Solutions Manual For Chemistry: Structure And Properties
2nd Edition
ISBN: 9780134460697
Author: Tro
Publisher: PEARSON
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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in
your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on
the LC-MS printout. How much different are they?
2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit,
explain what each of these is and why they are present.
3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by
calculating the accurate monoisotopic mass.
4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum
of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source.
5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one
point of extra credit, see if you can identify this molecule as well and confirm by…
Please draw, not just describe!
can you draw each step on a piece of a paper please this is very confusing to me
Chapter 7 Solutions
Solutions Manual For Chemistry: Structure And Properties
Ch. 7 - Prob. 1ECh. 7 - Prob. 2ECh. 7 - What is the difference between a physical change...Ch. 7 - What is the difference between a physical property...Ch. 7 - What is a balanced chemical equation?Ch. 7 - Why must chemical equations be balanced?Ch. 7 - What is reaction stoichiometry? What is the...Ch. 7 - In a chemical reaction, what is the limiting...Ch. 7 - In a chemical reaction, what is the theoretical...Ch. 7 - We typically calculate the percent yield using the...
Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Write a general equation for the reaction of an...Ch. 7 - Prob. 14ECh. 7 - Classify each change as physical or chemical....Ch. 7 - Prob. 16ECh. 7 - Prob. 17ECh. 7 - Prob. 18ECh. 7 - Classify each of the listed properties of...Ch. 7 - Prob. 20ECh. 7 - Classify each property as physical or chemical the...Ch. 7 - Prob. 22ECh. 7 - Sulfuric acid (H2SO4) is a component of acid rain...Ch. 7 - Nitric acid (HNO3) is a component of acid rain...Ch. 7 - Prob. 25ECh. 7 - Prob. 26ECh. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced equation for the photosynthesis...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Balance each chemical equation. CO2(g) + CaSiO3(s)...Ch. 7 - Balance each chemical equation. Na2S(aq) +...Ch. 7 - Prob. 35ECh. 7 - Consider the unbalanced equation for the...Ch. 7 - Calculate how many moles of NO2 form when each...Ch. 7 - Calculate how many moles of NH3 form when each...Ch. 7 - Consider the balanced equation: SiO2(s) + 3 C(s)...Ch. 7 - Consider the balanced equation: 2 N2H4(s) +...Ch. 7 - Hydrobromic acid (HBr) dissolves solid iron...Ch. 7 - Sulfuric acid (H2SO4) dissolves aluminum metal...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For the following reaction, determine the limiting...Ch. 7 - Find the limiting reactant for each initial amount...Ch. 7 - Consider the reaction: HCl(g) + O2(g) 2 H2O(g) +...Ch. 7 - Consider the reaction: 2 CH 3 OH(g)+3 O 2 (g)2 CO...Ch. 7 - Calculate the theoretical yield of the product (in...Ch. 7 - Calculate the theoretical yield of product (in...Ch. 7 - Zinc sulfide reacts with oxygen according to the...Ch. 7 - Iron(ll) sulfide reacts with hydrochloric acid...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - Iron(lll) oxide reacts with carbon monoxide...Ch. 7 - Elemental phosphorus reacts with chlorine gas...Ch. 7 - Lead(ll) ions can be removed from solution with...Ch. 7 - Prob. 58ECh. 7 - Urea (CH4N2O) is a common fertilizer that is...Ch. 7 - Prob. 60ECh. 7 - Prob. 61ECh. 7 - Complete and balance each combustion reaction...Ch. 7 - Prob. 63ECh. 7 - Prob. 64ECh. 7 - Prob. 65ECh. 7 - Prob. 66ECh. 7 - Prob. 67ECh. 7 - Prob. 68ECh. 7 - Prob. 69ECh. 7 - Prob. 70ECh. 7 - Aspirin can be made in the laboratory by reacting...Ch. 7 - The combustion of liquid ethanol (C2H5OH) produces...Ch. 7 - Prob. 73ECh. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - An important reaction that takes place in a blast...Ch. 7 - A liquid fuel mixture contains 30.35% hexane...Ch. 7 - Titanium occurs in the magnetic mineral ilmenite...Ch. 7 - A mixture of C3H8 and C2H2 has a mass of 2.0 g. It...Ch. 7 - Prob. 80ECh. 7 - Lead poisoning is a serious condition resulting...Ch. 7 - Prob. 82ECh. 7 - Metallic aluminum reacts with MnO2 at elevated...Ch. 7 - Prob. 84ECh. 7 - Consider the reaction: 4K(s)+O2(g)2K2O(s) The...Ch. 7 - Prob. 86ECh. 7 - Consider the reaction:...Ch. 7 - Prob. 88ECh. 7 - Prob. 89ECh. 7 - Prob. 90ECh. 7 - What are the correct coefficients (reading from...Ch. 7 - Prob. 2SAQCh. 7 - Prob. 3SAQCh. 7 - For the reaction shown here, 3.5 mol A is mixed...Ch. 7 - Manganese(IV) oxide reacts with aluminum to form...Ch. 7 - Sodium and chlorine react to form sodium chloride....Ch. 7 - Sulfur and fluorine react to form sulfur...Ch. 7 - A reaction has a theoretical yield of 45.8 g. When...Ch. 7 - Prob. 9SAQCh. 7 - Solid potassium chlorate (KCIO3) decomposes into...
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- > Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? esc ? A O O •If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. • If your answer is no, check the box under the drawing area instead. olo 18 Ar Explanation Check BB Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accessibilityarrow_forwardName the structurearrow_forward> For each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that: 1. the rate of substitution doesn't depend on nucleophile concentration and 2. the products are a roughly 50/50 mixture of enantiomers. Substrate A Substrate B Faster Rate X CI (Choose one) (Choose one) CI Br Explanation Check Br (Choose one) C 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy A F10arrow_forward
- How to draw this mechanism for the foloowing reaction in the foto. thank youarrow_forwardPredict the major products of the following organic reaction: Some important notes: CN A? • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. No reaction. Explanation Check Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Centerarrow_forwardDraw the major product of the following reaction. Do not draw inorganic byproducts. H3PO4 OHarrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) Δ ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. Explanation Check X ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacyarrow_forwardFor the structure below, draw the resonance structure that is indicated by the curved arrow(s). Be sure to include formal charges. :ÖH Modify the second structure given to draw the new resonance structure. Include lone pairs and charges in your structure. Use the + and - tools to add/remove charges to an atom, and use the single bond tool to add/remove double bonds.arrow_forwardUsing the table of Reactants and Products provided in the Hints section, provide the major product (with the correct stereochemistry when applicable) for questions below by selecting the letter that corresponds to the exact chemical structures for the possible product. OH conc Hydrochloric acid 40°C Temp A/arrow_forward
- Using arrows to designate the flow of electrons, complete the reaction below and provide a detailed mechanism for the formation of the product OH conc Hydrochloric acid 40°C Temp All chemical structures should be hand drawn on a piece of paper Paragraph BI UAE +varrow_forwarddraw out the following structures plesearrow_forwardDraw everything on a piece of paper outlining the synthesis from acetaldehyde to 2 cyclopentene carboxaldehyde using carbon based reagants with 3 carbons or fewers. Here is the attached image.arrow_forward
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