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Recent advancements in liquid chromatography include the development of ultrahigh pressure liquid chromatography (UHPLC) and an increased use of capillary columns that had previously only been used with gas chromatography. Both of these advances have made the development of portable LC systems possible. For example, Axcend Corp. makes a portable system that uses a capillary column with an internal diameter of 150-μm-that is packed with 1.7-um stationary phase particles. In contrast, a traditional LC column has a 4.6 mm internal diameter and utilizes 5-um stationary phase particles. a) Explain one advantage that is afforded by the use of a capillary column in liquid chromatographic separation. Explain one disadvantage of capillary columns. b) Explain how the use of smaller stationary phase particles can improve the resolution of a separation. Include any relevant equations that support your explanation. c) A scientist at Rowan University is using the Axcend LC to conduct analyses of F…
This paper describes the use of fullerene molecules, also known as buckyballs, as a stationary phase for liquid chromatography. The performance of the fullerene-modified stationary phase (FMS) is compared to that of a more common C18 stationary phase and to two other carbon-based stationary phases, PGC and COZ. A. 10A OM B. - Figure 1. Idealized drawing of the cross-section of a pore inside a silica particle, showing the relative densities of aminopropylsilyl (red/green) and fullerene (blue) groups: (A) full cross- section; (B) detailed view of covalent bonding of fullerene to the silica surface. Surface densities of silyl and fullerene groups were inferred from elemental composition results obtained at each stage of the synthesis (see Table 1). Absorbance (mAU, 220 nm) 700 600 500 400 300 200 100 a. Define selectivity, a, with words and an equation. b. Explain how the choice of stationary phase affects selectivity. c. Calculate the resolution of the nitrobenzene and toluene peaks in…
Normalized Intensity (a. u.) 0.5 1.0 A 3D-printed GC column (shown below) was created for use with "micro" gas chromatography applications. To prove its utility, it was used to separate a mixture of alkanes (C9-C18, C22, C24). For the separation shown below, the column temperature was ramped from 40 °C to 250 °C at a rate of 30 °C per minute. (a) 9 10 = 1 mm 12 13 15 22 0.0 0 100 200 300 400 Time (sec) a) What detector would you use for this analysis? Justify your selection. b) Explain how the chromatogram would change if the separation was run isothermally. c) Explain how the chromatogram would change if the temperature ramp were increased to 50 °C per minute.

Chapter 7 Solutions

Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)

Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Write a general equation for the reaction of an...Ch. 7 - Prob. 14ECh. 7 - Classify each change as physical or chemical....Ch. 7 - Prob. 16ECh. 7 - Prob. 17ECh. 7 - Prob. 18ECh. 7 - Classify each of the listed properties of...Ch. 7 - Prob. 20ECh. 7 - Classify each property as physical or chemical the...Ch. 7 - Prob. 22ECh. 7 - Sulfuric acid (H2SO4) is a component of acid rain...Ch. 7 - Nitric acid (HNO3) is a component of acid rain...Ch. 7 - Prob. 25ECh. 7 - Prob. 26ECh. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced equation for the photosynthesis...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Balance each chemical equation. CO2(g) + CaSiO3(s)...Ch. 7 - Balance each chemical equation. Na2S(aq) +...Ch. 7 - Prob. 35ECh. 7 - Consider the unbalanced equation for the...Ch. 7 - Calculate how many moles of NO2 form when each...Ch. 7 - Calculate how many moles of NH3 form when each...Ch. 7 - Consider the balanced equation: SiO2(s) + 3 C(s)...Ch. 7 - Consider the balanced equation: 2 N2H4(s) +...Ch. 7 - Hydrobromic acid (HBr) dissolves solid iron...Ch. 7 - Sulfuric acid (H2SO4) dissolves aluminum metal...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For the following reaction, determine the limiting...Ch. 7 - Find the limiting reactant for each initial amount...Ch. 7 - Consider the reaction: HCl(g) + O2(g) 2 H2O(g) +...Ch. 7 - Consider the reaction: 2 CH 3 OH(g)+3 O 2 (g)2 CO...Ch. 7 - Calculate the theoretical yield of the product (in...Ch. 7 - Calculate the theoretical yield of product (in...Ch. 7 - Zinc sulfide reacts with oxygen according to the...Ch. 7 - Iron(ll) sulfide reacts with hydrochloric acid...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - Iron(lll) oxide reacts with carbon monoxide...Ch. 7 - Elemental phosphorus reacts with chlorine gas...Ch. 7 - Lead(ll) ions can be removed from solution with...Ch. 7 - Prob. 58ECh. 7 - Urea (CH4N2O) is a common fertilizer that is...Ch. 7 - Prob. 60ECh. 7 - Prob. 61ECh. 7 - Complete and balance each combustion reaction...Ch. 7 - Prob. 63ECh. 7 - Prob. 64ECh. 7 - Prob. 65ECh. 7 - Prob. 66ECh. 7 - Prob. 67ECh. 7 - Prob. 68ECh. 7 - Prob. 69ECh. 7 - Prob. 70ECh. 7 - Aspirin can be made in the laboratory by reacting...Ch. 7 - The combustion of liquid ethanol (C2H5OH) produces...Ch. 7 - Prob. 73ECh. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - An important reaction that takes place in a blast...Ch. 7 - A liquid fuel mixture contains 30.35% hexane...Ch. 7 - Titanium occurs in the magnetic mineral ilmenite...Ch. 7 - A mixture of C3H8 and C2H2 has a mass of 2.0 g. It...Ch. 7 - Prob. 80ECh. 7 - Lead poisoning is a serious condition resulting...Ch. 7 - Prob. 82ECh. 7 - Metallic aluminum reacts with MnO2 at elevated...Ch. 7 - Prob. 84ECh. 7 - Consider the reaction: 4K(s)+O2(g)2K2O(s) The...Ch. 7 - Prob. 86ECh. 7 - Consider the reaction:...Ch. 7 - Prob. 88ECh. 7 - Prob. 89ECh. 7 - Prob. 90ECh. 7 - What are the correct coefficients (reading from...Ch. 7 - Prob. 2SAQCh. 7 - Prob. 3SAQCh. 7 - For the reaction shown here, 3.5 mol A is mixed...Ch. 7 - Manganese(IV) oxide reacts with aluminum to form...Ch. 7 - Sodium and chlorine react to form sodium chloride....Ch. 7 - Sulfur and fluorine react to form sulfur...Ch. 7 - A reaction has a theoretical yield of 45.8 g. When...Ch. 7 - Prob. 9SAQCh. 7 - Solid potassium chlorate (KCIO3) decomposes into...
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