used to treat urinary...Ch. 7 - The chapter sections to review are shown in...Ch. 7 - The chapter sections to review are shown in...Ch. 7 - The chapter sections to review are shown in...Ch. 7 - Prob. 64UTCCh. 7 - Prob. 65APPCh. 7 - Calculate the mass, in grams, of Cu in each of the...Ch. 7 - Prob. 67APPCh. 7 - Calculate the mass percent composition for each of...Ch. 7 - Prob. 69APPCh. 7 - Prob. 70APPCh. 7 - A mixture contains 0.250 mol of Mn2O3 and 20.0 g...Ch. 7 - A mixture contains 4.001023 molecules of PCl3 and...Ch. 7 - Prob. 73APPCh. 7 - Prob. 74APPCh. 7 - Prob. 75APPCh. 7 - Prob. 76APPCh. 7 - Prob. 77APPCh. 7 - Prob. 78APPCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - Aspirin, C9H8O4 , is used to reduce inflammation...Ch. 7 - Ammonium sulfate, (NH4)2SO4 , is used in...Ch. 7 - Prob. 83APPCh. 7 - Prob. 84APPCh. 7 - Oleic acid, a component of olive oil, is 76.54% C,...Ch. 7 - Prob. 86APPCh. 7 - Prob. 87CPCh. 7 - Prob. 88CPCh. 7 - Prob. 89CPCh. 7 - The following problems are related to the topics...Ch. 7 - For parts a to f, consider the loss of electrons...Ch. 7 - A sterling silver bracelet, which is 92.5% silver...Ch. 7 - Prob. 9CICh. 7 - The active ingredient in an antacid tablet is...Ch. 7 - Oseltamivir, C16H28N2O4 , is a drug that is used...Ch. 7 - Prob. 12CI
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