Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
7th Edition
ISBN: 9780198802259
Author: ATKINS
Publisher: Oxford University Press
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Chapter 7, Problem 7C.3ST
Interpretation Introduction

Interpretation:

The energy separation between the given levels of an electron trapped in a square cavity with sides of length 1nm has to be calculated.

Concept Introduction:

The wave function is considered to be normalized if the probability of finding the particle in considered domain is equal to 1 and therefore, the integral function of given wave function in considered domain is equal to 1.

The energy difference between adjacent levels in one dimensional box is determined by using the following equation.

ΔE=En+1En=(2n+1)h28mL2

The energy separation between two given levels are determined by using following expression,

EnX,nY=(n2X+n2Y)h28mL2here,L=lengthm=massh=Planck'sconstantnX&nY=Energylevels

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