a) CH 3 CH=CH 2 Interpretation: Can CH 3 CH=CH 2 exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry. Concept introduction: The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers. To change: Whether CH 3 CH=CH 2 can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Question

None

Answer 1

Question

Chapter 7.4, Problem 9P

Interpretation Introduction

a) CH₃CH=CH₂

Interpretation:

Can CH₃CH=CH₂ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether CH₃CH=CH₂ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

b) (CH₃)₂C=CHCH₃

Interpretation:

Can (CH₃)₂C=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether (CH₃)₂C=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

c) CH₃CH₂CH=CHCH₃

Interpretation:

Can CH₃CH₂CH=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether CH₃CH₂CH=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

d) (CH₃)₂C=C(CH₃)CH₂CH₃

Interpretation:

Can (CH₃)₂C=C(CH₃)CH₂CH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether (CH₃)₂C=C(CH₃)CH₂CH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

e) ClCH=CHCl

Interpretation:

Can ClCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether ClCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

f) BrCH=CHCl

Interpretation:

Can BrCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether BrCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 7.4, Problem 9P

Interpretation Introduction

a) CH₃CH=CH₂

Interpretation:

Can CH₃CH=CH₂ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether CH₃CH=CH₂ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

b) (CH₃)₂C=CHCH₃

Interpretation:

Can (CH₃)₂C=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether (CH₃)₂C=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

c) CH₃CH₂CH=CHCH₃

Interpretation:

Can CH₃CH₂CH=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether CH₃CH₂CH=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

d) (CH₃)₂C=C(CH₃)CH₂CH₃

Interpretation:

Can (CH₃)₂C=C(CH₃)CH₂CH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether (CH₃)₂C=C(CH₃)CH₂CH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

e) ClCH=CHCl

Interpretation:

Can ClCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether ClCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

f) BrCH=CHCl

Interpretation:

Can BrCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether BrCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

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Answer 3

Question

Chapter 7.4, Problem 9P

Interpretation Introduction

a) CH₃CH=CH₂

Interpretation:

Can CH₃CH=CH₂ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether CH₃CH=CH₂ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

b) (CH₃)₂C=CHCH₃

Interpretation:

Can (CH₃)₂C=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether (CH₃)₂C=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

c) CH₃CH₂CH=CHCH₃

Interpretation:

Can CH₃CH₂CH=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether CH₃CH₂CH=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

d) (CH₃)₂C=C(CH₃)CH₂CH₃

Interpretation:

Can (CH₃)₂C=C(CH₃)CH₂CH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether (CH₃)₂C=C(CH₃)CH₂CH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

e) ClCH=CHCl

Interpretation:

Can ClCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether ClCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

f) BrCH=CHCl

Interpretation:

Can BrCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether BrCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Expert Solution & Answer

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Answer 4

Question

Chapter 7.4, Problem 9P

Interpretation Introduction

a) CH₃CH=CH₂

Interpretation:

Can CH₃CH=CH₂ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether CH₃CH=CH₂ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

b) (CH₃)₂C=CHCH₃

Interpretation:

Can (CH₃)₂C=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether (CH₃)₂C=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

c) CH₃CH₂CH=CHCH₃

Interpretation:

Can CH₃CH₂CH=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether CH₃CH₂CH=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

d) (CH₃)₂C=C(CH₃)CH₂CH₃

Interpretation:

Can (CH₃)₂C=C(CH₃)CH₂CH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether (CH₃)₂C=C(CH₃)CH₂CH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

e) ClCH=CHCl

Interpretation:

Can ClCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether ClCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

f) BrCH=CHCl

Interpretation:

Can BrCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether BrCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

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Answer 5

Chapter 7.4, Problem 9P

Interpretation Introduction

a) CH₃CH=CH₂

Interpretation:

Can CH₃CH=CH₂ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether CH₃CH=CH₂ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

b) (CH₃)₂C=CHCH₃

Interpretation:

Can (CH₃)₂C=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether (CH₃)₂C=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

c) CH₃CH₂CH=CHCH₃

Interpretation:

Can CH₃CH₂CH=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether CH₃CH₂CH=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

d) (CH₃)₂C=C(CH₃)CH₂CH₃

Interpretation:

Can (CH₃)₂C=C(CH₃)CH₂CH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether (CH₃)₂C=C(CH₃)CH₂CH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

e) ClCH=CHCl

Interpretation:

Can ClCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether ClCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Interpretation Introduction

f) BrCH=CHCl

Interpretation:

Can BrCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether BrCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 6

Chapter 7.4, Problem 9P

Interpretation Introduction

a) CH₃CH=CH₂

Interpretation:

Can CH₃CH=CH₂ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether CH₃CH=CH₂ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 7

Chapter 7.4, Problem 9P

Interpretation Introduction

a) CH₃CH=CH₂

Interpretation:

Can CH₃CH=CH₂ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether CH₃CH=CH₂ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 8

Interpretation Introduction

b) (CH₃)₂C=CHCH₃

Interpretation:

Can (CH₃)₂C=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether (CH₃)₂C=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 9

Interpretation Introduction

b) (CH₃)₂C=CHCH₃

Interpretation:

Can (CH₃)₂C=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To change:

Whether (CH₃)₂C=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 10

Interpretation Introduction

c) CH₃CH₂CH=CHCH₃

Interpretation:

Can CH₃CH₂CH=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether CH₃CH₂CH=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 11

Interpretation Introduction

c) CH₃CH₂CH=CHCH₃

Interpretation:

Can CH₃CH₂CH=CHCH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether CH₃CH₂CH=CHCH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 12

Interpretation Introduction

d) (CH₃)₂C=C(CH₃)CH₂CH₃

Interpretation:

Can (CH₃)₂C=C(CH₃)CH₂CH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether (CH₃)₂C=C(CH₃)CH₂CH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 13

Interpretation Introduction

d) (CH₃)₂C=C(CH₃)CH₂CH₃

Interpretation:

Can (CH₃)₂C=C(CH₃)CH₂CH₃ exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether (CH₃)₂C=C(CH₃)CH₂CH₃ can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 14

Interpretation Introduction

e) ClCH=CHCl

Interpretation:

Can ClCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether ClCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 15

Interpretation Introduction

e) ClCH=CHCl

Interpretation:

Can ClCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether ClCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 16

Interpretation Introduction

f) BrCH=CHCl

Interpretation:

Can BrCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether BrCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

Answer 17

Interpretation Introduction

f) BrCH=CHCl

Interpretation:

Can BrCH=CHCl exist as pairs of cis-trans isomer is to be stated. If so, the structures of cis-trans pair are to be drawn indicating their geometry.

Concept introduction:

The lack of rotation around carbon-carbon double bonds leads to cis-trans isomerism. The requirement is that both the carbons in double bond should be bonded to different substituents. Compounds that have one of their doubly bonded carbons bonded to identical substituents cannot exist as cis-trans isomers.

To state:

Whether BrCH=CHCl can exist as a pair of cis-trans isomers and to draw their structures with the geometry.

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Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

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