Chemistry, Books a la Carte Edition and Modified Mastering Chemistry with Pearson eText & ValuePack Access Card (7th Edition)
7th Edition
ISBN: 9780134172514
Author: John E. McMurry
Publisher: PEARSON
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Chapter 7, Problem 7.73CP
Identify the fourth-row elements, X, that form the following compounds:
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-Page: 8
nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]".
What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry
of [Co(H2O)]?
b)
Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron
configurations of [Co(H2O)]:
Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance
or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of
[Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1
kJ/mol)
Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange
an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low
in configuration vs in the high spin configuration? What can you say about the importance of exchange energy
07
Draw everything please on a piece of paper explaining each step
Define crystalline, polycrystalline and amorphous materials
What crystal system and Bravais lattices are shown in the figure immediately below? What do a, b,
C, a, ẞ and y represent and what are their values? You can label the Bravais lattices directly above or under the
figure.
C
a
Chapter 7 Solutions
Chemistry, Books a la Carte Edition and Modified Mastering Chemistry with Pearson eText & ValuePack Access Card (7th Edition)
Ch. 7 - Prob. 7.1PCh. 7 - Conceptual APPLY 7.2 An electrostatic potential...Ch. 7 - Prob. 7.3PCh. 7 - Prob. 7.4ACh. 7 - Prob. 7.5PCh. 7 - Prob. 7.6ACh. 7 - Prob. 7.7PCh. 7 - Prob. 7.8ACh. 7 - Prob. 7.9PCh. 7 - Prob. 7.10A
Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12ACh. 7 - Prob. 7.13PCh. 7 - Prob. 7.14ACh. 7 - Prob. 7.15PCh. 7 - Prob. 7.16ACh. 7 - Prob. 7.17PCh. 7 - Prob. 7.18ACh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20ACh. 7 - Prob. 7.21PCh. 7 - Prob. 7.22ACh. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Prob. 7.27PCh. 7 - Prob. 7.28PCh. 7 - Prob. 7.29CPCh. 7 - Prob. 7.30CPCh. 7 - Prob. 7.31CPCh. 7 - Prob. 7.32CPCh. 7 - Prob. 7.33CPCh. 7 - Prob. 7.34CPCh. 7 - Prob. 7.35CPCh. 7 - Prob. 7.36CPCh. 7 - Prob. 7.37CPCh. 7 - Prob. 7.38CPCh. 7 - Prob. 7.39CPCh. 7 - Prob. 7.40CPCh. 7 - Prob. 7.41CPCh. 7 - Prob. 7.42CPCh. 7 - Prob. 7.43CPCh. 7 - Prob. 7.44CPCh. 7 - Prob. 7.45CPCh. 7 - Prob. 7.46CPCh. 7 - Prob. 7.47CPCh. 7 - Prob. 7.48CPCh. 7 - Which of the substances...Ch. 7 - Prob. 7.50CPCh. 7 - Order the following compounds according to the...Ch. 7 - Prob. 7.52CPCh. 7 - Prob. 7.53CPCh. 7 - Prob. 7.54CPCh. 7 - Prob. 7.55CPCh. 7 - Explain the difference in the bond dissociation...Ch. 7 - Explain the difference in the bond dissociation...Ch. 7 - Prob. 7.58CPCh. 7 - Prob. 7.59CPCh. 7 - Prob. 7.60CPCh. 7 - Prob. 7.61CPCh. 7 - Prob. 7.62CPCh. 7 - Prob. 7.63CPCh. 7 - Prob. 7.64CPCh. 7 - Prob. 7.65CPCh. 7 - Prob. 7.66CPCh. 7 - Prob. 7.67CPCh. 7 - Prob. 7.68CPCh. 7 - Prob. 7.69CPCh. 7 - Prob. 7.70CPCh. 7 - Prob. 7.71CPCh. 7 - Identify the third-row elements, X, that form the...Ch. 7 - Identify the fourth-row elements, X, that form the...Ch. 7 - Prob. 7.74CPCh. 7 - Prob. 7.75CPCh. 7 - Methyiphenidat (C14H19NO2) , marketed as Ritalin,...Ch. 7 - Prob. 7.77CPCh. 7 - Prob. 7.78CPCh. 7 - Prob. 7.79CPCh. 7 - Prob. 7.80CPCh. 7 - Prob. 7.81CPCh. 7 - Prob. 7.82CPCh. 7 - Prob. 7.83CPCh. 7 - Prob. 7.84CPCh. 7 - Prob. 7.85CPCh. 7 - Prob. 7.86CPCh. 7 - Prob. 7.87CPCh. 7 - Prob. 7.88CPCh. 7 - Prob. 7.89CPCh. 7 - Prob. 7.90CPCh. 7 - Draw two electron-dot resonance structures that...Ch. 7 - Prob. 7.92CPCh. 7 - Prob. 7.93CPCh. 7 - Prob. 7.94CPCh. 7 - Prob. 7.95CPCh. 7 - Prob. 7.96CPCh. 7 - Prob. 7.97CPCh. 7 - Prob. 7.98CPCh. 7 - Prob. 7.99CPCh. 7 - Write an electron-dot structure for chloral...Ch. 7 - Prob. 7.101CPCh. 7 - Prob. 7.102CPCh. 7 - Prob. 7.103CPCh. 7 - Prob. 7.104CPCh. 7 - Prob. 7.105CPCh. 7 - 7.106 Themolecule has nitrogen-oxygen bonds, but...Ch. 7 - Prob. 7.107CPCh. 7 - Prob. 7.108MPCh. 7 - Prob. 7.109MPCh. 7 - Prob. 7.110MPCh. 7 - Prob. 7.111MPCh. 7 - Prob. 7.112MP
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