
Concept explainers
(a)
Interpretation:
The commutator for
Concept introduction:
The commutators are the operators obtained from the operators which commute with each other. The commutator of the operators like position and momentum operators is given by the formula shown below.
(a)

Answer to Problem 7C.15P
The commutator for
Explanation of Solution
The commutator of the operators is given by the formula shown below.
The value of operator
Substitute the values of operators in the equation (1) for
The above is equation is simplified by substituting the value of momentum operator
The above equation on solving gives the value of zero.
Therefore, the value of
Substitute the values of operators in the equation (1) for
The above is equation is simplified by substituting the value of momentum operator
The above equation can be solved as shown below.
Therefore, the value of
(b)
Interpretation:
The commutator for
Concept introduction:
The commutators are the operator obtained from the operators which commute with each other. The commutator of the operators like position and momentum operators is given by the formula shown below.
(b)

Answer to Problem 7C.15P
The commutator for
Explanation of Solution
The commutator of the operators is given by the formula shown below.
The value of operator
Substitute the values of operators in the equation (2) for
The above is equation is simplified by substituting the value of momentum operator
Therefore, the value of
Substitute the values of operators in the equation (2) for
The above is equation is simplified by substituting the value of momentum operator
The above equation can be solved as shown below.
Therefore, the value of
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Chapter 7 Solutions
Atkins' Physical Chemistry
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