LL ORG CHEM
LL ORG CHEM
6th Edition
ISBN: 9781264840083
Author: SMITH
Publisher: MCG
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Chapter 7.12, Problem 23P

What happens to the rate of an S N 1 reaction under each of the following conditions?

a. [ RX ] is tripled, and [ Nu ] stays the same.

b. Both [ RX ] and [ Nu ] are tripled.

c. [ RX ] is halved, and [ Nu ] stays the same.

d. [ RX ] is halved, and [ Nu ] is doubled.

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Two cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 C
With the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.

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LL ORG CHEM

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