CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 7.2, Problem 2P
Give the IUPAC name for each compound.
a. 
b. 
c. 
d. 
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potential energy
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b) Translate the Newman projection below to its wedge-and-dash drawing.
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c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw
a Newman projection of six conformations about the C2-C3 bond of isopentane. On the
curve of potential energy versus angle of internal rotation for isopentane, label each
energy maximum and minimum with one of the conformations.
0°
。
F
A
B
D
C
angle of internal rotation
E
F
360° (=0°)
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Q7: Identify the functional groups in these molecules
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CH 3
b) Aspirin:
HO
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HO
O
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CH 3
Q2: Name the following alkanes
Chapter 7 Solutions
CNCT ORG CHEM 6 2020
Ch. 7.1 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7.2 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7.2 - Prob. 3PCh. 7.3 - An sp3 hybridized CCl bond is more polar than an...Ch. 7.4 - Prob. 5PCh. 7.6 - Prob. 6PCh. 7.7 - Prob. 10PCh. 7.8 - Prob. 15PCh. 7.8 - Prob. 16PCh. 7.8 - Prob. 17P
Ch. 7.11 - Prob. 18PCh. 7.11 - Prob. 19PCh. 7.11 - Draw the product of each SN2 reaction and indicate...Ch. 7.11 - Prob. 21PCh. 7.11 - Prob. 22PCh. 7.12 - What happens to the rate of an SN1 reaction under...Ch. 7.12 - Draw the products of each SN1 reaction and...Ch. 7.13 - Classify each carbocation as 1,2, or 3. a. b. c....Ch. 7.15 - Problem 7.30 For each alkyl halide and...Ch. 7.15 - Prob. 30PCh. 7.15 - Prob. 31PCh. 7.15 - Prob. 32PCh. 7.15 - Prob. 33PCh. 7.15 - Prob. 34PCh. 7 - Give the IUPAC name for each compound, including...Ch. 7 - Draw the products of each nucleophilic...Ch. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - 7.53 Consider the following reaction.
Draw a...Ch. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Consider the following SN1 reaction. a.Draw a...Ch. 7 - 7.59 Pick the reactant or solvent in each part...Ch. 7 - Draw the products of each SN1 reaction and...Ch. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Draw a stepwise, detailed mechanism for the...Ch. 7 - When a single compound contains both a nucleophile...Ch. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Draw a stepwise, detailed mechanism f or the...Ch. 7 - Prob. 72PCh. 7 - Prob. 78P
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- 1. Complete the following table in your laboratory notebook. Substance Formula Methanol CH3OH Ethanol C2H5OH 1-Propanol C3H7OH 1-Butanol C4H9OH Pentane C5H12 Hexane C6H14 Water H₂O Acetone C3H60 Structural Formula Molecular Weight (g/mol) Hydrogen Bond (Yes or No)arrow_forwardQ1: Compare the relative acidity in each pair of compounds. Briefly explain. (a) CH3OH vs NH 3 (b) HF vs CH3COOH (c) NH3 vs CH4 (d) HCI vs HI (e) CH3COOH vs CH3SH (f) H₂C=CH2 vs CH3 CH3 (g) compare the acidity of the two bolded hydrogens O. H N- (h) compare the acidity of the two bolded hydrogens, draw resonance structures to explain H H Harrow_forwardQ3: Rank the following molecules in order of decreasing boiling point: (a) 3-methylheptane; (b) octane; (c) 2,4-dimethylhexane; (d) 2,2,4-trimethylpentane.arrow_forward
- Q5: Conformations of Alkanes a) Draw a Newman Projection of the compound below about the C2-C3 bond. H3C Cli... H IIIH Br CH3arrow_forwardThe ability of atoms to associate with each other depends ona) the electronic structure and its spatial orientation.b) the electron affinity.c) The other two answers are correct.arrow_forwardWhat is the final volume after you reach the final temperature? I put 1.73 but the answer is wrong not sure why The initial volume of gas is 1.60 LL , the initial temperature of the gas is 23.0 °C°C , and the system is in equilibrium with an external pressure of 1.2 bar (given by the sum of a 1 bar atmospheric pressure and a 0.2 bar pressure due to a brick that rests on top of the piston). Then, as you did in Exercise 1, you heat the gas slowly until the temperature reaches 48.2 °Carrow_forward
- Q4: Identify the type of Carbon ( methyl, primary, secondary, etc. ) indicated by this arrow.arrow_forwardQ3: Curved Arrows, Lewis Acids & Bases, Nucleophiles and Electrophiles Considering the following reactions: a) Predict the products to complete the reactions. b) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw some of the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. c) Label Lewis acids and bases, nucleophiles and electrophiles in the reactions. A. S + AICI 3 B. + H₂Oarrow_forward3. A thermometer is placed in a test tube of chipped ice at -5.0 °C. The temperature is recorded at the time intervals shown below until room temperature is reached. Plot the data given below on graph paper and explain all flat, horizontal portions of the curve. Plot time on the X-axis! Time (min) Temperature (°C) 0 -5.0 2 -2.5 4 -1.0 6 0.0 10 0.0 15 0.0 20 0.0 25 0.0 30 1.5 35 4.0 40 8.0 45 11.5 50 15.0 55 17.5 60 19.0 65 20.0 70 20.0 75 20.0 80 20.0arrow_forward
- Naming the Alkanes a) Write the IUPAC nomenclature of the compound below b) Draw 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and quaternary carbons. c) Rank pentane, neopentane and isopentane for boiling point. pentane: H3C-CH2-CH2-CH2-CH3 neopentane: CH3 H3C-Ċ-CH3 I CH3 isopentane: CH3 H3C-CH2-CH-CH3arrow_forwardWhich will evaporate faster, 1-Butanol or Pentane? Explain your choice.arrow_forwardUsing the equation below, what is the rate of this reaction if the rate of disappearance of H2 is 0.44 M/sec? H2 + Br2 → 2HBrarrow_forward
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Nomenclature: Crash Course Chemistry #44; Author: CrashCourse;https://www.youtube.com/watch?v=U7wavimfNFE;License: Standard YouTube License, CC-BY