Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 7, Problem 7A.7E
Interpretation Introduction

Interpretation:

The de Broglie wavelength of oneself travelling with speed of 8 km h-1 has to be calculated and also the wavelength at speed zero has to be identified.

Concept Introduction:

Louis de Broglie in 1923 rationalized that when light shows particle aspects, then particles of matter display properties of waves under definite circumstances.

λ=hmυp = mυHence λ=hp

h is Planck’s constant(6.63×10-34J.s) which relates energy and frequency.

υ is the speed of particle.

m is the mass of particle.

λ is the wavelength.

p is the momentum.

The above equation is called de Broglie relation.

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The SN 1 mechanism starts with the rate-determining step which is the dissociation of the alkyl halide into a carbocation and a halide ion. The next step is the rapid reaction of the carbocation intermediate with the nucleophile; this step completes the nucleophilic substitution stage. The step that follows the nucleophilic substitution is a fast acid-base reaction. The nucleophile now acts as a base to remove the proton from the oxonium ion from the previous step, to give the observed product. Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all nonzero formal charges. Cl: Add/Remove step G Click and drag to start drawing a structure.
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