Study Guide And Selected Solutions Manual For Chemistry Format: Paperback
13th Edition
ISBN: 9780134553986
Author: Timberlake, Karen C
Publisher: Prentice Hall
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Textbook Question
Chapter 7.2, Problem 7.16PP
Calculate the molar mass for each of the following:
a.
b.
c.
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 7 Solutions
Study Guide And Selected Solutions Manual For Chemistry Format: Paperback
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 200...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Quinine, C20H24N2O2 , is a component of tonic...Ch. 7.1 - Aluminum sulphate, Al2SO43 , is used in some...Ch. 7.1 - Naproxen, found in Aleve, is used to treat the...Ch. 7.1 - Benadryl is an over-the-counter drug used to treat...
Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, in 0.150 mole of...Ch. 7.3 - Calculate the mass, in grams, in 2.28 moles of...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in 25.0 g of each of...Ch. 7.3 - Calculate the number of moles in 4.00 g of each of...Ch. 7.3 - Chloroethane, C2H5Cl , is used to diagnose dead...Ch. 7.3 - Allyl sulfide, C3H52S , gives garlic, onions, and...Ch. 7.3 - a. The compound MgSO4 , Epsom salts, is used to...Ch. 7.3 - a. Cyclopropane, C3H6 , is an anesthetic given by...Ch. 7.3 - Dinitrogen oxide (or nitrous oxide), N2O , also...Ch. 7.3 - Chloroform, CHCl3 , was formerly used as an...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.5 - Prob. 7.41PPCh. 7.5 - Prob. 7.42PPCh. 7.5 - Prob. 7.43PPCh. 7.5 - Prob. 7.44PPCh. 7.6 - Prob. 7.45PPCh. 7.6 - Prob. 7.46PPCh. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - Prob. 7.49PPCh. 7.6 - Prob. 7.50PPCh. 7.6 - Prob. 7.51PPCh. 7.6 - Prob. 7.52PPCh. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - The chemical reaction of hydrogen with oxygen...Ch. 7.7 - Ammonia is produced by the chemical reaction of...Ch. 7.7 - Carbon disulfide and carbon monoxide are produced...Ch. 7.7 - In the acetylene torch, acetylene gas C2H2 burns...Ch. 7.8 - Sodium reacts with oxygen to produce sodium oxide....Ch. 7.8 - Nitrogen gas reacts with hydrogen gas to produce...Ch. 7.8 - Ammonia and oxygen react to form nitrogen and...Ch. 7.8 - Iron(III) oxide reacts with carbon to give iron...Ch. 7.8 - Nitrogen dioxide and water react to produce nitric...Ch. 7.8 - Calcium cyanamide, CaCN2 , reads with water to...Ch. 7.8 - When solid lead(II) sulfide reacts with oxygen...Ch. 7.8 - When the gases dihydrogen sulfide and oxygen...Ch. 7.9 - Prob. 7.67PPCh. 7.9 - a. What is measured by the heat of reaction? b. In...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - a. What is meant by the rate of a reaction? b. Why...Ch. 7.9 - a. How does a catalyst affect the activation...Ch. 7.9 - Prob. 7.75PPCh. 7.9 - How would each of the following change the rate of...Ch. 7.9 - a. During cellular respiration, aqueous C6H12O6...Ch. 7.9 - Fatty acids undergo reaction with oxygen gas and...Ch. 7 - Prob. 7.79UTCCh. 7 - Using the models of the molecules (black = C,...Ch. 7 - A dandruff shampoo contains dipyrithione,...Ch. 7 - Ibuprofen, an anti-inflammatory drug in Advil, has...Ch. 7 - Prob. 7.83UTCCh. 7 - Balance each of the following by adding...Ch. 7 - Prob. 7.85UTCCh. 7 - Prob. 7.86UTCCh. 7 - If blue spheres represent nitrogen atoms, purple...Ch. 7 - Prob. 7.88UTCCh. 7 - Prob. 7.89UTCCh. 7 - Prob. 7.90UTCCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - How many grams are in 0.150 mole of each of the...Ch. 7 - How many grams are in 2.25 moles of each of the...Ch. 7 - How many moles are in 25.0 g of each of the...Ch. 7 - How many moles are in 4.00 g of each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Prob. 7.99APPCh. 7 - Prob. 7.100APPCh. 7 - Identify each of the following as an oxidation or...Ch. 7 - Identify each of the following as an oxidation or...Ch. 7 - When ammonia NH3 gas reacts with fluorine gas, the...Ch. 7 - When nitrogen dioxide NO2 gas from car exhaust...Ch. 7 - Pentane gas, C5H12 undergoes combustion with...Ch. 7 - Prob. 7.106APPCh. 7 - Prob. 7.107APPCh. 7 - The equation for the formation of nitrogen oxide...Ch. 7 - Prob. 7.109CPCh. 7 - Prob. 7.110CPCh. 7 - Prob. 7.111CPCh. 7 - A toothpaste contains 0.240% by mass sodium...Ch. 7 - Prob. 7.113CPCh. 7 - Prob. 7.114CPCh. 7 - Prob. 7.115CPCh. 7 - Prob. 7.116CP
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