Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
3rd Edition
ISBN: 9781119340577
Author: Klein
Publisher: Wiley (WileyPLUS Products)
Question
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Chapter 7.12, Problem 41CC

(a)

Interpretation Introduction

Interpretation:

Major and minor products should be drawn for the given reactions.

Concept Introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(b)

Interpretation Introduction

Interpretation:

Major and minor products should be drawn for the given reactions

Concept Introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(c)

Interpretation Introduction

Interpretation:

Major and minor products should be drawn for the given reactions

Concept Introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(d)

Interpretation Introduction

Interpretation:

Major and minor products should be drawn for the given reactions

Concept Introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(e)

Interpretation Introduction

Interpretation:

Major and minor products should be drawn for the given reactions.

Concept Introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(f)

Interpretation Introduction

Interpretation:

Major and minor products should be drawn for the given reactions

Concept Introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

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Chapter 7 Solutions

Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion

Ch. 7.4 - Prob. 9CCCh. 7.5 - Prob. 10CCCh. 7.6 - Prob. 11CCCh. 7.7 - Provide a systematic name for each of the...Ch. 7.7 - Prob. 13CCCh. 7.7 - Prob. 14CCCh. 7.7 - Prob. 15CCCh. 7.7 - Prob. 16CCCh. 7.7 - Prob. 17CCCh. 7.8 - Prob. 3LTSCh. 7.8 - Predict the major and minor products for each of...Ch. 7.8 - Prob. 19PTSCh. 7.8 - Prob. 20ATSCh. 7.8 - Prob. 4LTSCh. 7.8 - Prob. 21PTSCh. 7.8 - Prob. 23CCCh. 7.8 - Prob. 24CCCh. 7.8 - Prob. 5LTSCh. 7.8 - Prob. 25PTSCh. 7.8 - Prob. 26ATSCh. 7.9 - Prob. 6LTSCh. 7.9 - Prob. 27PTSCh. 7.9 - Prob. 28ATSCh. 7.9 - Prob. 29CCCh. 7.9 - Prob. 30CCCh. 7.9 - Prob. 31CCCh. 7.9 - Prob. 32CCCh. 7.9 - Draw all of the expected products for each of the...Ch. 7.10 - Prob. 35CCCh. 7.10 - Prob. 36CCCh. 7.11 - Prob. 7LTSCh. 7.11 - Prob. 37PTSCh. 7.11 - Prob. 38ATSCh. 7.11 - Prob. 39ATSCh. 7.11 - Prob. 40ATSCh. 7.12 - Prob. 41CCCh. 7.12 - Prob. 42CCCh. 7.12 - Prob. 43CCCh. 7.13 - Prob. 8LTSCh. 7.13 - Prob. 44PTSCh. 7.13 - Prob. 45PTSCh. 7.13 - Prob. 46ATSCh. 7 - Prob. 47PPCh. 7 - Prob. 48PPCh. 7 - Prob. 49PPCh. 7 - Prob. 50PPCh. 7 - Prob. 51PPCh. 7 - Prob. 52PPCh. 7 - Prob. 53PPCh. 7 - Prob. 54PPCh. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - Prob. 58PPCh. 7 - Prob. 59PPCh. 7 - Prob. 60PPCh. 7 - Prob. 61PPCh. 7 - Prob. 62PPCh. 7 - Prob. 63PPCh. 7 - Prob. 64PPCh. 7 - Prob. 65PPCh. 7 - Prob. 66PPCh. 7 - Prob. 67PPCh. 7 - Prob. 68PPCh. 7 - Prob. 69PPCh. 7 - Prob. 70PPCh. 7 - Prob. 71PPCh. 7 - Prob. 72PPCh. 7 - Predict which of the following substrates will...Ch. 7 - Prob. 74PPCh. 7 - Prob. 75PPCh. 7 - Prob. 76PPCh. 7 - Prob. 77PPCh. 7 - Prob. 78PPCh. 7 - Prob. 79PPCh. 7 - Prob. 80IPCh. 7 - Prob. 81IPCh. 7 - Prob. 82IPCh. 7 - Prob. 83IPCh. 7 - Prob. 84IPCh. 7 - Prob. 85IPCh. 7 - Prob. 87IPCh. 7 - Prob. 88IPCh. 7 - Prob. 89IPCh. 7 - Prob. 90IPCh. 7 - Prob. 91IPCh. 7 - Prob. 92IPCh. 7 - Prob. 94IPCh. 7 - Prob. 95IPCh. 7 - Prob. 96IPCh. 7 - Prob. 97IPCh. 7 - Prob. 98IPCh. 7 - For the following substitution reaction, which...Ch. 7 - Prob. 100IPCh. 7 - Prob. 101IPCh. 7 - Prob. 102CPCh. 7 - Prob. 104CPCh. 7 - Prob. 105CPCh. 7 - When 2-iodobutane is treated with a variety of...
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