CHEMISTRY+CHEM...(LL)-W/ACCESS >CUSTOM<
10th Edition
ISBN: 9780357096949
Author: Kotz
Publisher: CENGAGE C
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Textbook Question
Chapter 7, Problem 7PS
Use noble gas and spdf notations to depict electron configurations for the following metals of the third transition series.
(a) Tantalum, Ta. The metal and its alloys resist corrosion and are often used in surgical and dental tools.
(b) Platinum, Pt. This metal was used by pre-Columbian Indians in jewelry. Now it is still used in jewelry but it is also the basis for anti-cancer drugs and catalysts (such as those in automobile exhaust systems).
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
:☐
G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
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Explanation
Check
Click and drag to start drawing a
structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers.
OH
OH
OH
OH
OH
OH
Chapter 7 Solutions
CHEMISTRY+CHEM...(LL)-W/ACCESS >CUSTOM<
Ch. 7.3 - (a) What element has the configuration...Ch. 7.3 - Write one possible set of quantum numbers for the...Ch. 7.3 - Using the periodic table and without looking at...Ch. 7.4 - Prob. 7.4CYUCh. 7.5 - Without looking at the figures for the periodic...Ch. 7.6 - The most common oxidation state of a rare earth...Ch. 7.6 - Prob. 1.2ACPCh. 7.6 - Prob. 1.3ACPCh. 7.6 - Use the atomic radii of scandium, yttrium,...Ch. 7.6 - Prob. 1.5ACP
Ch. 7.6 - Prob. 1.6ACPCh. 7.6 - Give the electron configurations for iron and the...Ch. 7.6 - Prob. 2.2ACPCh. 7.6 - Prob. 2.3ACPCh. 7.6 - Prob. 2.4ACPCh. 7 - Write the electron configurations for P and CI...Ch. 7 - Write the electron configurations for Mg and Ar...Ch. 7 - Using spdf notation, write the electron...Ch. 7 - Using spdf notation, give the electron...Ch. 7 - Prob. 5PSCh. 7 - Prob. 6PSCh. 7 - Use noble gas and spdf notations to depict...Ch. 7 - The lanthanides, once called the rare earth...Ch. 7 - Prob. 9PSCh. 7 - Prob. 10PSCh. 7 - What is the maximum number of electrons that can...Ch. 7 - What is the maximum number of electrons that can...Ch. 7 - Depict the electron configuration for magnesium...Ch. 7 - Depict the electron configuration for phosphorus...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 17PSCh. 7 - Which of the following statements correctly...Ch. 7 - Prob. 19PSCh. 7 - Prob. 20PSCh. 7 - Using orbital box diagrams, depict an electron...Ch. 7 - Prob. 22PSCh. 7 - Prob. 23PSCh. 7 - Using orbital box diagrams and noble gas notation,...Ch. 7 - Manganese is found as MnO2 in deep ocean deposits....Ch. 7 - One compound found in alkaline batteries is NiOOH,...Ch. 7 - Prob. 27PSCh. 7 - Arrange the following elements in order of...Ch. 7 - Prob. 29PSCh. 7 - Prob. 30PSCh. 7 - Which of the following groups of elements is...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Compare the elements Na, Mg, O, and P. (a) Which...Ch. 7 - Compare the elements B. Al, C, and Si. (a) Which...Ch. 7 - Explain each answer briefly. (a) Place the...Ch. 7 - Explain each answer briefly. (a) Rank the...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Explain why the photoelectron spectra of hydrogen...Ch. 7 - Sketch the major features (number of peaks and...Ch. 7 - These questions are not designated as to type or...Ch. 7 - The deep blue color of sapphires comes from the...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 44GQCh. 7 - Prob. 45GQCh. 7 - Prob. 46GQCh. 7 - Which of the following is not an allowable set of...Ch. 7 - A possible excited state for the H atom has an...Ch. 7 - The magnet in the following photo is made from...Ch. 7 - Name the element corresponding to each...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Prob. 52GQCh. 7 - Answer the questions below about the elements A...Ch. 7 - Answer (he following questions about the elements...Ch. 7 - Which of the following ions are unlikely to be...Ch. 7 - Prob. 56GQCh. 7 - Answer each of the following questions: (a) Of the...Ch. 7 - Prob. 58GQCh. 7 - Prob. 59GQCh. 7 - Two elements in the second transition series (Y...Ch. 7 - Prob. 61GQCh. 7 - The configuration of an element is given here. (a)...Ch. 7 - Answer the questions below about the elements A...Ch. 7 - Answer the questions below concerning ground state...Ch. 7 - Nickel(II) formate [Ni(HCO2)2] is widely used as a...Ch. 7 - Spinets are solids with the general formula M2+...Ch. 7 - The following questions use concepts from this and...Ch. 7 - Which ions in the following list are not likely to...Ch. 7 - Answer the following questions about first...Ch. 7 - The ionization of the hydrogen atom can be...Ch. 7 - Compare the configurations below with two...Ch. 7 - Prob. 72SCQCh. 7 - Write electron configurations to show the first...Ch. 7 - Prob. 74SCQCh. 7 - (a) Explain why the sizes of atoms change when...Ch. 7 - Which of the following elements has the greatest...Ch. 7 - Prob. 77SCQCh. 7 - Prob. 78SCQCh. 7 - The energies of the orbitals in many elements have...Ch. 7 - The ionization energies for the removal of the...Ch. 7 - Using your knowledge of the trends in element...Ch. 7 - Prob. 82SCQCh. 7 - Prob. 83SCQCh. 7 - Prob. 84SCQCh. 7 - Thionyl chloride. SOCl2, is an important...Ch. 7 - Prob. 86SCQCh. 7 - Slaters rules are a way to estimate the effective...
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- Using wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टेarrow_forwardProvide photos of models of the following molecules. (Include a key for identification of the atoms) 1,2-dichloropropane 2,3,3-trimethylhexane 2-bromo-3-methybutanearrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
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